scholarly journals Development of Novel Methodology Using Diazo Compounds and Metal Catalysts

2021 ◽  
Vol 69 (12) ◽  
pp. 1170-1178
Author(s):  
Shingo Harada
Keyword(s):  
Metal Catalysts ◽  
Diazo Compounds

scholarly journals The Power of Iron Catalysis in Diazo Chemistry

Synthesis ◽  
2020 ◽  
Vol 53 (01) ◽  
pp. 79-94
Author(s):  
Thierry Ollevier ◽  
Virginie Carreras ◽  
Nour Tanbouza
Keyword(s):  
Short Review ◽  
Metal Catalysts ◽  
Diazo Compounds ◽  
Cycloaddition Reactions ◽  
Insertion Reactions ◽  
Iron Catalysis ◽  
Recent Advances ◽  
Olefination Reactions

AbstractThe use of iron catalysis to enable reactions with diazo compounds has emerged as a valuable tool to forge carbon–carbon or carbon–heteroatom bonds. While diazo compounds are often encountered with toxic and expensive metal catalysts, such as Rh, Ru, Pd, Ir, and Cu, a resurgence of Fe catalysis has been observed. This short review will showcase and highlight the recent advances in iron-mediated reactions of diazo compounds.1 Introduction2 Insertion Reactions2.1 Insertion into B–H Bonds2.2 Insertion into Si–H Bonds2.3 Insertion into N–H Bonds2.4 Insertion into S–H bonds3 Ylide Formation and Subsequent Reactions3.1 Doyle–Kirmse Rearrangement3.2 [1,2]-Stevens and Sommelet–Hauser Rearrangements3.3 Olefination Reactions3.4 Cycloaddition Reactions3.5 gem-Difluoroalkenylation4 Three-Component Reactions5 Miscellaneous6 Conclusion

Formaldehyde Synthesis over Foam Metal Catalysts

2016 ◽  
Vol 14 (999) ◽  
pp. 1-1
Author(s):  
Alexey Pestryakov ◽  
Valerii Lunin
Keyword(s):  
Metal Catalysts ◽  
Foam Metal ◽  
Formaldehyde Synthesis

Chemoselective Oxidation of Bio-Glycerol with Nano-Sized Metal Catalysts

2015 ◽  
Vol 12 (2) ◽  
pp. 162-177 ◽  
Author(s):  
Hu Li ◽  
Ramakrishna Kotni ◽  
Qiuyun Zhang ◽  
Saravanamurugan Shunmugavel ◽  
Song Yang
Keyword(s):  
Metal Catalysts

Styrene-divinylbenzene polymer oxidation catalyst

1981 ◽  
Vol 46 (11) ◽  
pp. 2657-2662
Author(s):  
Zdeněk Prokop ◽  
Karel Setínek
Keyword(s):  
Functional Groups ◽  
Noble Metal ◽  
Additional Data ◽  
Catalytic Properties ◽  
Metal Catalysts ◽  
Oxidation Catalyst ◽  
Noble Metal Catalysts ◽  
Polymer Catalyst ◽  
Styrene Divinylbenzene ◽  
Polymer Oxidation

Some additional data about properties and applicability of a styrene-divinylbenzene polymer catalyst containing acidic and redox functional groups are reported. It is shown that the catalysts of this type can be prepared reproducibly and exhibit catalytic properties comparable to the properties of noble metal catalysts.

New catalysts for the reduction of aromatic diazo compounds by alcohols to hydrocarbons

1983 ◽  
Vol 32 (4) ◽  
pp. 858-861 ◽  
Author(s):  
V. S. Lenenko ◽  
A. P. Borisov ◽  
V. D. Makhaev ◽  
E. I. Mysov ◽  
V. B. Shur ◽  
...  
Keyword(s):  
Diazo Compounds

Boosting electrochemical nitrogen reduction reaction performance of two-dimensional Mo porphyrin monolayers via turning the coordination environment

2021 ◽  
Vol 23 (7) ◽  
pp. 4178-4186
Author(s):  
Shiqiang Liu ◽  
Zhiwen Cheng ◽  
Yawei Liu ◽  
Xiaoping Gao ◽  
Yujia Tan ◽  
...  
Keyword(s):  
Energy Conversion ◽  
Reduction Reaction ◽  
Metal Catalysts ◽  
Two Dimensional ◽  
Coordination Environment ◽  
Nitrogen Reduction ◽  
Reaction Performance ◽  
Conversion Efficiencies

Designing atomically dispersed metal catalysts for the nitrogen reduction reaction (NRR) is an effective approach to achieve better energy conversion efficiencies.

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