Ultrathin Semi-Interpenetrating Network Membranes Based on Perfluorinated Sulfonic Acid Resin and Polydivinylbenzene with Declined Hydrogen Crossover for Proton Exchange Membrane Fuel Cell

Author(s):  
Shuyan Wang ◽  
Zhenfeng He ◽  
Xiaoli Wang ◽  
Chao Wang ◽  
Xue Li ◽  
...  
2019 ◽  
Vol 3 (7) ◽  
pp. 1790-1798 ◽  
Author(s):  
Robin Sandström ◽  
Alagappan Annamalai ◽  
Nicolas Boulanger ◽  
Joakim Ekspong ◽  
Alexandr Talyzin ◽  
...  

Two-dimensional perfluorinated sulfonic acid represent an intriguing new proton exchange membrane concept.


2018 ◽  
Vol 215 ◽  
pp. 338-347 ◽  
Author(s):  
Pucheng Pei ◽  
Ziyao Wu ◽  
Yuehua Li ◽  
Xiaoning Jia ◽  
Dongfang Chen ◽  
...  

2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Chao Meng ◽  
Sheng Huang ◽  
Dongmei Han ◽  
Shan Ren ◽  
Shuanjin Wang ◽  
...  

In the present work, a semi-interpenetrating network (semi-IPN) high-temperature proton exchange membrane based on polyethyleneimine (PEI), epoxy resin (ER), and polybenzimidazole (PBI) was prepared and characterized, aiming at their future application in fuel cell devices. The physical properties of the semi-IPN membrane are characterized by thermogravimetric analysis (TGA) and tensile strength test. The results indicate that the as-prepared PEI-ER/PBI semi-IPN membranes possess excellent thermal stability and mechanical strength. After phosphoric acid (PA) doping treatment, the semi-IPN membranes show high proton conductivities. PA doping level and volume swelling ratio as well as proton conductivities of the semi-IPN membranes are found to be positively related to the PEI content. High proton conductivities of 3.9 ∽ 7.8 × 10 − 2   S   c m − 1 are achieved at 160°C for these PA-doped PEI-ER/PBI series membranes. H2/O2 fuel cell assembled with PA-doped PEI-ER(1 : 2)/PBI membrane delivered a peak power density of 170 mW cm-2 at 160°C under anhydrous conditions.


Author(s):  
Hien T. T. Nguyen ◽  
Florian Lombeck ◽  
Claudia Schwarz ◽  
Philipp A. Heizmann ◽  
Michael Adamski ◽  
...  

Non-fluorinated hydrocarbon ionomers feature distinct technical, cost and environmental advantages over incumbent perfluorinated sulfonic acid (PFSA)-based ionomers: they offer improved thermo-mechanical properties at temperatures beyond 90 °C, likelihood of lower...


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