Effects of pH Value in the Electrolyte on the Properties of Cu2ZnSnS4Thin Film Fabricated by Single Step Co-Electrodeposition

2016 ◽  
Vol 5 (9) ◽  
pp. P521-P525 ◽  
Author(s):  
Hong Zhang ◽  
Shuying Cheng ◽  
Jinling Yu ◽  
Yunfeng Lai ◽  
Haifang Zhou ◽  
...  
Keyword(s):  
Ph Value ◽  
Single Step ◽  
Effects Of Ph

scholarly journals Removal of Trace Thallium from Industrial Wastewater by Fe0-Electrocoagulation

Water ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 163 ◽  
Author(s):  
Xianghui Fu ◽  
Li Li ◽  
Guochao Yang ◽  
Xiangyang Xu ◽  
Lihua He ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Current Density ◽  
Industrial Wastewater ◽  
Ph Value ◽  
Operation Time ◽  
Single Step ◽  
Toxic Heavy Metal ◽  
Effective Removal ◽  
Initial Ph ◽  
Effects Of Ph

As thallium (Tl) is a highly toxic heavy metal, there are compulsory environmental regulations in many countries on minimizing its release. This research investigated the treatment of real industrial wastewater with low Tl(I) concentration by Fe0-electrocoagulation (Fe0-EC) in a batch aeration-forced pump cycle reactor. The effects of pH (7–12), current density (8.3–33.3 mA/cm2), dissolved oxygen (DO) in wastewater, and initial Tl(I) concentration (66–165 µg/L) on Tl(I) removal efficiency were investigated. The removal efficiency of Tl(I) is pH-dependent, to be exact, it increases significantly with pH rising from 8 to 11. Initial pH of influent and DO concentration were the key operation parameters which strongly affect Tl(I) removal. After the water sample with initial Tl(I) concentration of 115 µg/L was treated for 12 min by a single-step process at pH of 11 and current density of 16.7 mA/cm2, the residual Tl(I) concentration was decreased to beneath the emission limit in China (2 µg/L) with a low energy consumption of 0.82 kWh/m3. By prolonging the operation time, the concentration was further reduced to 0.5 µg/L or even lower. The main composition of the flocculent sludges is iron oxyhydroxide, yet its crystal structure varies dependent on pH value which may result in different Tl(I) removal efficiency. Feroxyhyte nanosheets generate in situ by Fe0-EC, which contributes to the rapid and effective removal of Tl(I), while the speedy oxidation under DO-enriched conditions benefits the feroxyhyte formation. The mechanism of Tl(I) removal by Fe0-EC is attributed to the combination of electrostatic attraction and the formation of inner-sphere complexes. As shown in the technical and mechanical studies, Fe0-EC technology is an effective method for low Tl concentration removal from wastewater.

DIP quality influenced by process water quality

TAPPI Journal ◽  
2014 ◽  
Vol 13 (9) ◽  
pp. 51-60
Author(s):  
DENNIS VOSS ◽  
HANS-JOACHIM PUTZ ◽  
SAMUEL SCHABEL
Keyword(s):  
Water Quality ◽  
Surface Tension ◽  
Ph Value ◽  
Water Hardness ◽  
Process Water ◽  
Test Results ◽  
Negative Effects ◽  
Water Parameters ◽  
Effects Of Ph ◽  
Contamination Levels

The need for deinking mills to reduce their fresh water consumption has resulted in higher loads of various contaminants in the process water. Lower recovered paper quality also leads to higher contamination levels in the mills. This higher load has an influence on achievable target brightness. The objective of the work was to determine and explain the main reasons for relatively poor deinked pulp quality or poor deinking potential based on the influence of recovered paper composition and process water quality. The process water parameters significantly affect the deinking potential of recovered paper. The test results showed the negative effects of increased water hardness. For standard recovered paper mixtures, flotation selectivity is higher with increasing flotation pH-value. Good results were realized for standard recovered paper with low hardness, low surface tension, and high pH-value. The results for recovered paper containing flexo newsprint could be slightly improved with low hardness, low surface tension, and low pH-value. The results of the test program using design of experiments showed interacting effects of pH-value and surface tension on luminosity and flotation selectivity.

Effects of pH value on the formation of volatiles of Shiitake (Lentinus edodes), an edible mushroom

1984 ◽  
Vol 32 (5) ◽  
pp. 999-1001 ◽  
Author(s):  
Chu Chin Chen ◽  
Su Der Chen ◽  
Jer Jeun Chen ◽  
Chung May Wu
Keyword(s):  
Ph Value ◽  
Edible Mushroom ◽  
Lentinus Edodes ◽  
Effects Of Ph

Effects of pH Value on the Stress Corrosion Cracking of Super 13Cr Tubing Steel

2012 ◽  
Vol 557-559 ◽  
pp. 127-130 ◽  
Author(s):  
Xiao Fei Yao ◽  
Fa Qin Xie ◽  
Xiang Qing Wu ◽  
Yi Fei Wang
Keyword(s):  
Stress Corrosion ◽  
Stress Corrosion Cracking ◽  
Acidic Medium ◽  
Ph Value ◽  
Fracture Morphology ◽  
Corrosion Cracking ◽  
Nacl Solution ◽  
Susceptibility Index ◽  
Experiment Method ◽  
Effects Of Ph

Effects of pH value on the stress corrosion cracking (SCC) of super 13Cr tubing steel were investigated in 3.5% NaCl solution, that mechanics properties and fracture morphology and SCC resistance and stress corrosion cracking susceptibility index (kscc) were analyzed by slow strain rate tensile (SSRT) stress corrosion cracking experiment method and σ-ε curve and SEM. the results Effects of pH value on the stress corrosion cracking (SCC) of super 13Cr tubing steel were investigated in 3.5% NaCl solution, that mechanics properties and fracture morphology and SCC resistance and stress corrosion cracking susceptibility index (kscc) were analyzed by slow strain rate tensile (SSRT) stress corrosion cracking experiment method and σ-ε curve and SEM. the results showed that super 13Cr tubing steel has good properties of resistance stress corrosion cracking in acidic medium, effects of pH value on super13Cr tubing steel resistance stress corrosion was not very obviously in the acidic medium, with pH value decreased, super 13Cr tubing steel tensile strength decreased, elongation rate decreased, fracture area contraction ratio decreased, break time reduced, the tendency of the stress corrosion cracking increased. the stress corrosion cracking susceptibility index kσ and kε were all increasing, that increased degree of kε were obviously than kσ, effects of pH value on the plastic deformation of super 13Cr tubing steel were greater than tensile strength.

Effect of wood acidity and catalyst on UF resin gel time

Holzforschung ◽  
2004 ◽  
Vol 58 (4) ◽  
pp. 408-412 ◽  
Author(s):  
C. Xing ◽  
S.Y. Zhang ◽  
J. Deng
Keyword(s):  
Ph Value ◽  
Raw Materials ◽  
Urea Formaldehyde ◽  
Acid Catalyst ◽  
Buffering Capacity ◽  
Raw Material ◽  
Gel Time ◽  
Uf Resin ◽  
Effects Of Ph ◽  
Fiber Materials

Abstract Knowledge of pH and buffering capacity of raw fiber materials is important for understanding the effects of raw material on the curing rate of urea formaldehyde (UF) resin, used for panel manufacturing, especially with some less-desirable wood materials such as bark, top, and commercial thinnings. The effects of pH and buffering capacity as well as catalyst content on the gel time of UF resin were investigated. The results obtained from this study indicate that bark has a lower pH value as well as higher acid and alkaline buffering capacities than wood of the same species due to their extractives. The pH values of the raw fiber materials studied decrease with increased absolute and relative acid buffering capacity due to the increased absolute acidity mass in the solution. At lower levels of added catalyst, the effect of raw material pH on UF resin gel time is significant, while it is insignificant at higher catalyst contents. This may be due to the acidity of wood, which is the main acid catalyst source of the mixture at lower levels of added catalyst, while at higher levels, catalyst is the main source. With higher catalyst contents, all studied raw materials mixed with UF resin result in a longer gel time than does UF resin alone.

A Study of Fenton’s Oxidation Pretreatment on Dye Wastewater Containing Acetic Acid

2014 ◽  
Vol 1044-1045 ◽  
pp. 215-218
Author(s):  
Xian Huan Qiu ◽  
Hai Yu ◽  
Peng Fei Deng
Keyword(s):  
Acetic Acid ◽  
Processing Time ◽  
Ph Value ◽  
Removal Rate ◽  
Cod Removal ◽  
Dye Wastewater ◽  
Fenton’S Oxidation ◽  
Effects Of Ph ◽  
Cod Removal Rate ◽  
Fenton's Oxidation

In the presence of acetic acid, the effects of pH, processing time, addition of Fe2+ and H2O2 on dye wastewater treatment were studied. Experimental results showed that in the presence of acetic acid, when the pH value was 4, the processing time was 30.0min, addition of ferrous sulfate was 4.8g/L, and addition of hydrogen peroxide was 56mL/L, the treatment effect was the best, COD removal rate reached 51.0%. Further studied of the effect of the presence of acetic acid on Fenton’s oxidation of dye wastewater, the results showed that without of acetic acid, the COD removal rate was higher than that with acetic acid. And the effect of Fenton's reagent on oxidation of dye substances was interfered by the presence of acetic acid.

scholarly journals Preparation and Characterization of Nanoporous Activated Carbon Derived from Prawn Shell and Its Application for Removal of Heavy Metal Ions

Materials ◽  
2019 ◽  
Vol 12 (2) ◽  
pp. 241 ◽  
Author(s):  
Jian Guo ◽  
Yaqin Song ◽  
Xiaoyang Ji ◽  
Lili Ji ◽  
Lu Cai ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Activated Carbon ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Ph Value ◽  
Average Pore Size ◽  
High Specific Surface Area ◽  
Koh Activation ◽  
Average Pore ◽  
Effects Of Ph

The aim of this study was to optimize the adsorption performance of activated carbon (AC), derived from the shell of Penaeus vannamei prawns, on heavy metal ions. Inexpensive, non-toxic, and renewable prawn shells were subjected to carbonization and, subsequently, KOH-activation to produce nanoporous K-Ac. Carbonized prawn shells (CPS) and nanoporous KOH-activated carbon (K-Ac) from prawn shells were prepared and characterized by FTIR, XRD, BET, SEM, and TEM. The results showed that as-produced K-Ac samples were a porous material with microporous and mesoporous structures and had a high specific surface area of 3160 m2/g, average pore size of about 10 nm, and large pore volume of 2.38 m3/g. Furthermore, batches of K-Ac samples were employed for testing the adsorption behavior of Cd2+ in solution. The effects of pH value, initial concentration, and adsorption time on Cd2+ were systematically investigated. Kinetics and isotherm model analysis of the adsorption of Cd2+ on K-Ac showed that experimental data were not only consistent with the Langmuir adsorption isotherm, but also well-described by the quasi-first-order model. Finally, the adsorption behaviors of as-prepared K-Ac were also tested in a ternary mixture of heavy metal ions Cu2+, Cr6+, and Cd2+, and the total adsorption amount of 560 mg/g was obtained.

Pseudo-Second-Order Kinetics for the Adsorption of Uranyl Ion onto Peat at Different pH Value

2010 ◽  
Vol 113-116 ◽  
pp. 33-36
Author(s):  
Zhi Rong Liu ◽  
Qin Qin Tao ◽  
Chuan Xi Wen
Keyword(s):  
Contact Time ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Ph Value ◽  
Second Order ◽  
Uranyl Ions ◽  
Batch Tests ◽  
Effects Of Ph ◽  
Pseudo Second Order

Batch tests were used to investigate the effects of pH and contact time on the adsorption capability of peat. The results indicate that adsorption of uranyl ions on peat increase with increasing pH from 1 to 5. However it takes longer contact time to reach the adsorption equilibrium with increase of pH from 1 to 5. The adsorption process can be described by type 1 of the pseudo-second-order kinetics excellently.

scholarly journals Activated Charcoal—A Potential Material in Glucoamylase Recovery

2011 ◽  
Vol 2011 ◽  
pp. 1-4 ◽  
Author(s):  
S. O. Kareem ◽  
I. Akpan ◽  
T. O. S. Popoola ◽  
L. O. Sanni
Keyword(s):  
Molecular Weight ◽  
Activated Charcoal ◽  
Contact Time ◽  
Enzyme Purification ◽  
Downstream Processing ◽  
Single Step ◽  
Major Protein ◽  
Rhizopus Oligosporus ◽  
Sds Page ◽  
Effects Of Ph

The potential of activated charcoal in the purification of fungal glucoamylase was investigated. Various concentrations of activated charcoal (1–4% w/v) were used to concentrate crude glucoamylase from Rhizopus oligosporus at different temperature values (30–50°C). Effects of pH (3.0–6.0) and contact time (0–60 min) on enzyme purification were also monitored. Activated charcoal (3% w/v) gave a 16-fold purification in a single-step purification at 50°C for 20 min and pH 5.5. The result of SDS-PAGE analysis of purified glucoamylase showed two major protein bands with corresponding molecular weight of 36 kDa and 50 kDa. The method is inexpensive, rapid, and simple which could facilitate downstream processing of industrial enzyme.

Electroless Ni-La-P Coatings on 2024 Aluminum Alloys for Aircraft Structure

2012 ◽  
Vol 224 ◽  
pp. 348-351
Author(s):  
Chuan Yong Huang
Keyword(s):  
Aluminum Alloy ◽  
Aluminum Alloys ◽  
Aluminium Alloys ◽  
Ph Value ◽  
Deposition Method ◽  
Aircraft Structure ◽  
Corrosion Resistant ◽  
Effects Of Ph ◽  
Alloy Plating ◽  
Electroless Ni

2024 aluminium alloys are widely used in airframe construction.However,this series of alloys are susceptible to corrosion to limit their usefulness,In this study,electroless Ni-La-P alloy plating on aluminum alloy and the effects of pH value,temperature and concentration of LaNiO3 on deposition rate were investigated.Surface morphology and corosion-resistant of the electroless Ni-La-P deposits were evaluated.The results showed the corrosion-resistant in 5％ NaC1 solutions obviously enhance compared with original aluminum alloy using electroless Ni-La-P deposition method．

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