CORRELATION BETWEEN THE COMPOSITION AND STRUCTURE OF TRANSITION METAL COMPLEXES AND THEIR RF VALUES OBTAINED BY PLANAR CHROMATOGRAPHY

1993 ◽  
pp. 143-181 ◽  
Author(s):  
Gordana Vuckovic ◽  
Zivoslav Lj. Tesic ◽  
Milenko B. Celap
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Planar Chromatography ◽  
Composition And Structure ◽  
Rf Values

scholarly journals Synthese und Reaktivität von Silicium-Übergangsmetallkomplexen, XIV [1] Umsetzung von Cp(CO)2Fe-substituierten Silieium-Wasserstoff-Verbindungen mit DicobaJtoctacarbonyl: Synthese von Siliciumverbindungen mit zwei, drei und vier Übergangsmetall -Liganden / Synthesis and Reactivity of Silicon Transition Metal Complexes, XIV [1] Reaction of Cp(CO)2Fe-Substituted Silanes with Dicobaltoctacarbonyl: Synthesis of Silicon Compounds with Two, Three and Four Transition Metal Ligands

1982 ◽  
Vol 37 (5) ◽  
pp. 601-609 ◽  
Author(s):  
Wolfgang Malisch ◽  
Hans-Ulrich Wekel ◽  
Irmgard Grob ◽  
Frank H. Köhler
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
High Yield ◽  
Silicon Compounds ◽  
Metal Ligands ◽  
Composition And Structure ◽  
First Time ◽  
Transition Metal Ligands ◽  
Heteronuclear Complex

The reaction of Cp(CO)2Fe-SiHCl2 with Co2(CO)8 yields the heteronuclear complex Cp(CO)2Fe-SiCl2-Co(CO)4 (1) and HCo(CO)4.1 is degradated by AgBF4 to Cp(CO)2Fe-SiF3. PMe3 transforms 1 to Cp(CO)2Fe-SiCl2-Co(CO)3PMe3 (2). LnM-SiH2Me reacts with Co2(CO)8 to give LnM-SiMe-Co2(CO)7 [LnM = Cp(CO)2Fe (3a), Cp(CO)2PMe3W (3b)]. Starting with Cp(CO)2Fe-SiH3, μ3-Cp(CO)2Fe-SiCo3(CO)9 (4), the second example of a μ3-metallosilylidine tricobalt cluster is obtained in high yield, which is cleaved by acetic acid to Cp(C0)2Fe-Si[OC(O)Me]3 (5). The composition and structure of the silicon transition metal complexes 1-5 is proved by NMR, IR and mass spectroscopy. 29Si NMR shifts are determined for the first time for a tri- and tetra-metalated silicon species

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional

Synthesis, Characterization and in vitro Biological Evaluation of a New Schiff Base Derived from Drug and its Complexes with Transition Metal Ions

2018 ◽  
Vol 69 (7) ◽  
pp. 1678-1681
Author(s):  
Amina Mumtaz ◽  
Tariq Mahmud ◽  
M. R. J. Elsegood ◽  
G. W. Weaver
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Free Ligand ◽  
Transition Metal Ions ◽  
Biological Evaluation ◽  
Pyridoxal Hydrochloride

New series of copper (II), cobalt (II), zinc (II), nickel (II), manganese (II), iron (II) complexes of a novel Schiff base were prepared by the condensation of sulphadizine and pyridoxal hydrochloride. The ligand and metal complexes were characterized by utilizing different instrumental procedures like microanalysis, thermogravimetric examination and spectroscopy. The integrated ligand and transition metal complexes were screened against various bacteria and fungus. The studies demonstrated the enhanced activity of metal complexes against reported microbes when compared with free ligand.

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