scholarly journals Direct Z-scheme GdFeO3/g-C3N4 heterostructures with outstanding photocatalytic activity

Author(s):  
Li Li ◽  
Fengwu Wang ◽  
Jiajun Feng ◽  
Siqi Guo ◽  
Mai Xu ◽  
...  

Abstract The direct Z-scheme GdFeO3/g-C3N4 photocatalysts used without any mediators were obtained using an ultrasonic synthesis approach. The composites’ structures, elemental composition and morphologies, as well as optical, electrochemical and catalytic properties, were thoroughly analyzed. GdFeO3/g-C3N4-3:7 composite exhibited an excellent enhanced light-harvesting ability and low recombination rate, which manifested into an outstanding visible-light driven activity, 7.7 and 2.3 times more than of stand-alone g-C3N4 and GdFeO3, respectively. A mechanism responsible for the photocatalytic property enhancement was proposed. The stability and reusability of the GdFeO3/g-C3N4 composites make them excellent materials for practical applications related to the removal of organic pollutants from the wastewater.

Author(s):  
Justyna Sulej ◽  
Magdalena Jaszek ◽  
Monika Osińska-Jaroszuk ◽  
Anna Matuszewska ◽  
Renata Bancerz ◽  
...  

AbstractPolysaccharides are biopolymers composed of simple sugars like glucose, galactose, mannose, fructose, etc. The major natural sources for the production of polysaccharides include plants and microorganisms. In the present work, four bacterial and two fungal polysaccharides (PS or EPS) were used for the modification and preservation of Pycnoporus sanguineus cellobiose dehydrogenase (CDH) activity. It was found that the presence of polysaccharide preparations clearly enhanced the stability of cellobiose dehydrogenase compared to the control value (4 °C). The highest stabilization effect was observed for CDH modified with Rh110EPS. Changes in the optimum pH in the samples of CDH incubated with the chosen polysaccharide modifiers were evidenced as well. The most significant effect was observed for Rh24EPS and Cu139PS (pH 3.5). Cyclic voltammetry used for the analysis of electrochemical parameters of modified CDH showed the highest peak values after 30 days of incubation with polysaccharides at 4 °C. In summary, natural polysaccharides seem to be an effective biotechnological tool for the modification of CDH activity to increase the possibilities of its practical applications in many fields of industry.


RSC Advances ◽  
2016 ◽  
Vol 6 (5) ◽  
pp. 3600-3607 ◽  
Author(s):  
Yuanguo Xu ◽  
Liquan Jing ◽  
Xiao Chen ◽  
Haiyan Ji ◽  
Hui Xu ◽  
...  

Photoactivity of Ag3VO4 can be enhanced by modification with Fe2O3. The electrochemical impedance of the composite being smaller than pure Ag3VO4 may be one reason.


2015 ◽  
Vol 44 (25) ◽  
pp. 11582-11591 ◽  
Author(s):  
Zhengyuan Zhang ◽  
Deli Jiang ◽  
Chaosheng Xing ◽  
Linlin Chen ◽  
Min Chen ◽  
...  

Novel AgI nanoparticle-decorated β-Bi2O3 nanosheet heterostructured Z-scheme photocatalysts were fabricated, which exhibited significantly enhanced visible-light-driven photocatalytic activity.


2015 ◽  
Vol 5 (8) ◽  
pp. 4055-4063 ◽  
Author(s):  
Arpita Sarkar ◽  
Abhisek Brata Ghosh ◽  
Namrata Saha ◽  
Amit Kumar Dutta ◽  
Divesh N. Srivastava ◽  
...  

Eu-doped Bi2S3 nanoflowers possess highly visible light driven photocatalytic activity towards degradation of organic pollutants.


2014 ◽  
Vol 2014 ◽  
pp. 1-14 ◽  
Author(s):  
Ting Feng ◽  
Gen Sheng Feng ◽  
Lei Yan ◽  
Jia Hong Pan

The present paper reviews the progress in the synthesis of one-dimensional (1D) TiO2nanostructures and their environmental applications in the removal of organic pollutants. According to the shape, 1D TiO2nanostructures can be divided into nanorods, nanotubes, nanowires/nanofibers, and nanobelts. Each of them can be synthesized via different technologies, such as sol-gel template method, chemical vapor deposition, and hydrothermal method. These methods are discussed in this paper, and the recent development of the synthesis technologies is also presented. Furthermore, the organic pollutants, degradation using the synthesized 1D TiO2nanostructures is studied as an important application of photocatalytic oxidation (PCO). The 1D nanostructured TiO2exhibited excellent photocatalytic activity in a PCO process, and the mechanism of photocatalytic degradation of organic pollutants is also discussed. Moreover, the modification of 1D TiO2nanostructures using metal ions, metal oxide, or inorganic element can further enhance the photocatalytic activity of the photocatalyst. This phenomenon can be explained by the suppression of e−-h+pairs recombination rate, increased specific surface area, and reduction of band gap. In addition, 1D nanostructured TiO2can be further constructed as a film or membrane, which may extend its practical applications.


2020 ◽  
Vol 44 (29) ◽  
pp. 12806-12814 ◽  
Author(s):  
Ning Li ◽  
Yanlei He ◽  
Jiajia Lian ◽  
Qingyun Liu ◽  
Xianxi Zhang ◽  
...  

The photocatalytic performance of Z-scheme NiO/Ag/Ag3PO4 was evaluated by degrading organic pollutants under visible light.


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