Influence of pH, chloride ion concentration and spraying time on the corrosion behaviour of atmospheric plasma sprayed alumina coatings

2013 ◽  
Vol 30 (3) ◽  
pp. 183-194 ◽  
Author(s):  
D. Thirumalaikumarasamy ◽  
K. Shanmugam ◽  
V. Balasubramanian
2016 ◽  
Vol 16 (2) ◽  
pp. 89-102
Author(s):  
D. Thirumalai kumarasamy ◽  
K. Shanmugam ◽  
V. Balasubramanian ◽  
S. Vignesh

AbstractThe corrosion deterioration process of plasma sprayed alumina coatings on AZ31B magnesium alloy was investigated using immersion corrosion test in NaCl solution at different chloride ion concentrations, pH value and immersion time. The experiments were conducted based on a three factor, five level, central composite rotatable design matrix with full replications technique. Response surface methodology was used to develop the relationship. The developed relationship can be effectively used to predict the corrosion rate of plasma sprayed alumina coatings on AZ31B magnesium alloy at 95 % confidence level. The results showed that the corrosion deterioration of alumina coated magnesium alloy in NaCl solutions was significantly influenced by chloride ion concentration and pH value. The alumina coatings were found to be highly susceptible to localized damage, and could not provide an effective corrosion protection to Mg alloy substrate in solutions containing acidic environments (pH3), higher chloride concentrations and immersion time.


2021 ◽  
pp. 209-209
Author(s):  
Mathivanan Kannan ◽  
Thirumalaikumarasamy Duraisamy ◽  
Thirumal Pattabi ◽  
Ashokkumar Mohankumar

Stellite alloys are primarily preferred in various component manufacturing industries due to its magnificent mechanical and electrochemical properties. The stellite powder is deposited over the materials by Various thermal spray methods in industries. This research proposed investigating the microstructure and corrosion properties of stellite powder that is deposited on an AZ91D magnesium alloy substrate by atmospheric plasma spraying process. SEM, optical microscopy, and atomic force microscopy are typical of the coatings. Immersion experiments in sodium chloride conditions are conducted at varying pH levels, chloride ion concentration, and exposure time. In addition, XRD examined the phase change properties of the powder and sprayed condition of coatings along with corrosion testing. The corrosion experiments were conducted to establish several regression models based on the central composite design and the response surface process. The accuracy of the regression models was sufficient to allow correlations between input parameters and responses through variance analysis. It was found that the pH value significantly influences the corrosion behaviour of stellite coatings followed by other parameters such as chloride ion concentration and exposure time; even in corrosion tests, plasma-sprayed coatings performed better.


2019 ◽  
Vol 70 (7) ◽  
pp. 1214-1221
Author(s):  
Xinhong Xiong ◽  
Lianbo Chen ◽  
Kaixiong Hu ◽  
Zhiping Wang ◽  
Qiaoxin Zhang ◽  
...  

2015 ◽  
Vol 15 (2) ◽  
pp. 169-181 ◽  
Author(s):  
D. Thirumalaikumarasamy ◽  
K. Shanmugam ◽  
V. Balasubramanian

AbstractPlasma-sprayed alumina coatings find wide-ranging applications by virtue of their inherent wear and corrosion resistance and attractive dielectric and diffusion barrier properties. In this work, empirical relationships were developed to predict the porosity and microhardness of alumina coatings by incorporating independently controllable atmospheric plasma-sprayed operational parameters (input power, stand-off distance and powder feed rate) using response surface methodology (RSM). A central composite rotatable design with three factors and five levels was chosen to minimize the number of experimental conditions. Within the scope of the design space, the input power and the stand-off distance appeared to be the most significant two parameters affecting the responses among the three investigated process parameters. A linear regression relationship was also established between porosity and microhardness of the alumina coatings.


2008 ◽  
Vol 50 (11) ◽  
pp. 3168-3178 ◽  
Author(s):  
Ming-Chun Zhao ◽  
Ming Liu ◽  
Guang-Ling Song ◽  
Andrej Atrens

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