Temperature Dependence of Yield Stress and Dislocation Dissociation in L12-Ordered Intermetallic Compounds

2011 ◽  
Vol 1295 ◽  
Author(s):  
Haruyuki Inui ◽  
Norihiko L. Okamoto

ABSTRACTThe temperature dependence of yield stress and the associated dislocation dissociation in L12 intermetallic compounds are investigated in order to check the feasibility of the classification of L12 intermetallic compounds so far reported in terms of the planarity of core structures of partial dislocations with b = 1/2<110> and 1/3<112> on {111} and {001} glide planes. In contrast to what is believed from the reported classification, the motion of APB-coupled dislocations is proved to give rise to the rapid decrease in yield stress at low temperatures for Co3Ti and Co3 (Al,W). The temperature dependence of yield stress at low temperatures is newly interpreted in terms of a thermal component of solid-solution hardening, at least, for these two L12 compounds. We have proposed a new way to describe the yield stress–temperature curves of L12 compounds with three parameters (the athermal and thermal components of solid-solution hardening and the anomalous strengthening component) when the dislocation dissociation scheme is of the APB-type.

2015 ◽  
Vol 1760 ◽  
Author(s):  
Haruyuki Inui ◽  
Norihiko L. Okamoto

ABSTRACTThe temperature dependence of yield stress and the associated dislocation dissociation in L12 intermetallic compounds are investigated in order to check the feasibility of the classification of L12 intermetallic compounds so far made in terms of the planarity of core structures of partial dislocations with b = 1/2<110> and 1/3<112> on {111} and {001} glide planes. In contrast to what is believed from the classification, the motion of APB-coupled dislocations is evidenced to give rise to the rapid decrease in yield stress at low temperatures for Pt3Al. In view of the fact that rapid decrease in yield stress at low temperatures is also observed in Co3(Al,W) and Co3Ti in which APB-coupled dislocations are responsible for deformation, the SISF-type dissociation is not a prerequisite for the rapidly decreasing CRSS for slip on (111) and the relative magnitudes of the APB energy on (111) and the SISF energy on (111) cannot be a primary factor that determines the type of the temperature dependence of CRSS for L12 compounds. The importance of the CSF energy as a factor determining the type of the temperature dependence of yield stress for L12 compounds through the changes in the planarity of the core structure of the APB-coupled partial dislocation with bp = ½[1$\overline 1$0] is discussed in the light of experimental evidence obtained from Pt3Al.


1986 ◽  
Vol 96 (1) ◽  
pp. K43-K47 ◽  
Author(s):  
I. M. Ghauri ◽  
P. Feltham ◽  
M. Z. Butt

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1909
Author(s):  
Lukas Haußmann ◽  
Hamad ur ur Rehman ◽  
Dorothea Matschkal ◽  
Mathias Göken ◽  
Steffen Neumeier

Solid solution strengthening of the unordered γ matrix phase by alloying elements is of great importance during creep of Ni-based superalloys, particularly at high temperatures above 1000 °C. To study the role of different potent solutes, we have conducted creep experiments on binary Ni-2X alloys (X = Mo, Re, Ta, W) at 1000 °C, 1050 °C, and 1100 °C at a constant stress of 20 MPa. Compared to mechanical tests below 800 °C, where the size of the elements mostly determines the solid solution hardening contribution, the strengthening contribution of the different alloying elements above 1000 °C directly correlates with their diffusivity. Therefore, elements such as Ta that lead to strong solid solution hardening at low temperatures become less effective at higher temperatures and are exceeded by slower diffusing elements, such as Re.


Author(s):  
Stuart A. Maloy

MoSi2 has recently been investigated as a potential material for high temperature structural applications. It has excellent oxidation resistance up to 1700°C, a high melting temperature, 2030°C, and a brittle-to-ductile transition temperature at 900-1000°C. WSi2 is isomorphous with MoSi2 and has a body-centered tetragonal unit cell of the space group 14/mmm. The lattice parameters are a=3.20 Å and c=7.84 Å for MoSi2 and a=3.21 Å and c=7.88 Å for WSi2. Therefore, WSi2 was added to MoSi2 to improve its strength via solid solution hardening. The purpose of this study was to investigate the slip systems in polycrystalline MoSi2/WSi2 alloys.


2001 ◽  
Vol 44 (6) ◽  
pp. 879-884 ◽  
Author(s):  
A.A Sharif ◽  
A Misra ◽  
J.J Petrovic ◽  
T.E Mitchell

1980 ◽  
Vol 15 (1) ◽  
pp. 253-254 ◽  
Author(s):  
M. Z. Butt ◽  
P. Feltham

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