High-pressure synthesis and crystal structure of In3B5O12
2017 ◽
Vol 72
(1)
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pp. 69-76
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Keyword(s):
X Ray
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AbstractOrthorhombic In3B5O12 was synthesized in a Walker-type multianvil apparatus under high-pressure/high-temperature conditions of 12.2 GPa and 1500°C. Its structure is isotypic to the rare earth analogs RE3B5O12 (RE=Sc, Er–Lu). In the field of indium borate chemistry, In3B5O12 is the third known ternary indium borate besides InBO3 and InB5O9. The crystal structure of In3B5O12 has been determined via single-crystal X-ray diffraction data collected at room temperature. It crystallizes in the orthorhombic space group Pmna with the lattice parameters a=12.570(2), b=4.5141(4), c=12.397(2) Å, and V=703.4(2) Å3. IR and Raman bands of In3B5O12 were theoretically determined and assigned to experimentally recorded spectra.
2017 ◽
Vol 72
(12)
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pp. 977-982
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2008 ◽
Vol 63
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pp. 713-717
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2010 ◽
Vol 65
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pp. 1206-1212
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2008 ◽
Vol 63
(6)
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pp. 707-712
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2011 ◽
Vol 66
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pp. 107-114
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1996 ◽
Vol 51
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pp. 811-816
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2007 ◽
Vol 62
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pp. 759-764
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