Micro-Raman Spectroscopy of Zircon (ZrSiO4) Mineral at Annealing Conditions Usually Applied in Zircon Fission-Track Annealing Dataset

2020 ◽  
Vol 20 (3) ◽  
pp. 1884-1891
Author(s):  
Airton Natanael Coelho Dias ◽  
Carlos José Leopoldo Constantino ◽  
Cleber José Soares ◽  
Sandro Guedes de Oliveira

Raman analyzes were performed on zircon from a syenite located in the Poços de Caldas Complex, Brazil, with a fission-track (FT) zircon age of 81.4±6.8 Ma. Three isochronous heating (1, 10 and 100 hours) of zircon grains were subjected to temperatures between 300 and 750 °C. These temperature and times are usually applied to obtain zircon Fission-Track annealing dataset. For each time-temperature conditions, Raman spectra analyses were accomplished. The results show variations in the intensity and FWHM (full width at half maximum) in the main band (1007 cm-1– Si–O stretching mode), and a singular change in the peaks from 356 to 439 cm-1 (Si–O bending mode); and from 202 to 224 cm-1 (external modes). These changes were interpreted as spectral polarization-dependence related to common crystallinity increases due to the annealing radiation damages and that the thermal treatments do not interfere on the stability of zircon lattice.

1984 ◽  
Vol 121 (4) ◽  
pp. 269-277 ◽  
Author(s):  
A. J. Hurford ◽  
F. J. Fitch ◽  
A. Clarke

AbstractModes in the frequency of distribution of fission track ages obtained from detrital zircon grains may prove characteristic of individual sandstone bodies, supporting the identification of the sources from which a particular flow of sedimentary detritus was derived and thus allowing new inferences to be made concerning palaeogeography. A computer program has been written and used to identify modes in the zircon fission track age distribution within two Lower Cretaceous sandstone samples from the Weald of southern England. Pronounced modes appear in one rock around 119 Ma, 160 Ma, 243 Ma and 309 Ma and in the other around 141 Ma, 175 Ma, 257 to 277 Ma and 394 to 453 Ma. The geological implications of these quite dissimilar zircon age spectra are discussed. It is concluded that they support the palaeogeographical models of Allen (1981) and indicate that the provenance of the first sample, from the Top Ashdown Sandstone member at Dallington in East Sussex, was almost entirely southerly, while that of the second, from the Netherside Sand member at Northchapel in West Sussex, was more varied, but predominantly westerly and northerly.


2004 ◽  
Vol 74 (1) ◽  
pp. 82-94 ◽  
Author(s):  
M. Bernet ◽  
M. T. Brandon ◽  
J. I. Garver ◽  
B. Molitor

1993 ◽  
Vol 30 (4) ◽  
pp. 764-768 ◽  
Author(s):  
John M. Murphy ◽  
Arne Bakke

Eight apatite and two zircon fission-track ages provide evidence of complex Tertiary thermal overprinting by hydrothermal fluids in the Gilmore Dome area. Five ages on apatite from the Fort Knox gold deposit average 41 Ma, one from the Stepovich prospect is 80 Ma, and two from Pedro Dome average 67 Ma. Elevations of these samples overlap but their ages do not, indicating that each area experienced a different thermal history.Ages of apatite from the Fort Knox gold deposit decrease with elevation from 42 to 36 Ma but have data trends indicative of complex cooling. Two ~51 Ma ages on zircon indicate that maximum temperatures approached or exceeded ~180 °C. An alteration assemblage of chalcedony + zeolite + calcite + clay in the deposit resulted from deposition by a paleo-hydrothermal system. The data suggest that the system followed a complex cooling path from > 180 to < 110 °C between 51 and 36 Ma, and that final cooling to below 60 °C occurred after ~25 Ma.The 80 Ma age from Stepovich prospect either resulted from cooling after intrusion of the underlying pluton (~90 Ma) or records postintrusion thermal overprinting sometime after ~50 Ma. The 67 Ma samples from Pedro Dome may also have experienced partial age reduction during later heating. The differences in the data from the different areas and the presence of a late alteration assemblage at Fort Knox suggest that the fluids responsible for heating were largely confined to the highly fractured and porous Fort Knox pluton.


2012 ◽  
Vol 66 (5) ◽  
pp. 545-551 ◽  
Author(s):  
Carlos Alberto Tello Sáenz ◽  
Eduardo Augusto Campos Curvo ◽  
Airton Natanael Coelho Dias ◽  
Cleber José Soares ◽  
Carlos José Leopoldo Constantino ◽  
...  

Studies of zircon grains using optical microscopy, micro-Raman spectroscopy, and scanning electron microscopy (SEM) have been carried out to characterize the surface of natural zircon as a function of etching time. According to the surface characteristics observed using an optical microscope after etching, the zircon grains were classified as: (i) homogeneous; (ii) anomalous, and (iii) hybrid. Micro-Raman results showed that, as etching time increases, the crystal lattice is slightly altered for homogeneous grains, it is completely damaged for anomalous grains, and it is altered in some areas for hybrid grains. The SEM (energy dispersive X-ray spectroscopy, EDS) results indicated that, independent of the grain types, where the crystallinity remains after etching, the chemical composition of zircon is approximately 33% SiO2:65% ZrO2 (standard natural zircon), and for areas where the grain does not have a crystalline structure, there are variations of ZrO2 and, mainly, SiO2. In addition, it is possible to observe a uniform surface density of fission tracks in grain areas where the determined crystal lattice and chemical composition are those of zircon. Regarding hybrid grains, we discuss whether the areas slightly altered by the chemical etching can be analyzed by the fission track method (FTM) or not. Results of zircon fission track and U-Pb dating show that hybrid and homogeneous grains can be used for dating, and not only homogeneous grains. More than 50 sedimentary samples from the Bauru Basin (southeast Brazil) were analyzed and show that only a small amount of grains are homogeneous (10%), questioning the validity of the rest of the grains for thermo-chronological evolution studies using zircon FTM dating.


1985 ◽  
Vol 56 ◽  
Author(s):  
J. K. ABROKWAH ◽  
H. HIBBS ◽  
R. R. DANIELS ◽  
P. JOSLYN

AbstractThe use of an AlGaAs/n-GaAs superlattice in place of the n-AlGaAs layer in MODFET devices reduces the light and temperature sensitivity of the threshold voltage. This paper considers the stability of Si doped superlattices under annealing conditions required for activation of the implant in the self-aligned gate MODFET fabrication process. Rapid optical annealing does not significantly degrade the superlattice structure. The DX center concentration in the superlattice structures is a factor of 30 less than measured in conventional MODFET structures. High performance MOOFET devices have been fabricated using the self-aligned gate process with rapid optical annealing.


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