The Meyer Reaction of Phenylnitromethane in Acid. II. Reactions in Acid of Benzonitrile Oxide and Benzohydroxamic Acid

1971 ◽  
Vol 49 (21) ◽  
pp. 3489-3492 ◽  
Author(s):  
J. T. Edward ◽  
P. H. Tremaine
Keyword(s):  
Sulfuric Acid ◽  
Room Temperature ◽  
Detailed Mechanism ◽  
Benzohydroxamic Acid ◽  
Dilute Sulfuric Acid ◽  
Rate Profile ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of the transformation of benzonitrile oxide in dilute sulfuric acid into benzohydroxamic acid have been followed by u.v. spectrophotometry at a temperature near room temperature. A mechanism is proposed on the basis of the effects of substituents and sulfuric acid concentration.The rate profile for the hydrolysis of benzohydroxamic acid in hot dilute sulfuric acid has been obtained.The results of these studies are applied to the detailed mechanism of the Meyer rearrangement – hydrolysis of phenylnitromethane in acid.

Evaluation of the Kinetics of Xylose Formation from Dilute Sulfuric Acid Hydrolysis of Forest Residues ofEucalyptusgrandis

2007 ◽  
Vol 46 (7) ◽  
pp. 1938-1944 ◽  
Author(s):  
Eliana V. Canettieri ◽  
George J. M. Rocha ◽  
João A. Carvalho, ◽  
João B. A. Silva
Keyword(s):  
Sulfuric Acid ◽  
Acid Hydrolysis ◽  
Forest Residues ◽  
Dilute Sulfuric Acid ◽  
Kinetics Of ◽  
Hydrolysis Of

scholarly journals Two-stage, dilute sulfuric acid hydrolysis of wood : an investigation of fundamentals

1985 ◽  
Author(s):  
John F. Harris ◽  
Andrew J. Baker ◽  
Anthony H. Conner ◽  
Thomas W. Jeffries ◽  
James L. Minor ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Acid Hydrolysis ◽  
Two Stage ◽  
Dilute Sulfuric Acid ◽  
Hydrolysis Of

Dilute sulfuric acid hydrolysis of tropical region biomass

2012 ◽  
Vol 4 (2) ◽  
pp. 021201 ◽  
Author(s):  
I. P. Hernández ◽  
José A. Pérez-Pimienta ◽  
Sarah Messina ◽  
Claudia E. Saldaña Durán
Keyword(s):  
Sulfuric Acid ◽  
Acid Hydrolysis ◽  
Tropical Region ◽  
Dilute Sulfuric Acid ◽  
Hydrolysis Of

Crystallization kinetics of cerium oxide nanoparticles formed by spontaneous, room-temperature hydrolysis of cerium(iv) ammonium nitrate in light and heavy water

2017 ◽  
Vol 19 (5) ◽  
pp. 3523-3531 ◽  
Author(s):  
Natasha W. Pettinger ◽  
Robert E. A. Williams ◽  
Jinquan Chen ◽  
Bern Kohler
Keyword(s):  
Proton Transfer ◽  
Heavy Water ◽  
Room Temperature ◽  
Transfer Reaction ◽  
Proton Transfer Reaction ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Kinetics Of ◽  
Hydrolysis Of ◽  
Cerium Iv Ammonium Nitrate

Ceria nanocrystals form tenfold more slowly in D2O vs. H2O, revealing a rate-determining proton transfer reaction and a non-classical crystallization mechanism.

scholarly journals Effect of Dilute Sulfuric Acid Hydrolysis of Coconut Dregs on Chemical and Thermal Properties

2013 ◽  
Vol 68 ◽  
pp. 372-378 ◽  
Author(s):  
Normah Bujang ◽  
Miradatul Najwa Muhd Rodhi ◽  
Mohibah Musa ◽  
Fuzieah Subari ◽  
Norazlina Idris ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Sulfuric Acid ◽  
Acid Hydrolysis ◽  
Dilute Sulfuric Acid ◽  
Hydrolysis Of
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