Mixed Matrix Membranes for Gas Separation Applications

2017 ◽  
pp. 1-57 ◽  
Author(s):  
Maria Carreon ◽  
Ganpat Dahe ◽  
Jie Feng ◽  
Surendar R Venna
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Mehtap Safak Boroglu ◽  
Ismail Boz ◽  
Busra Kaya

Abstract In our study, the synthesis of zeolitic imidazolate framework (ZIF-12) crystals and the preparation of mixed matrix membranes (MMMs) with various ZIF-12 loadings were targeted. The characterization of ZIF-12 and MMMs were carried out by Fourier transform infrared spectroscopy analysis, thermogravimetric analysis, scanning electron microscopy (SEM), and thermomechanical analysis. The performance of MMMs was measured by the ability of binary gas separation. Commercial polyetherimide (PEI-Ultem® 1000) polymer was used as the polymer matrix. The solution casting method was utilized to obtain dense MMMs. In the SEM images of ZIF-12 particles, the particles with a rhombic dodecahedron structure were identified. From SEM images, it was observed that the distribution of ZIF-12 particles in the MMMs was homogeneous and no agglomeration was present. Gas permeability experiments of MMMs were measured for H2, CO2, and CH4 gases at steady state, at 4 bar and 35 °C by constant volume-variable pressure method. PEI/ZIF-12-30 wt% MMM exhibited high permeability and ideal selectivity values for H2/CH4 and CO2/CH4 were P H 2 / CH 4 = 331.41 ${P}_{{\text{H}}_{2}/{\text{CH}}_{4}}=331.41$ and P CO 2 / CH 4 = 53.75 ${P}_{{\text{CO}}_{2}/{\text{CH}}_{4}}=53.75$ gas pair.


2021 ◽  
Vol 11 (2) ◽  
pp. 313-330
Author(s):  
Ovaid Mehmood ◽  
Sarah Farrukh ◽  
Arshad Hussain ◽  
Mohammad Younas ◽  
Zarrar Salahuddin ◽  
...  

2012 ◽  
Vol 35 (5) ◽  
pp. 885-892 ◽  
Author(s):  
H. Karkhanechi ◽  
H. Kazemian ◽  
H. Nazockdast ◽  
M. R. Mozdianfard ◽  
S. M. Bidoki

2019 ◽  
Vol 573 ◽  
pp. 359-369 ◽  
Author(s):  
Yanfang Fan ◽  
Cong Li ◽  
Xiaosa Zhang ◽  
Xiaomei Yang ◽  
Xingyu Su ◽  
...  

2019 ◽  
Author(s):  
Andrew Paul Han ◽  
Frederick F Stewart ◽  
Christopher J Orme

2015 ◽  
Vol 3 (16) ◽  
pp. 8650-8658 ◽  
Author(s):  
Junhui Wang ◽  
Yang Li ◽  
Zhongshen Zhang ◽  
Zhengping Hao

The incorporation of a low percentage of KIT-6 into PDMS membranes can greatly increase the C4H10permeability and C4H10/N2selectivity simultaneously.


Langmuir ◽  
2009 ◽  
Vol 25 (10) ◽  
pp. 5903-5909 ◽  
Author(s):  
Beatriz Zornoza ◽  
Silvia Irusta ◽  
Carlos Téllez ◽  
Joaquín Coronas

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