scholarly journals Adsorption and Desorption Behavior of Herbicide Mefenpyr-diethyl in the Agricultural Soils of Morocco

2018 ◽  
Vol 7 (5) ◽  
pp. 386-395 ◽  
Author(s):  
Abdellah El Boukili ◽  
Nidae Loudiyi ◽  
Ahmed El Bazaoui ◽  
Abderrahim El Hourch ◽  
M'Hamed Taibi ◽  
...  
Keyword(s):  
Organic Matter ◽  
Adsorption Capacity ◽  
Agricultural Soils ◽  
Organic Matter Content ◽  
Matter Content ◽  
Isotherm Models ◽  
Desorption Process ◽  
Adsorption And Desorption ◽  
Total Percentage ◽  
Adsorption Isotherm Models

The present study was conducted in order to investigate the adsorption and desorption behavior of Mefenpyr-diethyl (MFD) using the batch equilibration technique in four soils, with different ranges of organic matter content, from different regions of Morocco orders of Benimellal (Soil 1), Settat (Soil 2), Sidi Bettach (Soil 3) and EL Hajeb (Soil 4). The adsorption isotherm models Langmuir, linear and Freundlich were used to compare the adsorption capacity of the soils. The results indicated that the Freundlich equation provided the best fit for all adsorption data. The values of KF and Kd ranged from 4.45 to 15.9 and 4.30 to 18.30 L.kg-1 , respectively. The calculated total percentage of desorption values from the Soil 1, Soil 2, Soil 3 and Soil 4 after the four desorption process were 59 %; 55,6 %; 37,5 % and 52,5%, respectively. Highest adsorption and desorption were observed in soil 1, and the lowest was in soil 3. According to the adsorption and desorption results, organic matter and clay seemed to be the most important factors influencing the adsorption capacity of MFD.

Plastic limits of agricultural soils as functions of soil texture and organic matter content

Soil Research ◽  
2012 ◽  
Vol 50 (1) ◽  
pp. 7 ◽  
Author(s):  
Thomas Keller ◽  
Anthony R. Dexter
Keyword(s):  
Organic Matter ◽  
Soil Texture ◽  
Agricultural Soils ◽  
Organic Matter Content ◽  
Clay Content ◽  
Liquid Limit ◽  
Matter Content ◽  
Pedotransfer Functions ◽  
Strongly Correlated ◽  
Yield Information

The plastic limits (lower plastic limit, PL; and liquid limit, LL) are important soil properties that can yield information on soil mechanical behaviour. The objective of this paper is to study the plastic limits of agricultural soils as functions of soil texture and organic matter (OM) content. The plastic limits were highly related to the clay content. The LL was more strongly correlated with clay than was PL, but the reasons are unclear. Interestingly, PL was virtually unaffected by clay content for soils with clay contents below ~35%. The OM had a strong effect on the plastic limits. This effect was clearly demonstrated when analysing soils of similar texture with a range of OM. We present equations (pedotransfer functions) for estimation of PL, LL, and plasticity index (PI) from soil texture and OM. Finally, we predict that the clay content must be ≥10% for soils without OM to be plastic; however, soils with <10% clay can be plastic if OM is present. More research is needed to investigate OM effects on soil consistency.

scholarly journals Examination of zinc adsorption capacity of soils treated with different pyrolysis products

2014 ◽  
Vol 6 (1) ◽  
pp. 33-38
Author(s):  
Gabriella Rétháti ◽  
Adrienn Vejzer ◽  
Barbara Simon ◽  
Ramadan Benjared ◽  
György Füleky
Keyword(s):  
Organic Matter ◽  
Adsorption Capacity ◽  
Solid Phase ◽  
Organic Matter Content ◽  
Pyrolysis Product ◽  
Matter Content ◽  
Pyrolysis Products ◽  
Bone Ash ◽  
Original Product ◽  
Zinc Adsorption

Abstract Organic matter input into soils is essential regarding agricultural, environmental and soil science aspects as well. However, the application of the pyrolysed forms of biochars and materials with different organic matter content gained more attention in order to decrease the emission of the green house gases (CO2, N2O) from the soil. During pyrolysis, the materials containing high organic matter (biomass-originated organic matter) are heated in oxygen-free (or limited amount of oxygen) environment. As a result, the solid phase, which remains after eliminating the gases and liquid phase, is more stable compared to the original product, it cannot be mineralized easily in the soil and its utilization is more beneficial in terms of climatic aspects. Furthermore, it can improve soil structure and it can retain soil moisture and cations in the topsoil for long periods of time, which is very important for plants. In our experiment, the effects of biochar and bone char were examined on soils by zinc adsorption experiments. Based on our experiments, we concluded that the pyrolysis products can have significant Zn adsorption capacity compared to the soil. Bone ash can adsorb more Zn than the charcoal product. The Zn adsorption capacity of soils treated by pyrolysis products can be described by Langmuir adsorption isotherms. However, based on the amount of pyrolysis products, one or two term Langmuir isotherm fits well on the experiment data, which depends on the time the pyrolysis product has spent in the soil.

scholarly journals Sorption Behavior of Lead (Pb) onto Agricultural Soils of Khyber Pakhtunkhwa, ‎Pakistan: Potentials for Leaching

2021 ◽  
Author(s):  
Iqbal Ahmad ◽  
Bushra Khan ◽  
Nida Gul ◽  
Muhammad Khan ◽  
Javaid Iqbal ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Texture ◽  
Agricultural Soils ◽  
Organic Matter Content ◽  
Sorption Isotherms ◽  
Matter Content ◽  
Sorption Behavior ◽  
Silty Clay ◽  
Clay Loam

Abstract Lead (Pb) contamination in soil and subsequent transport in groundwater poses severe threats to the food safety and human health. In current study, the effects of soil organic matter on sorption behavior of Pb onto six agricultural soils were investigated by batch sorption experiments and microscopic characterization. Results indicated that Pb sorption onto agricultural soils was dominated by the soil organic matter content and soil texture. The decrease of organic matter content reduced the sorption capacity of Pb onto agricultural soils. Based on soil texture, the Pb sorption was highest in clay soil and lowest in silt type of soil. The overall Pb sorption was in the order of clay > clay loam > silty clay loam ≈ loam > silt loam > silt. The sorption isotherms of measured aqueous and soil phase Pb concentrations were fit well with the linear sorption model. The organic carbon normalized partition coefficients (Log KOC) ranged from 2.90 to 2.99. Linear partition coefficient (Kd) values were positively correlated with the soil properties, such as clay (R2 =0.90), OC (R2 =0.94) and pH (R2 = 0.45); however, weak correlation was found between Kd and soil sand contents (R2 = 0.12). The leachability model showed potential risk of Pb leaching from silt soil with lowest organic matter content. The findings are of significant importance for understanding potential threats of Pb to the soil ecosystem, groundwater, plants, and humans.

scholarly journals Adsorption and Degradation Behavior of Six Herbicides in Different Agricultural Soils.

2021 ◽  
Author(s):  
Umrbek Sharipov ◽  
Martin Kočárek ◽  
Miroslav Jursík ◽  
Antonín Nikodem ◽  
Luboš Borůvka
Keyword(s):  
Organic Matter ◽  
Agricultural Soils ◽  
Negative Relationship ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Matter Content ◽  
Sorption Coefficient ◽  
The Czech Republic ◽  
Degradation Rates ◽  
Agricultural Regions

Abstract This study focuses on the assessment of herbicide adsorption and degradation in three soils (Haplic Chernozem, Haplic Fluvisol, and Arenic Regozem) from different agricultural regions of the Czech Republic where sunflower is cultivated. Soil samples were used in laboratory batch sorption and degradation experiments for six herbicides commonly used on sunflower crops. The findings are used to examine the effect of soil and herbicide properties on adsorption and degradation, as well as to determine the possible relation between the two processes. The (Kf) sorption coefficient ranged from 1.07 to 135.37 cm3/n μg1-1/n g-1, and sorption increased in order: dimethenamid-p < pethoxamid < s-metolachlor < flurochloridone < aclonifen < pendimethalin. Sorption of all six herbicides was positively correlated with organic matter content (p < 0. 001), and cation exchange capacity (p < 0.001). pH was negatively correlated with the sorption of all six compounds (p < 0.001). Degradation rates of herbicides ranged from 0. 012 to 0. 048 day-1, which corresponding to (DT50) half-lives between 14 - 57 days respectively. The longer half-lives were always found in Haplic Fluvisol with higher organic matter content. Results showed that both adsorption and degradation of herbicides is mainly controlled by soil organic matter. A negative relationship was found between the sorption coefficient and the rate of degradation. It can be concluded that the Freundlich sorption coefficient (Kf) can be a good predictor for soil degradation of the studied herbicides.

scholarly journals The relationship between soil properties, enzyme activity and land use

2017 ◽  
Vol 78 (1) ◽  
pp. 39-44 ◽  
Author(s):  
Ewa Błońska ◽  
Jarosław Lasota ◽  
Maciej Zwydak
Keyword(s):  
Land Use ◽  
Organic Matter ◽  
Enzyme Activity ◽  
Soil Properties ◽  
Agricultural Soils ◽  
Vegetation Type ◽  
Organic Matter Content ◽  
Matter Content ◽  
Carbon And Nitrogen ◽  
The Relationship

Abstract The aim of this study was to assess the effects of different types of land use (forest, tillage and pasture) on soil properties, especially enzyme activity. Our investigation was carried out on 53 research plots with 11 plots in broadleaved forest stands, 12 plots in mixed broadleaved stands, 10 plots in mixed coniferous stands, 9 plots on tillage and 11 plots on pasture. The soil samples were collected from a depth of 0–15 cm after removing the organic horizon. Contents of organic carbon and nitrogen, pH and soil texture were investigated. Furthermore, dehydrogenase and urease activity were determined. Significant differences in the enzyme activity between forest and agricultural soils were observed, thus demonstrating that enzyme activity is influenced by the organic matter content of the soil. The highest enzyme activity was recorded in the forest soil within broadleaved stands, whilst the lowest activity was found in tillage soil, because tillage soil contained significantly less organic matter. High enzymatic activity of pasture soils is the combined result of vegetation type and the lack of plowing.

scholarly journals Low mobility of CuO and TiO2 nanoparticles in agricultural soils of contrasting texture and organic matter content

2021 ◽  
Vol 783 ◽  
pp. 146952
Author(s):  
Marie Simonin ◽  
Jean M.F. Martins ◽  
Gaëlle Uzu ◽  
Lorenzo Spadini ◽  
Aline Navel ◽  
...  
Keyword(s):  
Organic Matter ◽  
Tio2 Nanoparticles ◽  
Agricultural Soils ◽  
Organic Matter Content ◽  
Matter Content

scholarly journals Changes in soil microbial activity and physicochemical properties in agricultural soils in Eastern Spain

2015 ◽  
Vol 5 ◽  
Author(s):  
Alicia Morugán-Coronado ◽  
Fuensanta García-Orenes ◽  
Artemi Cerdà
Keyword(s):  
Organic Matter ◽  
Soil Properties ◽  
Land Management ◽  
Management Practices ◽  
Agricultural Soils ◽  
Organic Matter Content ◽  
Matter Content ◽  
Microbial Properties ◽  
Soil Microbial ◽  
Citrus Orchards

Agricultural land management greatly affects soil properties. Microbial soil communities are the most sensitive and rapid indicators of perturbations in land use and soil enzyme activities are sensitive biological indicators of the effects of soil management practices. Citrus orchards frequently have degraded soils and this paper evaluates how land management in citrus orchards can improve soil quality. A field experiment was performed in an orchard of orange trees (<em>Citrus Sinensis</em>) in the Alcoleja Experimental Station (Eastern Spain) with clay-loam agricultural soils to assess the long-term effects of herbicides with inorganic fertilizers (H), intensive ploughing and inorganic fertilizers (P) and organic farming (O) on the soil microbial properties, and to study the relationship between them. Nine soil samples were taken from each agricultural management plot. In all the samples physicochemical parameters, basal soil respiration, soil microbial biomass carbon, microbial indexes (BSR/C, Cmic/C and BSR/Cmic) and enzymatic activities (urease, dehydrogenase, ß-glucosidase and acid phosphatase) were determined. The results showed significant differences between the different agricultural management practices for the microbial properties and soil microbial indexes, since these were strongly associated with the soil organic matter content. Unlike herbicide use and intensive ploughing  - management practices that both showed similar microbial soil properties -  the organic management practices contributed to an increase in the soil biology quality, aggregate stability and organic matter content.

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