scholarly journals GeSe nanosheets modified surface plasmon resonance sensors for enhancing sensitivity

Nanophotonics ◽  
2020 ◽  
Vol 9 (2) ◽  
pp. 327-336 ◽  
Author(s):  
Yuting Zhao ◽  
Shuaiwen Gan ◽  
Leiming Wu ◽  
Jiaqi Zhu ◽  
Yuanjiang Xiang ◽  
...  

AbstractGermanium selenide (GeSe) nanosheets are stable and inexpensive and considered to have a great potential for photovoltaic applications, however we have demonstrated that GeSe nanosheets are also promising for sensing technology, in this paper. By spin-coating the GeSe nanosheets on the surface of noble metal (Au), we have obtained a surface plasmon resonance (SPR) sensor with significantly enhanced sensitivity, and the performance of the sensor is closely related to the thickness of the GeSe film. By detecting different refractive index solutions, we have obtained the optimized sensitivity with 3581.2 nm/RIU (which is nearly 80% improvement compared to traditional SPR sensors) and figure of merit with 14.37 RIU−1. Moreover, the proposed SPR sensor was vastly superior in sensing Pb2+ heavy metal ions after coating it with chitosan and GeSe composite. A maximum sensitivity of 30.38 nm/μg/l has been verified, which is nearly six times better than that of conventional SPR sensor. Our results demonstrated that GeSe nanosheets overlayer with modified SPR sensor has its great potential in heavy metal detection and chemical-specific molecular identification.

Nanophotonics ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 1941-1951
Author(s):  
Jiaqi Zhu ◽  
Yuxuan Ke ◽  
Jianfeng Dai ◽  
Qi You ◽  
Leiming Wu ◽  
...  

AbstractSurface plasmon resonance (SPR) sensors have been applied in a wide range of applications for real-time and label-free detection. In this article, by covering the topological insulators nanosheets on the surface of the noble metal (Au), the sensitivity of the SPR sensor is greatly enhanced because of the strong interaction of light with Au–bismuth selenide (Bi2Se3) heterostructure. It is shown that the sensitivity of proposed SPR sensors depends on the concentration of Bi2Se3 solution or the thickness of the coated Bi2Se3 film. The optimised sensitivity (2929.1 nm/RIU) and figure of merit (33.45 RIU−1) have been obtained after three times drop-casting, and the enhancement sensitivity of proposed sensors is up to 51.97% compared to the traditional Au–SPR sensors. Meanwhile, the reflection spectrum is simulated by using the method of effective refractive index, and the reason for the increase of sensitivity is analysed theoretically. For researching the application of modified SPR sensor, heavy metal detection is employed to detect in the last part. Our proposed SPR sensors have potential applications in heavy metal detections and biosensing.


2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Fahad Usman ◽  
John Ojur Dennis ◽  
Khe Cheng Seong ◽  
Abdelaziz Yousif Ahmed ◽  
Thomas L. Ferrell ◽  
...  

PANI/chitosan composite and a ternary composite comprising of PANI, chitosan, and reduced graphene oxide have been successfully synthesised and characterised using FTIR and UV-VIS spectroscopy. Optical constants of the composites were extracted from the UV-VIS spectra. The extracted parameters were applied in the simulation of a surface plasmon resonance (SPR) biosensor functionalised with PANI/chitosan and ternary composites. The aim was to explore the applicability of the composite-based SPR sensor in the detection of low-concentration acetone vapour within the range of 1.8 ppm–5.0 ppm for diabetes monitoring and screening. The functionalization of the SPR sensor with the PANI/chitosan and the ternary composites shows promising application of the sensor in the detection of acetone vapour at a low concentration down to less than 0.5 ppm. The maximum sensitivity values of about 60 and 180 degree/refractive index change were observed for PANI/chitosan and ternary composite sensing layers, respectively, in comparison with the bare gold-based SPR which shows no response up to 10 ppm concentration of acetone vapour in air. In addition, the two sensing layers show good selectivity to acetone vapour compared to ethanol, methanol, and ammonia. The response in the case of ternary composite shows better linearity with a correlation coefficient of 1.0 compared to PANI/chitosan- and gold-based SPR layers with 0.9999 and 0.9997, respectively.


Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2518
Author(s):  
Nunzio Cennamo ◽  
Lorena Saitta ◽  
Claudio Tosto ◽  
Francesco Arcadio ◽  
Luigi Zeni ◽  
...  

In this work, a novel approach to realize a plasmonic sensor is presented. The proposed optical sensor device is designed, manufactured, and experimentally tested. Two photo-curable resins are used to 3D print a surface plasmon resonance (SPR) sensor. Both numerical and experimental analyses are presented in the paper. The numerical and experimental results confirm that the 3D printed SPR sensor presents performances, in term of figure of merit (FOM), very similar to other SPR sensors made using plastic optical fibers (POFs). For the 3D printed sensor, the measured FOM is 13.6 versus 13.4 for the SPR-POF configuration. The cost analysis shows that the 3D printed SPR sensor can be manufactured at low cost (∼15 €) that is competitive with traditional sensors. The approach presented here allows to realize an innovative SPR sensor showing low-cost, 3D-printing manufacturing free design and the feasibility to be integrated with other optical devices on the same plastic planar support, thus opening undisclosed future for the optical sensor systems.


Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1516
Author(s):  
Lian Liu ◽  
Shijie Deng ◽  
Jie Zheng ◽  
Libo Yuan ◽  
Hongchang Deng ◽  
...  

An enhanced plastic optical fiber (POF)-based surface plasmon resonance (SPR) sensor is proposed by employing a double-sided polished structure. The sensor is fabricated by polishing two sides of the POF symmetrically along with the fiber axis, and a layer of Au film is deposited on each side of the polished region. The SPR can be excited on both polished surfaces with Au film coating, and the number of light reflections will be increased by using this structure. The simulation and experimental results show that the proposed sensor has an enhanced SPR effect. The visibility and full width at half maximum (FWHM) of spectrum can be improved for the high measured refractive index (RI). A sensitivity of 4284.8 nm/RIU is obtained for the double-sided POF-based SPR sensor when the measured liquid RI is 1.42. The proposed SPR sensor is easy fabrication and low cost, which can provide a larger measurement range and action area to the measured samples, and it has potential application prospects in the oil industry and biochemical sensing fields.


Biosensors ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 21
Author(s):  
Duygu Çimen ◽  
Nilay Bereli ◽  
Adil Denizli

In this study, we designed a simple, rapid, sensitive and selective surface plasmon resonance (SPR) sensor for detection of L-phenylalaine by utilizing molecular imprinting technology. l-phenylalanine imprinted and non-imprinted poly(2-hydroxyethyl methacrylate-methacryloyl-l-phenylalanine) polymeric films were synthesized onto SPR chip surfaces using ultraviolet polymerization. l-phenyalanine imprinted and non-imprinted SPR sensors were characterized by using contact angle, atomic force microscopy and ellipsometry. After characterization studies, kinetic studies were carried out in the concentration range of 5.0–400.0 μM. The limit of detection and quantification were obtained as 0.0085 and 0.0285 μM, respectively. The response time for the test including equilibration, adsorption and desorption was approximately 9 min. The selectivity studies of the l-phenylalanine imprinted SPR sensor was performed in the presence of d-phenylalanine and l-tryptophan. Validation studies were carried out via enzyme-linked immunosorbent analysis technique in order to demonstrate the applicability and superiority of the l-phenylalanine imprinted SPR sensor.


2021 ◽  
Vol 11 (7) ◽  
pp. 2963
Author(s):  
Nur Alia Sheh Omar ◽  
Yap Wing Fen ◽  
Irmawati Ramli ◽  
Umi Zulaikha Mohd Azmi ◽  
Hazwani Suhaila Hashim ◽  
...  

A novel vanadium–cellulose composite thin film-based on angular interrogation surface plasmon resonance (SPR) sensor for ppb-level detection of Ni(II) ion was developed. Experimental results show that the sensor has a linear response to the Ni(II) ion concentrations in the range of 2–50 ppb with a determination coefficient (R2) of 0.9910. This SPR sensor can attain a maximum sensitivity (0.068° ppb−1), binding affinity constant (1.819 × 106 M−1), detection accuracy (0.3034 degree−1), and signal-to-noise-ratio (0.0276) for Ni(II) ion detection. The optical properties of thin-film targeting Ni(II) ions in different concentrations were obtained by fitting the SPR reflectance curves using the WinSpall program. All in all, the proposed Au/MPA/V–CNCs–CTA thin-film-based surface plasmon resonance sensor exhibits better sensing performance than the previous film-based sensor and demonstrates a wide and promising technology candidate for environmental monitoring applications in the future.


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