A new three-phase heterocrystal catalysts and their superior treatment efficiency for tetracycline

2016 ◽  
Vol 10 (03) ◽  
pp. 1750015
Author(s):  
Feng-Rui Wang ◽  
Hui-Ping Sun ◽  
Yan Wang ◽  
Jin-Ku Liu ◽  
Yi Fang ◽  
...  

An easy recyclable and interesting Ag3PO4@Pt@TiO2 (APTP) three-phase heterocrystal chains were self-assembled by the cohesive action and chemical construction of polyvinylpyrrolidone (PVP). We found that a new electron–hole transmission path has been built via the rematch of the band structure of Ag3PO4, Pt and TiO2 which extends the light absorption and promoted the electron–hole separation to treat the antibiotic residues in the water. Based on the thorough investigations, a new catalytic material was provided for antibiotics degradation. The catalytic activity of APTP toward the degradation of tetracycline solution was enhanced by 166.67% and the stability increased remarkably compared with pure Ag3PO4 through the integration of different functional components.

1999 ◽  
Vol 96 (9) ◽  
pp. 1335-1339 ◽  
Author(s):  
ALAN E. VAN GIESSEN, DIRK JAN BUKMAN, B.

2015 ◽  
Vol 11 (1) ◽  
pp. 2927-2949
Author(s):  
Lyubov E. Lokot

In the paper a theoretical study the both the quantized energies of excitonic states and their wave functions in grapheneand in materials with "Mexican hat" band structure dispersion as well as in zinc-blende GaN is presented. An integral twodimensionalSchrödinger equation of the electron-hole pairing for a particles with electron-hole symmetry of reflection isexactly solved. The solutions of Schrödinger equation in momentum space in studied materials by projection the twodimensionalspace of momentum on the three-dimensional sphere are found exactly. We analytically solve an integral twodimensionalSchrödinger equation of the electron-hole pairing for particles with electron-hole symmetry of reflection. Instudied materials the electron-hole pairing leads to the exciton insulator states. Quantized spectral series and lightabsorption rates of the excitonic states which distribute in valence cone are found exactly. If the electron and hole areseparated, their energy is higher than if they are paired. The particle-hole symmetry of Dirac equation of layered materialsallows perfect pairing between electron Fermi sphere and hole Fermi sphere in the valence cone and conduction cone andhence driving the Cooper instability. The solutions of Coulomb problem of electron-hole pair does not depend from a widthof band gap of graphene. It means the absolute compliance with the cyclic geometry of diagrams at justification of theequation of motion for a microscopic dipole of graphene where >1 s r . The absorption spectrums for the zinc-blendeGaN/(Al,Ga)N quantum well as well as for the zinc-blende bulk GaN are presented. Comparison with availableexperimental data shows good agreement.


2021 ◽  
Vol 379 ◽  
pp. 457-465
Author(s):  
Tiancheng Zhang ◽  
Quanle Zou ◽  
Zhiheng Cheng ◽  
Zihan Chen ◽  
Ying Liu ◽  
...  

1986 ◽  
Vol 51 (8) ◽  
pp. 1571-1578 ◽  
Author(s):  
Alois Motl

The radiation catalytic properties of the BASF K-3-10 catalyst were studied, namely the dependence of these effects on the time interval between the catalyst irradiation and the reaction itself and also on the length of the catalyst use. The catalytic effects decrease exponentially with the interval between the irradiation and the reaction if the catalyst is kept in the presence of air. The stability of effects induced by various types of radiations increases in the sequence beta radiation - gamma radiation - fast neutrons. The radiation catalytic effect stability in the reaction increases in the same sequence.


2021 ◽  
Author(s):  
Jaimie Swartz ◽  
Alexandra Von Meier
Keyword(s):  

Author(s):  
P. Vimala ◽  
C. R. Balamurugan ◽  
A. Subramanian ◽  
T. Vishwanath

The FOPID and PID controller are designed to control the speed of <br /> the BLDC motor. The parameters , , , λ and µ of these controller are optimized based on genetic algorithm. The optimized coefficients keep in track with zero error signals. The output of the controller is given to the variable dc source which varies the input voltage to the three phase inverter depending on the input signal. The three phase inverter gives the voltage to the BLDC motor which enhances the stability of the system. <br /> The effectiveness of the controller is demonstrated by simulation.


Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1163
Author(s):  
Ning Cui ◽  
Kexiao Bi ◽  
Wei Sun ◽  
Qianqian Wu ◽  
Yinan Li ◽  
...  

MOF–derived porous carbon is a type of promising catalyst to replace expensive Pt–based catalysts for oxygen reduction reaction (ORR). The catalytic activity for ORR depends closely on pyrolysis conditions. In this work, a Co–doped ZIF–8 material was chosen as a research object. The effect of pyrolysis conditions (temperature, heating rate, two–step heating) on the ORR performance of ZIF–derived carbon catalysts was systematically studied. The Co–ZIF–8 catalyst carbonized at 900 °C exhibits better ORR catalytic activity than that carbonized at 800 °C and 1000 °C. Moreover, a low heating rate can enhance catalytic activity. Two–step pyrolysis is proven to be an effective way to improve the performance of catalysts. Reducing the heating rate in the low–temperature stage is more beneficial to the ORR performance, compared to the heating rate in the high–temperature stage. The results show that the Co–ZIF–8 catalyst exhibits the best performance when the precursor was heated to 350 °C at 2 °C/min, and then heated to 900 °C at 5 °C/min. The optimum Co–ZIF–8 catalyst shows a half–wave potential of 0.82 V and a current density of 5.2 mA·cm−2 in 0.1 M KOH solution. It also exhibits high content of defects and good graphitization. TEM mapping shows that Co and N atoms are highly dispersed in the polyhedral carbon skeleton. However, two–step pyrolysis has no significant effect on the stability of the catalyst.


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