Influence of Laser Irradiation and Ambient Gas in Preparation of PZT Films by Laser Ablation

1990 ◽  
Vol 191 ◽  
Author(s):  
Akiharu Morimoto ◽  
Shigeru Otsubo ◽  
Tatsuo Shimizu ◽  
Toshiharu Minamikawa ◽  
Yasuto Yonezawa ◽  
...  

ABSTRACTPb(Zr0.52Ti0. 48)O3 (PZT) films were prepared on r-plane sapphire substrates by the laser ablation method utilizing ArF excimer laser in O2 or N2O environment. The composition of the films deposited in O2 environment was found to be fairly close to the composition of the target material for a wide range of substrate temperatures, 400 – 750 °c. Increasing the laser fluence (the laser power density) for the ablation enhances the formation of the perovskite structure rather than the pyrochlore one. Use of N2O ambient gas instead of O2 gas enhances the formation of the perovskite structure of PZT films. Furthermore, it was found that a laser irradiation on the growing film surface during deposition enhances the formation of the perovskite structure.

1992 ◽  
Vol 275 ◽  
Author(s):  
Akiharu Morimoto ◽  
Shigeru Mizukami ◽  
Tatsuo Shimizu ◽  
Toshiharu Mlnamikawa ◽  
Yasuto Yonezawa ◽  
...  

ABSTRACTBa2YCu3Ox superconducting films were prepared by Nd:YAG laser ablation, equipped with a second (ArF excimer) laser for irradiation onto the growing film surface. The irradiation onto the film during the deposition were delayed for various delay times against the ablation of Ba2YCu3Ox target. The experiment showed that the second laser irradiation within several tens us around the ablation event induces a change of the crystal orientation. This result suggests that the crystal growth for the laser ablation is determined mainly around this time scale.


2018 ◽  
Vol 32 (19) ◽  
pp. 1840064 ◽  
Author(s):  
Makoto Kanazawa ◽  
Pankaj Koinkar ◽  
Akihiro Furube ◽  
Dnyaneshwar Gavhane ◽  
Mahendra A. More

The laser ablation of a noble target material in a liquid is known as an alternative physical method for nanostructure fabrication. In the present study, the nanosecond laser ablation is used to irradiate MoS2 in water to produce MoS2 nanosheets. The experiments of laser ablation time of 20 minutes and 120 minutes have been carried out to study their field emission properties. Transmission electron microscopy (TEM) and Raman spectroscopy have been used to reveal surface and structural morphology. It is observed that the laser ablation time is an important factor in determining the size of MoS2 nanostructure. The Raman spectra of laser ablation confirm the formation of MoS2 nanosheets and removal of molybdenum oxide species. The TEM shows the size of MoS2 microsheet has been reduced from 2 [Formula: see text]m to 400 nm after the laser ablation treatment. It is found that the turn-on fields are reduced and current densities of MoS2 are increased after the laser ablation. The enhancement in the field emission characteristics of MoS2 is due to the reduction in the size of MoS2 and removal of molybdenum oxide species. The nanostructures produced by laser ablation may be used for optoelectronic application.


Author(s):  
Yongli Zhang ◽  
Brenton S. McLaury ◽  
Siamack A. Shirzai

Erosion equations are usually obtained from experiments by impacting solid particles entrained in a gas or liquid on a target material. The erosion equations are utilized in CFD (Computational Fluid Dynamics) models to predict erosion damage caused by solid particle impingements. Many erosion equations are provided in terms of an erosion ratio. By definition, the erosion ratio is the mass loss of target material divided by the mass of impacting particles. The mass of impacting particles is the summation of (particle mass × number of impacts) of each particle. In erosion experiments conducted to determine erosion equations, some particles may impact the target wall many times and some other particles may not impact the target at all. Therefore, the experimental data may not reflect the actual erosion ratio because the mass of the sand that is used to run the experiments is assumed to be the mass of the impacting particles. CFD and particle trajectory simulations are applied in the present work to study effects of multiple impacts on developing erosion ratio equations. The erosion equation as well as the CFD-based erosion modeling procedure is validated against a variety of experimental data. The results show that the effect of multiple impacts is negligible in air cases. In water cases, however, this effect needs to be accounted for especially for small particles. This makes it impractical to develop erosion ratio equations from experimental data obtained for tests with sand in water or dense gases. Many factors affecting erosion damage are accounted for in various erosion equations. In addition to some well-studied parameters such as particle impacting speed and impacting angle, particle size also plays a significant role in the erosion process. An average particle size is usually used in analyzing experimental data or estimating erosion damage cases of practical interest. In petroleum production applications, however, the size of sand particles that are entrained in produced fluids can vary over a fairly broad range. CFD simulations are also performed to study the effect of particle size distribution. In CFD simulations, particle sizes are normally distributed with the mean equaling the average size of interest and the standard deviation varying over a wide range. Based on CFD simulations, an equation is developed and can be applied to account for the effect of the particle size distribution on erosion prediction for gases and liquids.


2009 ◽  
Vol 4 (3) ◽  
pp. 74-77
Author(s):  
Mikhail Vagin ◽  
Anton Unitsyn ◽  
Aleksandr Petrov ◽  
Aleksandr Kozlov ◽  
Sergey Malyshkin ◽  
...  

Possibility of mass definition using terahertz laser ablation method for biological nanoobjects is researched. Diffusion spectrometer of aerosols was applied for measuring the size of dispersed products of terahertz laser ablation. Dependence of molecular mass from the aerosol particle size was obtained for fragments of DNA λ-hind. This work was carried out using THz radiation of free electron laser of Siberian center of photochemical researches.


2009 ◽  
Vol 2 (1) ◽  
pp. 17-23 ◽  
Author(s):  
S. Somekawa ◽  
Y. Kusumoto ◽  
H. Yang ◽  
M. Abdulla-Al-Mamun ◽  
B. Ahmmad

The relation among the change of the crystal structure, the amount of doped N and the photocatalytic activity for the decomposition of methylene blue was studied. The N-doping was promoted by the change of the crystal structure from the rutile phase to the anatase phase. The photocatalytic activity for the decomposition of methylene blue was enhanced by an increase in the amount of anatase crystals and doped N. Keywords: Laser ablation; N-doping process; Crystal change; N-doped TiO2 thin film; Dye decomposition. © 2010 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved. DOI: 10.3329/jsr.v2i1.2992        J. Sci. Res. 2 (1), 17-23 (2010) 


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