Electron Transfer and Transport Studies on Sensitized Titanium Dioxide Films Using Time Resolved Microwave Conductivity

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xiaochun Liu ◽  
Haifeng Zhao ◽  
Linfeng Wei ◽  
Xinjian Ren ◽  
Xinyang Zhang ◽  
...  

Abstract In most perovskite nanocrystal (PeNC)-based optoelectronic and photonic applications, surface ligands inevitably lead to a donor–bridge–acceptor charge transfer configuration. In this article, we demonstrate successful modulation of electron transfer (ET) rates from all-inorganic CsPbBr3 PeNCs to mesoporous titanium dioxide films, by using different surface ligands including single alkyl chain oleic acid and oleylamine, cross-linked insulating (3-aminopropyl)triethoxysilane and aromatic naphthoic acid molecules as the ligand-bridge. We systematically investigated the ET process through time-resolved photoluminescence spectroscopy. Calculations verified the ligand-bridge barrier effect of the three species upon the ET process. Transient absorption measurements excluded carrier-delocalization effect of the naphthoic acid ligands and confirmed the bridge-barrier effect. Our work provides a perspective for composable and appropriate ligands design for diverse practical purposes.


LWT ◽  
2014 ◽  
Vol 57 (2) ◽  
pp. 548-555 ◽  
Author(s):  
Zhe Wang ◽  
Ning Zhang ◽  
Huai-yu Wang ◽  
Si-yao Sui ◽  
Xiu-xiu Sun ◽  
...  

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