THEORIES OF DIFFUSION AT A MICRORING ELECTRODES: A REVIEW

2007 ◽  
Vol 06 (04) ◽  
pp. 699-713
Author(s):  
L. RAJENDRAN ◽  
G. RAHAMATHUNISSA ◽  
C. A. BASHA

Microring electrodes are useful for the investigation of electrode kinetics due to their large perimeter-to-area ratio and compact nature but have hitherto been limited in application due to the absence of the underpinning theory. In this review, the analytical solutions, approximate expressions, and numerical solutions of transient chronoamperometric current at a microring electrode under diffusion control are discussed. The steady and non-steady-state current for microring electrode for an EC' reaction are also discussed. Tabular compilations of dimensionless current are provided.

2017 ◽  
Vol 59 (2) ◽  
pp. 167-182 ◽  
Author(s):  
H. Y. ALFIFI

Semi-analytical solutions are derived for the Brusselator system in one- and two-dimensional domains. The Galerkin method is processed to approximate the governing partial differential equations via a system of ordinary differential equations. Both steady-state concentrations and transient solutions are obtained. Semi-analytical results for the stability of the model are presented for the identified critical parameter value at which a Hopf bifurcation occurs. The impact of the diffusion coefficients on the system is also considered. The results show that diffusion acts to stabilize the systems better than the equivalent nondiffusive systems with the increasing critical value of the Hopf bifurcation. Comparison between the semi-analytical and numerical solutions shows an excellent agreement with the steady-state transient solutions and the parameter values at which the Hopf bifurcations occur. Examples of stable and unstable limit cycles are given, and Hopf bifurcation points are shown to confirm the results previously calculated in the Hopf bifurcation map. The usefulness and accuracy of the semi-analytical results are confirmed by comparison with the numerical solutions of partial differential equations.


Open Physics ◽  
2011 ◽  
Vol 9 (1) ◽  
Author(s):  
Erik Sweet ◽  
Kuppalapalle Vajravelu ◽  
Robert Gorder

AbstractIn this paper we investigate the three-dimensional magnetohydrodynamic (MHD) rotating flow of a viscous fluid over a rotating sphere near the equator. The Navier-Stokes equations in spherical polar coordinates are reduced to a coupled system of nonlinear partial differential equations. Self-similar solutions are obtained for the steady state system, resulting from a coupled system of nonlinear ordinary differential equations. Analytical solutions are obtained and are used to study the effects of the magnetic field and the suction/injection parameter on the flow characteristics. The analytical solutions agree well with the numerical solutions of Chamkha et al. [31]. Moreover, the obtained analytical solutions for the steady state are used to obtain the unsteady state results. Furthermore, for various values of the temporal variable, we obtain analytical solutions for the flow field and present through figures.


2017 ◽  
Vol 24 (4) ◽  
pp. 727-735
Author(s):  
Mayer Humi

Abstract. Two-dimensional, steady-state, stratified, isothermal atmospheric flow over topography is governed by Long's equation. Numerical solutions of this equation were derived and used by several authors. In particular, these solutions were applied extensively to analyze the experimental observations of gravity waves. In the first part of this paper we derive an extension of this equation to non-isothermal flows. Then we devise a transformation that simplifies this equation. We show that this simplified equation admits solitonic-type solutions in addition to regular gravity waves. These new analytical solutions provide new insights into the propagation and amplitude of gravity waves over topography.


Author(s):  
Arthur W. Warrick

This chapter addresses one-dimensional infiltration and vertical flow problems. Traditionally, infiltration has received more attention than other unsaturated flow procedures, both for empirical formulations and for applications of Richards’ equation. Rarely is infiltration the only process of interest, and from an overall point of view it is only one example of soil water dynamics. Here, we will first emphasize systems for which analytical (or quasi-analytical) solutions can be found. These include the Green and Ampt solution (1911), which adds gravity to the simplified analysis discussed in chapter 4. Then a linearized form of Richards’ equation will be examined, followed by the perturbation of the horizontal problem of Philip leading to his famous series solution. Although the closed-form and quasi-analytical solutions are convenient for calculations and discussing the physical principles, generally, the nonlinearity of Richards’ equation precludes such convenient forms. However, numerical approximations can be used. The conventional numerical methods applied in water and solute transport are based on finite differences and finite elements. Because of its greater simplicity, we will emphasize finite differences and build on the methodology from the saturated-flow example in chapter 3. Richards’ equation is a parabolic partial differential equation reducing to an elliptical form for steady-state cases. The analyses and methods parallel developments for techniques developed primarily for the linear diffusion equation. Many texts exist for numerical methods; one to which we refer is by Smith (1985). Ideally, numerical methods give solutions that are as accurate as the input warrants or as necessary for application. In some cases, results may be easier or more accurate than the evaluation of a complex analytical expression. Clearly, infiltration is of limited duration, with drainage and redistribution occurring over much longer time frames. We will visit briefly some steady-state examples, including layered profile and upward flow from a shallow water table. Other examples include modeling plant water uptake from the profile and drainage of initially wet profiles. The rapid increase in computational power and availability of computers make solutions feasible and routine for problems that were very tedious or time consuming only a few years ago. This is particularly true of the one-dimensional numerical solutions.


2017 ◽  
Author(s):  
Mayer Humi

Abstract. Two dimensional, steady state, stratified, isothermal, atmospheric flow over topography is governed by Long's equation. Numerical solutions of this equation were derived and used by several authors. In particular these solutions were applied extensively to analyze the experimental observations of gravity waves. In the first part of this paper we derive an extension of this equation to non-isothermal flows. Then we devise a transformation that simplifies this equation. We show that this simplified equation admits solitonic type solutions in addition to regular gravity waves. These new analytical solutions provide insights about the propagation and amplitude of gravity waves over topography.


2021 ◽  
Vol 11 (15) ◽  
pp. 6920
Author(s):  
Oldřich Coufal

Two infinitely long parallel conductors of arbitrary cross section connected to a voltage source form a loop. If the source voltage depends on time, then due to induction there is no constant current density in the loop conductors. It is only recently that a method has been published for accurately calculating current density in a group of long parallel conductors. The method has thus far been applied to the calculation of steady-state current density in a loop connected to a sinusoidal voltage source. In the present article, the method is used for an accurate calculation of transient current using transient current density. The transient current is analysed when connecting and short-circuiting the sources of sinusoidal, constant and sawtooth voltages. For circular cross section conductors, the dependences of maximum current density, maximum current and the time of achieving steady state on the source frequency, the distance of the conductors and their resistivity when connecting the source of sinusoidal voltage are examined.


Author(s):  
Robert L. McMasters ◽  
Filippo de Monte ◽  
James V. Beck ◽  
Donald E. Amos

This paper provides a solution for two-dimensional heating over a rectangular region on a homogeneous plate. It has application to verification of numerical conduction codes as well as direct application for heating and cooling of electronic equipment. Additionally, it can be applied as a direct solution for the inverse heat conduction problem, most notably used in thermal protection systems for re-entry vehicles. The solutions used in this work are generated using Green’s functions. Two approaches are used which provide solutions for either semi-infinite plates or finite plates with isothermal conditions which are located a long distance from the heating. The methods are both efficient numerically and have extreme accuracy, which can be used to provide additional solution verification. The solutions have components that are shown to have physical significance. The extremely precise nature of analytical solutions allows them to be used as prime standards for their respective transient conduction cases. This extreme precision also allows an accurate calculation of heat flux by finite differences between two points of very close proximity which would not be possible with numerical solutions. This is particularly useful near heated surfaces and near corners. Similarly, sensitivity coefficients for parameter estimation problems can be calculated with extreme precision using this same technique. Another contribution of these solutions is the insight that they can bring. Important dimensionless groups are identified and their influence can be more readily seen than with numerical results. For linear problems, basic heating elements on plates, for example, can be solved to aid in understanding more complex cases. Furthermore these basic solutions can be superimposed both in time and space to obtain solutions for numerous other problems. This paper provides an analytical two-dimensional, transient solution for heating over a rectangular region on a homogeneous square plate. Several methods are available for the solution of such problems. One of the most common is the separation of variables (SOV) method. In the standard implementation of the SOV method, convergence can be slow and accuracy lacking. Another method of generating a solution to this problem makes use of time-partitioning which can produce accurate results. However, numerical integration may be required in these cases, which, in some ways, negates the advantages offered by the analytical solutions. The method given herein requires no numerical integration; it also exhibits exponential series convergence and can provide excellent accuracy. The procedure involves the derivation of previously-unknown simpler forms for the summations, in some cases by virtue of the use of algebraic components. Also, a mathematical identity given in this paper can be used for a variety of related problems.


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