F–CN Bond Cleavage by Iron Silyl Complex and Electronic Effect of the Group or Atom Attached to Cyano Group: A Theoretical DFT Study

2013 ◽  
Vol 86 (2) ◽  
pp. 273-275 ◽  
Author(s):  
AbdelRahman A. Dahy ◽  
Nobuaki Koga
Keyword(s):  
Electronic Effect ◽  
Cyano Group ◽  
Bond Cleavage ◽  
Dft Study ◽  
Group A ◽  
Silyl Complex

BiCl3-Facilitated removal of methoxymethyl-ether/ester derivatives and DFT study of –O–C–O– bond cleavage

2021 ◽  
Vol 45 (16) ◽  
pp. 7109-7116
Author(s):  
Angela Pacherille ◽  
Beza Tuga ◽  
Dhanashree Hallooman ◽  
Isaac Dos Reis ◽  
Mélodie Vermette ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Dft Study ◽  
Ether Ester

An experimental and DFT study of the cleavage of the MOM group mediated by an eco-friendly reagent, bismuth trichloride.

Catalytic Cycle for N–CN Bond Cleavage by Molybdenum Silyl Catalyst: A DFT Study

2013 ◽  
Vol 32 (9) ◽  
pp. 2725-2735 ◽  
Author(s):  
AbdelRahman A. Dahy ◽  
Nobuaki Koga ◽  
Hiroshi Nakazawa
Keyword(s):  
Bond Cleavage ◽  
Catalytic Cycle ◽  
Dft Study

Facile N≡N Bond Cleavage by Anionic Trimetallic ClustersV3‐xTaxC4– (x = 0‐3): A DFT Study

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Ya-Ya Wang ◽  
Xunlei Ding ◽  
Joseph Israel Gurti ◽  
Yan Chen ◽  
Xue-Qian Huang ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Dft Study

Iminyl-Radical-Triggered C–C Bond Cleavage of Cycloketone Oxime Derivatives: Generation of Distal Cyano-Substituted Alkyl Radicals and Their Functionalization

Synthesis ◽  
2020 ◽  
Vol 52 (11) ◽  
pp. 1585-1601 ◽  
Author(s):  
Tiebo Xiao ◽  
Lei Zhou ◽  
Hongtai Huang ◽  
Devireddy Anand
Keyword(s):  
Halogen Bond ◽  
Cyano Group ◽  
Bond Cleavage ◽  
Bond Formation ◽  
Radical Reaction ◽  
Building Blocks ◽  
Aromatic Rings ◽  
Organometallic Reagents ◽  
Alkyl Radicals ◽  
Oxime Derivatives

Alkyl nitriles are versatile building blocks in organic synthesis because the cyano group can be easily converted into other functional groups. Iminyl-radical-triggered C–C bond cleavage of cycloketone oxime­ derivatives provides a practical route to access distal cyano-substituted alkyl radicals, which has given chemists a new radical reaction platform for the synthesis of diverse alkyl nitriles. This review provides an overview of various types of radical cyanoalkylation via ring opening of cycloketone oxime derivatives.1 Introduction2 C–C Bond Formation2.1 Alkenes as Radical Acceptors2.2 Aromatic Rings as Radical Acceptors2.3 Organometallic Reagents as Radical Acceptors2.4 Cyanoalkyl-Radical-Triggered Cyclization Reactions2.5 Miscellaneous3 C–Heteroatom Bond Formation3.1 C–O Bond Formation3.2 C–N Bond Formation3.3 C–S Bond Formation3.4 C–Halogen Bond Formation3.5 C–B Bond Formation4 Conclusion

Oxidative Addition Promoted C–C Bond Cleavage in Rh-Mediated Cyclopropenone Activation: A DFT Study

ACS Catalysis ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 10876-10886 ◽  
Author(s):  
Yixin Luo ◽  
Chunhui Shan ◽  
Song Liu ◽  
Tao Zhang ◽  
Lei Zhu ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Oxidative Addition ◽  
Dft Study

Reversible carbon-silicon bond cleavage in the methylene/silyl complex Cp*2Ru2(.mu.-CH2)(.mu.-Cl)(SiMe3)

1993 ◽  
Vol 115 (7) ◽  
pp. 3022-3023 ◽  
Author(s):  
Wenbin Lin ◽  
Scott R. Wilson ◽  
Gregory S. Girolami
Keyword(s):  
Bond Cleavage ◽  
Silyl Complex

The Mechanism of Nucleophilic Displacements at Phosphorus in Chloro-Substituted Methylphosphonate Esters: P−O vs P−C Bond Cleavage: A DFT Study

2010 ◽  
Vol 75 (6) ◽  
pp. 1917-1926 ◽  
Author(s):  
Nissan Ashkenazi ◽  
Yoffi Segall ◽  
Ravit Chen ◽  
Gali Sod-Moriah ◽  
Eyal Fattal
Keyword(s):  
Bond Cleavage ◽  
Dft Study

A Mechanistic Investigation of the Carbon−Carbon Bond Cleavage of Aryl and Alkyl Cyanides Using a Cationic Rh(III) Silyl Complex

2003 ◽  
Vol 125 (32) ◽  
pp. 9808-9813 ◽  
Author(s):  
Felicia L. Taw ◽  
Alexander H. Mueller ◽  
Robert G. Bergman ◽  
Maurice Brookhart
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Mechanistic Investigation ◽  
Silyl Complex
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