Dithioquadratato-Komplexe von Kupfer(II) und Kupfer(I). / Dithiosquarate Complexes of Copper(II) and Copper(I).

1990 ◽  
Vol 45 (4) ◽  
pp. 490-496 ◽  
Author(s):  
Ralf Krause ◽  
Rainer Mattes
Keyword(s):  
Aqueous Solutions ◽  
Antiferromagnetic Coupling ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Space Group ◽  
Ferromagnetic Behaviour ◽  
A Chain

From aqueous solutions of potassium dithiosquarate and bis(ethylenediamino)copper(II) sulfate the following compounds have been obtained: [CuII(en)2][CuII(C4O2S2)2] (2) and [CuII(en)2(H2O)]2[Cu4I(C4O2S2)4] · 2 H2O (3). Their structures have been determined: Crystal data, 2, monoclinic, space group C 2/c, a = 1914.5(6), b = 823.0(1), c = 1669.5(5) pm, β = 133.23(1)°, Ζ = 4; 1809 reflections, R = 0.024. 3, triclinic, a = 779.2(3), b = 958.7(4), c = 1478.8(4) pm, α = 82.34(3), β = 82.68(2), γ = 73.47(3)°, Ζ = 1; 3376 reflections, R = 0.045. 2 contains infinite chains of centrosymmetrical [Cu(en)2]2+ cations and bisphenoidal [Cu(C4O2S2)2]2- anions. 2 shows ferromagnetic behaviour above 75 K. At lower temperatures antiferromagnetic coupling between the chains dominates. 3 contains isolated [Co(en)2H2O]2+ cations and tetrameric [Cu(C4O2S2)]- anions. The anion consists of a chain of tetrahedrally and trigonally coordinated Cu(I) atoms with short Cu · · · Cu distances of 255.2( 1 ) and 257.9( 1 ) pm. The dithiosquarate ligands are stacked in pairs.

Syntheses, Structures and Photoluminescent Properties of Two New Pb(II) and Cd(II) Coordination Polymers Constructed from 1,10-Phenanthroline-derived and 1,4-Naphthalenedicarboxylate Ligands

2012 ◽  
Vol 67 (1) ◽  
pp. 23-28
Author(s):  
Zhi-Guo Kong ◽  
Yu He ◽  
Na Xu ◽  
Jia Guo ◽  
Dan Li
Keyword(s):  
Coordination Polymers ◽  
Layer Structure ◽  
Luminescent Properties ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Hydrothermal Conditions ◽  
Space Group ◽  
Π Interactions ◽  
A Chain

Two new related coordination polymers, namely, [Pb(L)(1,4-ndc)] · 0.5H2O (1) and [Cd(L)(1,4- ndc)] · 0.5H2O (2), where L = 2-(3-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,4- ndc = 1,4-naphthalenedicarboxylate, were synthesized under hydrothermal conditions. Crystal data for 1: C62H36F2N8O9Pb2, monoclinic space group C2/c, a = 15.874(3), b = 19.982(4), c = 16.045(3) Å, β = 94.26(3), V = 5075.3(18) Å3, Z = 4. Crystal data for 2: C62H36Cd2F2N8O9, monoclinic space group P21/n, a = 12.622(2), b = 14.038(3), c = 14.938(3) Å , β = 100.81(2), V = 2600.0(8) Å3, Z = 2. In compound 1, the 1,4-ndc ligands connect the Pb(II) atoms to yield a chain structure. The L ligands are attached on the same side of the chain. The π-π interactions between L ligands of neighboring chains result in a 2D supramolecular architecture of 1. In compound 2, 1,4-ndc ligands link the Cd(II) atoms to generate a layer structure. The L ligands from adjacent layers are paired to furnish strong π-π interactions. Further, these layers are extended into 3D supramolecular architectures through these π-π interactions. The structural differences of 1 and 2 suggest the importance of the metal centers in the construction of the coordination polymers. The luminescent properties of the compounds were also investigated.

scholarly journals Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2 / Molecular and Crystal Structure of l,r-Dimethylsilylene Titanocene Dichloride, (CH3)2Si(C5H4)2TiCl2

1981 ◽  
Vol 36 (10) ◽  
pp. 1208-1210 ◽  
Author(s):  
Hartmut Köpf ◽  
Joachim Pickardt
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Structure Determination ◽  
Titanocene Dichloride ◽  
Molecular And Crystal Structure ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Space Group ◽  
X Ray ◽  
Structural Dimensions

Abstract The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH3)2Si(C5H4)2TiCl2, has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH2(C5H4)TiCl2, with the unbridged titanocene dichloride, (C5H5)2TiCl2 and the ethylene-bridged compound (CH2)2(C5H4)2TiCl2

Strukturuntersuchungen an Diaryldichalkogeniden: Die Molekülstrukturen von [2,4,6-(CF3)3C6H2S]2,[2,4,6-Me3C6H2Te]2 und [2-Me2N-4,6-(CF3)2C6H2Te]2 / Structural Investigations of Diaryl Dichalcogenides: The Molecular Structures of [2,4,6-(CF3)3C6H2S]2, [2,4,6-Me3C6H2Te]2 and [2-Me2N-4,6-(CF3)2C6H2Te]2

1992 ◽  
Vol 47 (3) ◽  
pp. 305-309 ◽  
Author(s):  
Anja Edelmann ◽  
Sally Brooker ◽  
Norbert Bertel ◽  
Mathias Noltemeyer ◽  
Herbert W. Roesky ◽  
...  
Keyword(s):  
Molecular Structures ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
Structural Investigations ◽  
Space Group ◽  
X Ray

Abstract The Molecular Structures of [2,4,6-(CF3)3C6H2S]2 (1) [2,4,6-Me3C6H2Te]2 and [2-Me2N-4,6-(CF3)2C6H2Te]2 (3) have been determined by X-ray diffraction. Crystal data: 1: orthorhombic, space group P212121, Z = 4, a = 822.3(2), b = 1029.2(2), c = 2526.6(5) pm (2343 observed independent reflexions, R = 0.042); 2: orthorhombic, space group Iba 2, Z = 8, a = 1546.5(2), b = 1578.4(2), c = 1483.9(1) pm (2051 observed independent reflexions, R = 0.030); 3: monoclinic, space group P 21/c, Z = 4, a = 1118.7(1), b = 1536.5(2), c = 1492.6(2) pm, β = 98.97(1)° (3033 observed independent reflexions, R = 0.025).

Two- and three-dimensional coordination polymers based on zinc(II) and furan-2,5-dicarboxylic acid: structure variation due to metal-to-linker ratio

2018 ◽  
Vol 74 (12) ◽  
pp. 1719-1724 ◽  
Author(s):  
Yimin Mao ◽  
Peter Y. Zavalij
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Molar Ratio ◽  
Monoclinic Space Group ◽  
Structure Variation ◽  
Space Group ◽  
Hydrogen Bonding Pattern ◽  
Solvent Molecules ◽  
A Chain

Two ZnII-based coordination polymers (CPs) were synthesized by the hydrothermal method, using Zn(NO3)2·6H2O and furan-2,5-dicarboxylic acid (FDCA) in dimethylformamide (DMF) solvent, at 95 °C. Poly[tetrakis(dimethylazanium) [tetrakis(μ2-furan-2,5-dicarboxylato-κ2 O 2:O 5)dizinc(II)]], {(C2H8N)4[Zn2(C6H2O5)4]} n or {[DMA]4[ZnII 2(FDC)4]} n (DMA = dimethylazanium and FDC = furan-2,5-dicarboxylate), (1), was obtained with a 1:1 molar ratio of ZnII and FDCA. It crystallized in the monoclinic space group C2/c. Coordinated by ZnII ions, FDC2− ligands form 21 double-stranded helices propagating along the b axis. The helices are interconnected and extend laterally in the a direction, forming a two-dimensional (2D) sheet-like network. The 2D sheets are stacked along the c direction without interconnections. DMA cations are cocrystallized in (1) and are hydrogen bonded with carboxylate O atoms of the FDC2− ligands. The hydrogen-bonding pattern consists of R 2 2(4) and R 2 2(10) motifs alternating in a chain. Poly[bis(dimethylazanium) [bis(μ4-furan-2,5-dicarboxylato-κO 2:κO 2′:κO 5:κO 5)bis(μ3-furan-2,5-dicarboxylato-κO 2:κO 2′:κO 5)dizinc(II)] dimethylformamide 3.08-solvate], {(C2H8N)2[Zn2(C6H2O5)4]·3.08C3H7NO} n or {[DMA]2[ZnII 3(FDC)4]·3.08DMF} n , (2), was obtained with a 1:2 molar ratio of ZnII and FDCA. It crystallized in the monoclinic space group P21/c, forming a three-dimensional network. The pores are filled with DMA cations and DMF solvent molecules.

Strukturen der mehrkernigen nickelthiolato-komplexe [(μ-SMe)2(Ni(MeNHCS2))2] und cyclo-[(μ-SMe)2Ni]6 / Structures of Two Polynuclear Nickel-Thiolato-Complexes [(μ-SMe)2(Ni(MeNHCS2))2] and cyclo-[(μ-SMe)2Ni]6

1994 ◽  
Vol 49 (6) ◽  
pp. 770-772 ◽  
Author(s):  
Klaus Schulbert ◽  
Rainer Mattes
Keyword(s):  
Crystal Structures ◽  
Nickel Acetate ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
Dithiocarbamic Acid ◽  
Coordination Spheres ◽  
Partial Degradation ◽  
Acid Esters

The reactions of N-substituted dithiocarbamic acid esters and nickel acetate yield, by partial degradation of the esters, the polynuclear nickel thiolato complexes cyclo-[(μ-SMe)2Ni]6, 1 and [(μ-SMe)2(Ni(MeNHCS2))2, 2. Their crystal structures have been determined. The Ni coordination spheres are comprised of four sulfur atoms in a planar arrangement. 1 is a second, highly symmetrical modification of the already known cyclic hexamer Ni6(SMe)12. In 2 two Ni(PhNHCS2) moieties are bridged to dimers by thiolato groups. Two of these dimers are connected to a tetramer by weak axial Ni-S interactions. Crystal data for 1: monoclinic, space group P21/n, a = 986.1(2), b = 1308.1(3), c = 1228.6(2) pm, β = 96.07(3)°, Z = 2, R = 0.072, Rw = 0.062, 3797 reflections. 2: orthorhombic, space group Pnma, a = 1790.0(4), b = 1806.7(4), c = 934.4(2) pm. Z = 4, R = 0.061, Rw = 0.051, 2079 reflections

Untersuchungen an Polyhalogeniden, XXXVI. Zur Kenntnis des Oktaiodid-Ions I82-: Darstellung und Kristallstruktur des [(Crypt-2.2.2)H2]l8, des [Ni(phen)3]I8 · 2CHCl3 und der Bis(N-alkylurotropinium) oktaiodide (UrR)2I8 mit R = Methyl und Ethyl / Studies on Polyhalides, XXXVI. On the Octaiodide Ion I82-: Preparation and Crystal Structure of [(Crypt-2.2.2)H2]I8, of [Ni(phen)3]I8-2CHCl3 and of the Bis(N-alkylurotropinium)octaiodides (UrR)2I8 with R = methyl and ethyl

1998 ◽  
Vol 53 (7) ◽  
pp. 641-652 ◽  
Author(s):  
Arista Gräfe-Kavoosian ◽  
Shida Nafepour ◽  
Klaus Nagel ◽  
Karl-Friedrich Tebbe
Keyword(s):  
Crystal Structure ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Iodine Molecule ◽  
Orthorhombic Space Group ◽  
Triclinic Space Group ◽  
Space Group

Abstract The new compound [(Crypt-2.2.2)H2]I8 has been prepared by the reaction of [(Crypt-2.2.2)H2](I3)2 with iodine in methanol. It crystallizes in the orthorhombic space group Pbcn with a = 11.476 (2), b = 13.589 (2), c = 22.888 (2) Å and Z = 4. The crystal structure has been refined to RF = 0.031 for 1618 reflections. It may be described as a layerlike packing of octaiodide anions I82-and diprotonated 2.2.2-Crypt as cations. The non planar octaiodide anion is built up from two triiodide groups and a bridging iodine molecule.Tris(1, 10-phenanthroline)nickel(II) octaiodide bis(chloroform) crystallizes in the monoclinic space group P21/n with a = 11.683 (8), b = 21.717 (8), c = 20.752 (5) Å, β = 95.03 (5)° and Z = 4 formula units. The crystal structure has been refined to RF = 0.058 for 3894 reflections. The structure consists of two chloroform molecules, octahedrally coordinated complex cations [Ni(phen)3]2+ and nonplanar octaiodide anions I82- each composed of two asymmetric triiodide units I3- weakly associated with an elongated bridging iodine molecule I2.The already known structure of bis(N-methylurotropinium) octaiodide, (UrMe)2I8, has been verified and more accurate crystal data have been collected. The crystal structure has been refined to RF = 0.045 for 1908 reflections. The compound crystallizes in the monoclinic space group P21/c with a = 11.302 (2), b = 9.850 (2), c = 14.188 (2) Å , β = 92.59 (1)° and Z = 2. The anion has the shape of a stretched Z.The structure of bis(N-ethylurotropinium) octaiodide (UrEt)2I8 has been determined and a new configuration (I3-, I5-) for octaiodide ions between Z (I3- · I2 ·I3-) and a “broken” configuration (I3-, I5-) has been observed. The compound crystallizes in the triclinic space group P1̄ with a = 9.741 (3), b = 11.815 (3), c = 15.426 (3) Å, α = 91.80 (2), β = 107.14 (2), γ = 90.04 (2)° and Z = 2. The crystal structure has been refined to RF = 0.037 for 3657 reflections.

scholarly journals Einkristallzüchtung und Röntgenstrukturanalyse polymerer 1:1-Komplexe von CuBr2 und CuCl2 mit Pyrazin aus Gelen / Crystal Growth in Gels and X-Ray Characterization of Polymeric 1:1-Complexes of CuBr2 and CuCl2 with Pyrazine

1989 ◽  
Vol 44 (5) ◽  
pp. 553-556 ◽  
Author(s):  
Th. Fetzer ◽  
A. Lentz ◽  
T. Debaerdemaeker
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Crystal Growth ◽  
Chloro Complex ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Space Group ◽  
X Ray ◽  
Linear Chains

Single crystals of Cu(pz)Br2 and Cu(pz)Cl2 were grown by using gel methods with tetramethoxysilane as the gel-forming reagent. Thermal decomposition is interpreted. Crystal data for the bromo complex: monoclinic, space group C2/m with a = 1239.2(3) pm, b = 685.9(2) pm, c = 390.7(3) pm, β = 96,23(5)°. Crystal data for the chloro-complex: monoclinic, space group C2/m with a = 1197.1(3) pm, b = 684.9(3) pm, c = 370.1(3) pm, β = 95.96(5)°. Crystal structure analyses reveal that CuHal2 molecules are bonded by pyrazine to form linear chains. These chains are cross-linked by bridging halogen atoms.

scholarly journals Novel Structures and Magnetic Properties of Two [Mn2] Complexes with 2,4-di-2-pyridyl-2,4-pentanediol as the Ligand

2019 ◽  
Vol 5 (3) ◽  
pp. 43
Author(s):  
En-Che Yang ◽  
Yu-Ying Chang ◽  
Shi-Yi Huang ◽  
Ling-Xuan Hong ◽  
Gene-Hsiang Lee ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Property ◽  
The Other ◽  
Antiferromagnetic Coupling ◽  
Monoclinic Space Group ◽  
Ferromagnetic Coupling ◽  
Manganese Ions ◽  
Space Group ◽  
Metal Metal ◽  
Novel Structures

Two ligands, 2,4-di-2-pyridyl-2,4-pentanediol (rD and mD), were employed to synthesize two Mn2 complexes, [Mn2(rD)2Br2] (1) and [Mn2(mD)2(H2O)2]Br2 (2). Compound 1 crystallized in a tetragonal space group, P41212, with a novel hamburger shaped structure. A detailed study indicated that compound 1 did not contain a metal–metal bond, but antiferromagnetic coupling was observed between the Mn(III) ions. Compound 2 crystallized in a monoclinic space group, C2/c, with one Mn(II) and the other with Mn(IV). The two manganese ions were bridged by two alkoxide ligands, resulting in ferromagnetic coupling. Magnetic property studies confirm the above assignments.

scholarly journals Komplexe offenkettiger und zyklischer Diazathiaalkane. Die Kristallstrukturen von 1,7-Diaza-4-thiaheptan-tricarbonyl-molybdän(0), 1-Thia-4,7-diazacycIononan-tricarbonyI-molybdän(0) und 1-Thia-4,7-diazacyclononan-tricarbonyl-rhenium(I)-bromid

1987 ◽  
Vol 42 (7) ◽  
pp. 867-873 ◽  
Author(s):  
Peter Hoffmann ◽  
Andreas Steinhoff ◽  
Rainer Mattes
Keyword(s):  
Monoclinic Space Group ◽  
Crystal Data ◽  
Orthorhombic Space Group ◽  
Space Group ◽  
Bond Lengths

Abstract The reactions of Mo(CO)6, W(CO)6 and Re(CO)6Br with the ligand l-thia-4,7-diazacyclononane (C6H14N2S = L) yield crystals of LMo(CO)3 (4a), LW(CO)3 (4b) and LRe(CO)3Br (5). A n improved synthesis of L has been developed, and the structures of 4a and 5 have been determined. Crystal data: 4a, monoclinic, space group P21/n, a = 791.3(4), b - 1332.6(4), c = 1149.2(6) pm, β - 98.96(4)°, Z = 4.1841 reflexions, R = 0.045. 5, orthorhombic, space group Pbca, a = 1413.4(5), b = 1398.0(5), c = 1409.5(5) pm, Z = 8.2619 reflexions, R = 0.038. Both crystals contain pseudooctahedral LM(CO)3 moieties, with facial coordination of the CO molecules. The Re - N bond lengths (average 220.3(4) pm) are rather short. The structure of L 'Mo(CO)3 (3) with the acyclic ligand 1,7-diaza-4-thiaheptane (C4H10N2S = L') was also determined. Crystal data: monoclinic, space group P21/c, a = 682.8(2), b = 1213.0(3), c = 1253.0(3), β = 99.74°, Z = 4.1889 reflexions, R = 0.023.

Crystal data for the monoclinic form of the lanthanide molybdoperrhenates Ln(MoO4)(ReO4)

1981 ◽  
Vol 14 (6) ◽  
pp. 462-463
Author(s):  
D. Argelès ◽  
M. Quarton ◽  
J.-P. Silvestre
Keyword(s):  
Powder Diffraction ◽  
Diffraction Data ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Powder Diffraction Data ◽  
Space Group ◽  
Monoclinic Form ◽  
Cell Dimensions

Nd(MoO4) (ReO4) is monoclinic, space group P21/c; the cell dimensions are a = 6.169 (1), b = 9.822 (1), c = 13.139 (2) Å and β = 111.65 (1)°. The monoclinic compounds in the series Ln(MoO4) (ReO4), with Ln = Ce to Lu (Pm compound is not examined), are isotypic. Crystal parameters and powder diffraction data are given.

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