Low-temperature Hydrogen-selective Catalytic Reduction of NOxon Pt/Sulfated-ZrO2Catalysts under Excess Oxygen Conditions

2008 ◽  
Vol 37 (12) ◽  
pp. 1210-1211 ◽  
Author(s):  
Makoto Saito ◽  
Masahiro Itoh ◽  
Jun Iwamoto ◽  
Ken-ichi Machida
2013 ◽  
Vol 295-298 ◽  
pp. 364-369 ◽  
Author(s):  
Jun Lin Xie ◽  
Zheng Bing Fu ◽  
Feng He ◽  
De Fang

Amorphous phase MnOx/TiO2 catalysts were prepared by two different methods, their catalytic activities for low temperature selective catalytic reduction (SCR) of NOx with NH3 in the presence of excess oxygen were investigated. The catalysts were characterized by XRD, XPS and HRTEM. The results showed that the catalyst prepared by soft template method had better catalytic active than those prepared by sol-gel method, its catalytic property could reach 98.2% at 200°C. From the microstructure characterization, it could be known that the catalyst prepared by soft template had the shape of nanorod, this shape was contributed to the dispersion of the manganese oxides and possessed higher surface lattice oxygen concentration. Furthermore, narrow slit-shaped pores associated with rod-like particles could provide efficient transport pathways to reactant molecules and products. Due to these, the catalyst performed catalytic active very well.


RSC Advances ◽  
2018 ◽  
Vol 8 (73) ◽  
pp. 42017-42024 ◽  
Author(s):  
Zhicheng Han ◽  
Qingbo Yu ◽  
Zhijia Xue ◽  
Kaijie Liu ◽  
Qin Qin

Trace amount of Sm-doped Mn-based Zr–Fe polymeric pillared interlayered montmorillonite promotes low temperature catalytic activity in excess oxygen.


2011 ◽  
Vol 233-235 ◽  
pp. 1564-1567
Author(s):  
Zhi Hang Chen ◽  
Xue Hui Li ◽  
Chao Ping Cen ◽  
Xiang Gao ◽  
Le Fu Wang

The solid state reaction method, coprecipitation method and citric acid method were employed for the preparation of Cr-Mn mixed-oxide catalysts. Experimental results showed that this catalytic system has good selective catalytic reduction (SCR) properties of NOxby ammonia in the presence of excess oxygen at low temperature (80-220°C). 97.8% conversion of NOxwith 100% selectivity of N2had been achieved on Cr-MnOxmixed oxide prepared by the citric acid method at 120°C with the space velocity of 30,000 h-1. X-ray diffraction, BET were adopted for the characterization of the active phase. The characterization results showed that a new crystal phase CrMn1.5O4generated in mixed oxides which was the active center of the Cr-Mn catalysts.


RSC Advances ◽  
2017 ◽  
Vol 7 (51) ◽  
pp. 32146-32154 ◽  
Author(s):  
Chengkai Pang ◽  
Yuqun Zhuo ◽  
Qiyu Weng

A series of Mn-exchanged SAPO-34 catalysts were synthesized and developed as catalysts for the low temperature selective catalytic reduction (SCR) of NO with ammonia in the presence of excess oxygen.


2012 ◽  
Vol 27 (5) ◽  
pp. 495-500 ◽  
Author(s):  
Da-Wang WU ◽  
Qiu-Lin ZHANG ◽  
Tao LIN ◽  
Mao-Chu GONG ◽  
Yao-Qiang CHEN

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