Darstellung und Kristallstruktur von K2Sb4S7 · H2O / Preparation and Crystal Structure of K2Sb4S7 · H2O
1979 ◽
Vol 34
(3)
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pp. 383-385
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Keyword(s):
Abstract K2Sb4S7 · H2O crystallizes in the triclinic system with a = 1171.4(5) pm, b = 952.0(5) pm, c = 715.6(5) pm and α = 99.36(5)°, β = 86.80(5)°, γ= 103.48(5)°. One half of the Sb atoms has three sulfur neighbours forming with the free electron pair a ψ-ShS3 tetrahedron, while the other half is coordinated by four S atoms to build a ψ-trigonal SbS4 bipyramid. These polyhedra are connected by common edges and corners to a three-dimensional network with two types of channels, in which either K+ ions only or K+ ions and water molecules are located.
2015 ◽
Vol 71
(6)
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pp. m127-m128
Keyword(s):
2014 ◽
Vol 70
(2)
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pp. m47-m48
Keyword(s):
1981 ◽
Vol 155
(3-4)
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Keyword(s):
2007 ◽
Vol 63
(11)
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pp. m2826-m2827
Keyword(s):
2016 ◽
Vol 72
(5)
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pp. 751-755
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2012 ◽
Vol 68
(9)
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pp. m265-m268
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Keyword(s):
2014 ◽
Vol 70
(6)
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pp. m227-m228
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2006 ◽
Vol 62
(4)
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pp. m796-m798
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