Mechanical, Thermal, and Degradation Properties of Linear Low-Density Polyethylene/Polyvinyl Alcohol/Kenaf Bast Powder Composites

Author(s):  
A.L. Pang ◽  
H. Ismail ◽  
A.B. Azhar
2013 ◽  
Vol 795 ◽  
pp. 433-437 ◽  
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
O.H. Lin ◽  
H. Ismail

Soya spent powder as an inexpensive and renewable source has been used as a filler for linear-low density polyethylene (LLDPE) in this study. Linear-low density polyethylene (LLDPE)/soya spent powder composites were prepared by using Haake internal mixer. The mixing time was 10 minutes at 150°C with rotor speed 50 rpm. Epoxidised natural rubber (ENR 50) has been used as a compatibilizer in the present study. The thermal properties of the LLDPE/soya spent powder composites with and without ENR were studied with a differential scanning calorimetry (DSC). The crystallinity of the LLDPE/soya spent powder composites decreased with increasing soya spent powder content. However, the addition of ENR 50 as a compatibilizer increased the crystallinity of the LLDPE/soya spent powder composites.


2018 ◽  
Vol 1019 ◽  
pp. 012060 ◽  
Author(s):  
Abduati Alnaid ◽  
N Z Noriman ◽  
Omar S Dahham ◽  
R Hamzah ◽  
Marwa N Al-Samarrai ◽  
...  

BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 8648-8661
Author(s):  
Ai Ling Pang ◽  
Agus Arsad ◽  
Mohsen Ahmadipour ◽  
Hanafi Ismail ◽  
Azhar Abu Bakar

In recent decades, natural fibers have become widely used with petroleum based polymers such as polyethylene (PE) and polypropylene (PP) because of their light weight, lower cost, and inherent biodegradability. In the present work, linear low-density polyethylene/polyvinyl alcohol (LLDPE/PVOH) composites with untreated kenaf and silane-treated kenaf at filler loadings of 0, 10, and 40 phr were prepared via the melt mixing process. The soil burial test was used to evaluate the degradability of the composites for different durations (90 and 180 d). The tensile properties, surface morphology, chemical composition, percentage of weight loss, and crystallinity of the composites before and after degradation were evaluated. With increased kenaf loading and soil burial duration, all the composites showed a decrease in tensile properties. This was further confirmed by the changes in surface morphology and chemical structure of the buried composites. The increase in weight loss percentage and crystallinity after soil burial indicated that the longer burial duration had increased the degradation of composites. Composites with silane-treated kenaf exhibited lower degradability than that of composites with untreated kenaf after being buried for 90 and 180 d. This may be attributed to the improved adhesion of kenaf to the LLDPE/PVOH matrix via silane treatment.


2010 ◽  
Vol 123-125 ◽  
pp. 415-418 ◽  
Author(s):  
Mubarak A. Khan ◽  
Rafiqul Islam ◽  
Towhidul Islam ◽  
Farah Nigar ◽  
Nazia Rahman ◽  
...  

Composites containing various amounts of LLDPE (Linear Low Density Polyethylene) and clay (0, 1, 5, 10, 20 and 30% of clay) were prepared using two different types of clay (Bijoypur white clay and China clay) by extrusion technique followed by compression molding. Tensile strength (TS) & tensile modulus (TM) of pure LLDPE were found to be 9.8 MPa & 175 MPa respectively. For both types of clay TS, Eb% was gradually decreased but TM was gradually increased with increasing the percentage of clay in LLDPE/clay composites. The effects of ionizing (gamma) and non-ionizing (UV) radiations on the mechanical properties of LLDPE/clay composites were studied. The composites irradiated under UV & gamma radiation showed higher TS than that of non-irradiated one. Thermal degradation of the composites was studied at different temperatures. Water uptake of the composites was found negligible.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1537
Author(s):  
Luděk Hynčík ◽  
Petra Kochová ◽  
Jan Špička ◽  
Tomasz Bońkowski ◽  
Robert Cimrman ◽  
...  

Current industrial trends bring new challenges in energy absorbing systems. Polymer materials as the traditional packaging materials seem to be promising due to their low weight, structure, and production price. Based on the review, the linear low-density polyethylene (LLDPE) material was identified as the most promising material for absorbing impact energy. The current paper addresses the identification of the material parameters and the development of a constitutive material model to be used in future designs by virtual prototyping. The paper deals with the experimental measurement of the stress-strain relations of linear low-density polyethylene under static and dynamic loading. The quasi-static measurement was realized in two perpendicular principal directions and was supplemented by a test measurement in the 45° direction, i.e., exactly between the principal directions. The quasi-static stress-strain curves were analyzed as an initial step for dynamic strain rate-dependent material behavior. The dynamic response was tested in a drop tower using a spherical impactor hitting a flat material multi-layered specimen at two different energy levels. The strain rate-dependent material model was identified by optimizing the static material response obtained in the dynamic experiments. The material model was validated by the virtual reconstruction of the experiments and by comparing the numerical results to the experimental ones.


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