Configuration Determination of Transition Metal Complexes by Multiple Scattering EXAFS Analysis: A Case Study

2014 ◽  
Vol 228 (10-12) ◽  
Author(s):  
Matthias Bauer
Keyword(s):  
Fine Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Multiple Scattering ◽  
Transition Metal Complexes ◽  
X Ray ◽  
Exafs Analysis ◽  
X Ray Absorption

AbstractA multiple scattering extended X-ray absorption fine structure (EXAFS) analysis of Ti(acac)

scholarly journals Probing the oxidation state of transition metal complexes: a case study on how charge and spin densities determine Mn L-edge X-ray absorption energies

2018 ◽  
Vol 9 (33) ◽  
pp. 6813-6829 ◽  
Author(s):  
Markus Kubin ◽  
Meiyuan Guo ◽  
Thomas Kroll ◽  
Heike Löchel ◽  
Erik Källman ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Oxidation State ◽  
Transition Metal Complexes ◽  
Theoretical Approach ◽  
X Ray ◽  
Local Charge ◽  
X Ray Absorption ◽  
Spin Densities

A combined experimental and theoretical approach reveals correlations of metal L-edge X-ray absorption energies to local charge and spin densities.

scholarly journals X-ray-induced sample damage at the Mn L-edge: a case study for soft X-ray spectroscopy of transition metal complexes in solution

2018 ◽  
Vol 20 (24) ◽  
pp. 16817-16827 ◽  
Author(s):  
Markus Kubin ◽  
Jan Kern ◽  
Meiyuan Guo ◽  
Erik Källman ◽  
Rolf Mitzner ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Absorption Spectroscopy ◽  
X Rays ◽  
X Ray ◽  
X Ray Absorption ◽  
Sample Damage ◽  
Dose Dependent

Dose-dependent damage to a Mniii complex in solution, induced by soft X-rays, is investigated with Mn L-edge X-ray absorption spectroscopy.

scholarly journals Characterization of reactive organometallic species via MicroED

2019 ◽  
Author(s):  
Christopher Jones ◽  
Matthew Asay ◽  
Lee Joon Kim ◽  
Jack Kleinsasser ◽  
Ambarneil Saha ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cryogenic Cooling ◽  
Structural Determination ◽  
X Ray ◽  
X Ray Crystallography ◽  
Diamagnetic Transition

Here we apply microcrystal electron diffraction (MicroED) to the structural determination of transition metal complexes. We find that the simultaneous use of 300 keV electrons, very low electron doses, and an ultra-sensitive camera allows for the collection of data without cryogenic cooling of the stage. This technique reveals the first crystal structures of the classic zirconocene hydride, colloquially known as “Schwartz’s reagent”, a novel Pd(II) complex not amenable to solution-state NMR or X-ray crystallography, and five other paramagnetic or diamagnetic transition metal complexes.

Determination of the Structures of Antiinflammatory Copper(II) Dimers of Indomethacin by Multiple-Scattering Analyses of X-ray Absorption Fine Structure Data

2001 ◽  
Vol 40 (6) ◽  
pp. 1295-1302 ◽  
Author(s):  
Jane E. Weder ◽  
Trevor W. Hambley ◽  
Brendan J. Kennedy ◽  
Peter A. Lay ◽  
Garry J. Foran ◽  
...  
Keyword(s):  
Fine Structure ◽  
Multiple Scattering ◽  
Structure Data ◽  
X Ray ◽  
Absorption Fine ◽  
X Ray Absorption

Ultrafast laser-driven x-ray spectrometer for x-ray absorption spectroscopy of transition metal complexes

2004 ◽  
Vol 29 (9) ◽  
pp. 1028 ◽  
Author(s):  
Frank Benesch ◽  
Taewoo Lee ◽  
Yan Jiang ◽  
Christoph G. Rose-Petruck
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Absorption Spectroscopy ◽  
Ultrafast Laser ◽  
X Ray ◽  
X Ray Absorption
Sign in / Sign up

Export Citation Format

Share Document