Vibrational Potential Energy Distributions and Coriolis Coefficients for Extremal Force Constants in Bent XY2, Pyramidal XY3, and Tetrahedral XY4 Molecules
1970 ◽
Vol 25
(2)
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pp. 217-221
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Keyword(s):
Abstract For 27 molecules with approximately extremal force fields, an empirical distinction between hydrides and non-hydrides is linked, via the comparison of calculated and observed Coriolis coefficients, to a difference, based ultimately on the relative lightness of the hydrogen atom, in the potential energy distributions of hydrides and non-hydrides. The potential energy criteria of Becher and Ballein are compared to those corresponding to extremal diagonal force constants. Coriolis coefficients for the model of progressive rigidity are mostly in rough agreement with those observed.
2014 ◽
Vol 16
(43)
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pp. 23594-23603
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2001 ◽
Vol 115
(23)
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pp. 10647-10655
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Keyword(s):
2017 ◽
Vol 14
(1)
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pp. 274-281
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1979 ◽
Vol 34
(3)
◽
pp. 362-368
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2002 ◽
Vol 4
(9)
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pp. 1555-1563
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