Structural hydroxyl distribution in jadeite grains and the diagenesis mechanism of jadeitite in Myanmar, Guatemala and Russia

2021 ◽  
Vol 63 (3) ◽  
pp. 235-244
Author(s):  
Xing Yingying ◽  
Qi Lijian

Abstract Carrying out jadeitite diagenesis in its basic state as well as in combination with the multiple fluid activities of water, we focused on jadeite grains in production areas such as Myanmar, Guatemala and Russia to determinethe essence of nominal anhydrous jadeite grains and the distribution of structural hydroxyl in individual jadeite grains via infrared microscope. This is a scientific problem that urgently needs to be solved. The results show that a microscale of structural water in the form of structural hydroxyl is widely found in the jadeite grains of primary jadeitite in Myanmar, Guatemala and Russia. There are certain differences in the three groups of characteristic infrared absorption bands generated by the stretching vibration of the structural hydroxyl in jadeite from these different producing areas. The structural hydroxyl content of the individual jadeite grain shows obvious differences according to the producing areas, and the structural hydroxyl content in jadeite grains in Myanmar is up to 2522.11 × 10-6. By contrast, jadeite grains in Guatemala and Russia yield lower results. In addition, the structural hydroxyl content in individual jadeite grains in the three producing areas are inhomogeneous, showing an increasing trend from interior to exterior. However, dynamic metamorphism of different intensities and multi-period fluid participation lead to differences in the increase, whereby an increase in structural hydroxyl content in jadeite grains from Guatemala and Russia is slower. The study of the distribution of structural hydroxyl in jadeite grain from different producing areas is helpful for exploring the interaction trajectory of fluids involved in jadeitite and the diagenesis mechanism of jadeitite, a fact that is of great scientific significance for revealing the formation process and conditions of jadeitite.

1990 ◽  
Vol 44 (1) ◽  
pp. 69-75 ◽  
Author(s):  
Robert L. White ◽  
Aurobindo Nair

Diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS) is employed to study the dehydroxylation of amorphous silica. Dehydroxylation results in the appearance of infrared absorption bands at 1022, 1107, and 1240 cm−1 assigned to asymmetric stretching vibrations for three different siloxane bridge types. The 1107-cm−1 absorbance band represents a siloxane bridge that is indistinguishable from bulk species. The 1022-cm−1 absorbance band represents a siloxane bridge with a bond angle that is smaller than the bulk, with little change in the stretching vibration force constant. The 1240-cm−1 absorbance band derives from a siloxane bridge characterized by a stretching force constant significantly larger than that of bulk siloxane bridges. This band may be indicative of a highly strained or broken siloxane bridge.


2005 ◽  
Vol 59 (9) ◽  
pp. 1160-1165 ◽  
Author(s):  
Sanong Ekgasit ◽  
Pimthong Thongnopkun

A novel transflectance technique using an infrared microscope was employed for spectral acquisition of loose and mounted faceted diamonds. The observed transflectance spectrum shows the same spectral features as those of the well-accepted diffuse reflectance spectrum. Unlike the diffuse reflectance spectrum, the transflectance spectrum was not affected by the diamond arrangements. The technique can be employed for direct spectra acquisition of mounted diamonds without taking the diamonds out of the jewelry bodies. Moreover, an individual diamond on a complex jewelry setting can be selectively measured. Infrared absorption bands unique to the chemical compositions, impurities, and treatment processes of the diamonds are discussed. The observed transflectance spectra can be exploited for diamond classification.


1998 ◽  
Vol 7 (11-12) ◽  
pp. 1657-1662 ◽  
Author(s):  
M.A. Djouadi ◽  
S. Ilias ◽  
D. Bouchier ◽  
J. Pascallon ◽  
G. Sené ◽  
...  

1980 ◽  
Vol 72 (4) ◽  
pp. 2356-2363 ◽  
Author(s):  
E. Zouboulis ◽  
N. D. Bhaskar ◽  
A. Vasilakis ◽  
W. Happer

2003 ◽  
Vol 799 ◽  
Author(s):  
M. H. Kane ◽  
R. Varatharajan ◽  
Z. C. Feng ◽  
S. Kandoor ◽  
J. Nause ◽  
...  

ABSTRACTIn this work, we report on the material properties of ZnO doped with Mn, Co, and Fe grown by a modified melt growth technique. X-ray diffraction measurements show that transition metals can be incorporated on Zn sites; an increase in the lattice parameter is apparent with increasing doping level. UV-visible transmission and reflectance measurements have also been performed. Absorption bands in the visible regime are distinctive to the individual transition metal dopants. A noticeable shift in the optical band edge has been observed from these Mn/Co/Fe-doped ZnO crystals in comparison with the undoped material. ZnO may also provide a suitable platform for the incorporation of transition metal elements through high temperature near equilibrium growth processes; however, further work is required in order to employ these materials for spintronic applications.


Sign in / Sign up

Export Citation Format

Share Document