The Atomic Structure of the UO2 (111) Surface and the Effects of Additional Surface Oxygen Studied by Elevated Temperature STM
1998 ◽
Vol 05
(01)
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pp. 315-320
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The structure of the UO 2+x (111) surface has been investigated by elevated temperature STM. Images of atomic terraces reveal two different types of surface termination. One of them corresponds to the stoichiometric UO 2 (111) surface and can be resolved atomically in empty state images above ~ 1.6 V sample bias. The observed (1 × 1) ordering is thought to be due to uranium states because its occurrence corresponds to the bottom of the empty uranium 5f band. On these terraces mobile oxygen forms a local [Formula: see text] superstructure. The other terrace type observed on top of the UO 2+x (111) surface is thought to be a phase of a higher uranium oxide which has grown epitaxially.
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1977 ◽
Vol 7
(2)
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pp. 327-340
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