Origin of corundum within anorthite megacrysts from anorthositic amphibolites, Granulite Terrane, Southern India

2020 ◽  
Vol 105 (8) ◽  
pp. 1161-1174
Author(s):  
Shreya Karmakar ◽  
Subham Mukherjee ◽  
Upama Dutta
Keyword(s):  
High Pressure ◽  
Grain Boundaries ◽  
Chemical Potential ◽  
Regional Metamorphism ◽  
Phase Relations ◽  
Southern India ◽  
Triple Junctions ◽  
Medium Temperature ◽  
Hp Metamorphism ◽  
Basic Rocks

Abstract Growth of corundum in metamorphosed anorthosites and related basic-ultra-basic rocks is an exceptional feature, and its origin remains elusive. We describe the occurrence of and offer an explanation for the genesis of corundum in anorthositic amphibolites from ~2.5 Ga old basement of the Granulite Terrane of Southern India (GTSI). The studied amphibolites from two localities, Manavadi (MvAm) and Ayyarmalai (AyAm), contain anorthite lenses (An90–99) with euhedral to elliptical outline set in a finer-grained matrix of calcic plagioclase (An85–90) and aluminous amphibole (pargasite-magnesiohastingsite). The lenses, interpreted as primary magmatic megacrysts, and the matrix are both recrystallized under static condition presumably during the regional high pressure (HP) metamorphism (~800 °C, 8–11 kbar) at ~2.45 Ga. Corundum occurs in the core of some of the recrystallized anorthite lenses (An95–99) in two modes: (1) Dominantly, it forms aggregates with magnetite (with rare inclusion of hercynite; in MvAm) or spinel (and occasionally hematite-ilmenite; in AyAm). The aggregates cut across the polygonal grain boundaries of the anorthite and contain inclusions of anorthite. (2) Corundum also occurs along the grain boundaries or at the triple junctions of the polygonal anorthite grains, where it forms euhedral tabular grains, sieved with inclusions of anorthite or forms skeletal rims around the recrystallized anorthite, such that it seems to be intergrown with anorthite. Combined petrological data and computed phase relations are consistent with growth of corundum in an open system during regional metamorphism in the presence of intergranular fluids. Two mechanisms are proposed to explain the formation of the corundum in the amphibolites: (1) corundum + magnetite/spinel aggregates formed dominantly by oxy-exsolution of pre-existing Al-Fe-Mg-(Ti)-spinel. This pre-existing spinel may be primary magmatic inclusions within the anorthite phenocrysts or could have formed due to reaction of primary magmatic inclusions of olivine with the host anorthite. Pseudosections of fO2-nH2O-T-P in the CaO–FeO–MgO–Al2O3–SiO2–H2O (CFMASH) system indicate that fO2 and H2O strongly influence the formation of corundum + amphibole from the initial magmatic assemblage of anorthite (phenocrysts) + spinel ± olivine (inclusions). (2) The corundum with anorthite presumably formed through desilification and decalcification of anorthite, as is indicated by computed phase relations in isobaric-isothermal chemical potential diagrams (µSiO2-µCaO) in parts of the CASH system. Growth of corundum in this mode is augmented by high activity of anorthite in plagioclase, high pressure, and low-to-medium temperature of metamorphism. This study thus presents a new viable mechanism for the origin of corundum in anorthositic amphibolites, and basic-ultra-basic rocks in general, which should provide new insight into lower crustal processes like high-pressure metamorphism.

scholarly journals Metasediments Covering Ophiolites in the HP Internal Belt of the Western Alps: Review of Tectono-Stratigraphic Successions and Constraints for the Alpine Evolution

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 411
Author(s):  
Paola Tartarotti ◽  
Silvana Martin ◽  
Andrea Festa ◽  
Gianni Balestro
Keyword(s):  
High Pressure ◽  
Western Alps ◽  
Metamorphic Evolution ◽  
Alpine Orogeny ◽  
Sedimentary Evolution ◽  
Hp Metamorphism ◽  
Tethys Ocean ◽  
Depositional Setting ◽  
Oceanic Rocks ◽  
Outer Band

Ophiolites of the Alpine belt derive from the closure of the Mesozoic Tethys Ocean that was interposed between the palaeo-Europe and palaeo-Adria continental plates. The Alpine orogeny has intensely reworked the oceanic rocks into metaophiolites with various metamorphic imprints. In the Western Alps, metaophiolites and continental-derived units are distributed within two paired bands: An inner band where Alpine subduction-related high-pressure (HP) metamorphism is preserved, and an outer band where blueschist to greenschist facies recrystallisation due to the decompression path prevails. The metaophiolites of the inner band are hugely important not just because they provide records of the prograde tectonic and metamorphic evolution of the Western Alps, but also because they retain the signature of the intra-oceanic tectono-sedimentary evolution. Lithostratigraphic and petrographic criteria applied to metasediments associated with HP metaophiolites reveal the occurrence of distinct tectono-stratigraphic successions including quartzites with marbles, chaotic rock units, and layered calc schists. These successions, although sliced, deformed, and superposed in complex ways during the orogenic stage, preserve remnants of their primary depositional setting constraining the pre-orogenic evolution of the Jurassic Tethys Ocean.

Migration of grain boundaries and triple junctions in high-purity aluminum during annealing after slight cold rolling

2015 ◽  
Vol 107 ◽  
pp. 134-138 ◽  
Author(s):  
Wenhong Yin ◽  
Weiguo Wang ◽  
Xiaoying Fang ◽  
Congxiang Qin ◽  
Xiaoguang Xing
Keyword(s):  
Cold Rolling ◽  
Grain Boundaries ◽  
High Purity ◽  
Triple Junctions ◽  
High Purity Aluminum

Quantifying the influence of non-hydrostatic stress on polymorph equilibria

2021 ◽  
Author(s):  
Benjamin Hess ◽  
Jay Ague
Keyword(s):  
High Pressure ◽  
Normal Stress ◽  
Chemical Potential ◽  
Hydrostatic Stress ◽  
Low Pressure ◽  
Surprising Result ◽  
Metamorphic Petrology ◽  
Equilibrium Thermodynamics ◽  
Stress Variation ◽  
Mineral Assemblages

<p>Thermodynamic modeling in active tectonic settings typically makes the assumption that stress is equal in all directions. This allows for the application of classical equilibrium thermodynamics. In contrast, geodynamic modeling indicates that differential, or non-hydrostatic, stresses are widespread. Non-hydrostatic equilibrium thermodynamics have been developed by past workers [1], but their application to geological systems has generated controversy in recent years [2-5]. Therefore, we seek to clarify how stress influences the chemical potential of non-hydrostatically stressed elastic solids. To quantify this, we consider the effects of stress variation on the equilibrium between the single-component polymorph pairs of kyanite/sillimanite, quartz/coesite, calcite/aragonite, and diamond/graphite.</p><p>The stress on each interface of a solid can be decomposed into components normal to the interface and parallel to the interface. In our work, we determine the shift in the temperature of equilibrium on fixed interfaces between polymorph pairs as a function of both interface-normal and interface-parallel stress variation. We find that the influence of normal stress variation on the equilibrium temperature of polymorphs is approximately two orders of magnitude greater than interface-parallel stress variation. Thus, at a fixed temperature, normal stress determines the chemical potential of a given interface to first order. Consequently, high-pressure polymorphs will preferentially form normal to the maximum stress, while low-pressure polymorphs, normal to the minimum stress.</p><p>Nonetheless, interface-parallel stress variations can meaningfully affect the stability of phases that are at or near equilibrium. We demonstrate the surprising result that for a given polymorph pair, a decrease in interface-parallel stresses can make a high-pressure polymorph more stable relative to a low-pressure polymorph on the given interface.</p><p>The effects of non-hydrostatic stress on mineral assemblages are most likely to be seen in dry systems. Many reactions in metamorphic systems are fluid-mediated, and fluids cannot sustain non-hydrostatic stress. Consequently, in systems with interconnected, fluid-filled porosity, mineral assemblages will tend to form at a pressure approximately equal to the fluid pressure. In contrast, in dry systems all reactions occur directly between solids which can sustain non-hydrostatic stress. This facilitates the application of non-hydrostatic thermodynamics. Consequently, dry rocks containing polymorphs such as such as quartzites, marbles, and peridotites represent ideal lithologies for the testing and application of these concepts. By influencing the chemical potential of solid interfaces, non-hydrostatic stress alters the thermodynamic driving force and subsequent kinetics of polymorphic reactions. This likely results in preferential orientations of polymorphs which could influence seismic anisotropy and potentially generate seismicity.</p><p>[1] Larché, F., & Cahn, J. W. (1985). Acta Metallurgica, 33(3), 331-357. https://doi.org/10.1016/0001-6160(85)90077-X</p><p>[2] Hobbs, B. E., & Ord, A. (2016). Earth-Science Reviews, 163, 190-233. https://doi.org/10.1016/j.earscirev.2016.08.013</p><p>[3] Powell, R., Evans, K. A., Green, E. C. R., & White, R. W. (2018). Journal of Metamorphic Petrology, 36(4), 419-438. https://doi.org/10.1111/jmg.12298</p><p>[4] Tajčmanová, L., Podladchikov, Y., Powell, R., Moulas, E., Vrijmoed, J. C., & Connolly, J. A. D. (2014). Journal of Metamorphic Petrology, 32(2), 195-207. https://doi.org/10.1111/jmg.12066</p><p>[5] Wheeler, J. (2018). Journal of Metamorphic Petrology, 36(4), 439-461. https://doi.org/10.1111/jmg.12299</p>

High Pressure Phase Relations for KDP-Type Compounds

1979 ◽  
pp. 261-265
Author(s):  
E. Rapoport ◽  
J. B. Clark ◽  
P. W. Richter
Keyword(s):  
High Pressure ◽  
Phase Relations ◽  
High Pressure Phase ◽  
Pressure Phase

HPHT synthesis and enhanced TE performance of Te and Sn/Se elements binary-doped CoSb3

2019 ◽  
Vol 12 (01) ◽  
pp. 1850105 ◽  
Author(s):  
Hairui Sun ◽  
Pin Lv ◽  
Chao Wang ◽  
Yunxian Liu ◽  
Xiaopeng Jia ◽  
...  
Keyword(s):  
Experimental Data ◽  
Thermal Conductivity ◽  
High Pressure ◽  
High Temperature ◽  
Seebeck Coefficient ◽  
Grain Boundaries ◽  
Preparation Methods ◽  
Synthesis Time ◽  
Lattice Disorder ◽  
Positive Effect

A series of binary-doped CoSb3 with Te and Se/Sn bulk compounds Co4Sb[Formula: see text]TexSny/Sey ([Formula: see text] and 0.6, [Formula: see text] and 0.3), have been successfully prepared via a simple high pressure and high-temperature (HPHT) method. And, the influence of the doping elements on the microstructure of the samples synthesized under diverse pressures and the corresponding TE performance were studied in detail. Comparing with other preparation methods, the synthesis time of HPHT was acutely shortened. The obtained samples contain more grain boundaries, lattice disorder, dislocations and the possible “nanodot”, which have positive effect on reducing thermal conductivity. The experimental data indicate that the absolute values of Seebeck coefficient increases with pressure. What’s more, the thermal conductivities show a monotone decreasing trend as the synthesis pressure rises. The minimum value obtained is 1.93[Formula: see text]Wm[Formula: see text]K[Formula: see text] at normal temperature for Co4Sb[Formula: see text]Te[Formula: see text]Se[Formula: see text] prepared under 3[Formula: see text]GPa.

Phase relations of camphene at high pressure up to 9.5 GPa

1998 ◽  
Vol 109 (2) ◽  
pp. 670-675 ◽  
Author(s):  
Kaichi Suito ◽  
Akihiro Ohta ◽  
Noriko Sakurai ◽  
Akifumi Onodera ◽  
Muneyuki Motoyama ◽  
...  
Keyword(s):  
High Pressure ◽  
Phase Relations

scholarly journals Failure Mechanisms of Cu–Cu Bumps under Thermal Cycling

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5522
Author(s):  
Kai-Cheng Shie ◽  
Po-Ning Hsu ◽  
Yu-Jin Li ◽  
Dinh-Phuc Tran ◽  
Chih Chen
Keyword(s):  
Thermal Cycling ◽  
Grain Boundaries ◽  
Maximum Stress ◽  
Failure Mechanisms ◽  
Deep Understanding ◽  
Bonding Interface ◽  
Triple Junctions ◽  
Element Analysis ◽  
Resistance Change ◽  
Hybrid Joints

The failure mechanisms of Cu–Cu bumps under thermal cycling test (TCT) were investigated. The resistance change of Cu–Cu bumps in chip corners was less than 20% after 1000 thermal cycles. Many cracks were found at the center of the bonding interface, assumed to be a result of weak grain boundaries. Finite element analysis (FEA) was performed to simulate the stress distribution under thermal cycling. The results show that the maximum stress was located close to the Cu redistribution lines (RDLs). With the TiW adhesion layer between the Cu–Cu bumps and RDLs, the bonding strength was strong enough to sustain the thermal stress. Additionally, the middle of the Cu–Cu bumps was subjected to tension. Some triple junctions with zig-zag grain boundaries after TCT were observed. From the pre-existing tiny voids at the bonding interface, cracks might initiate and propagate along the weak bonding interface. In order to avoid such failures, a postannealing bonding process was adopted to completely eliminate the bonding interface of Cu–Cu bumps. This study delivers a deep understanding of the thermal cycling reliability of Cu–Cu hybrid joints.

Phase relations of iron–silicon alloys at high pressure and high temperature

2009 ◽  
Vol 36 (9) ◽  
pp. 511-518 ◽  
Author(s):  
Yasuhiro Kuwayama ◽  
Toshimitsu Sawai ◽  
Kei Hirose ◽  
Nagayoshi Sata ◽  
Yasuo Ohishi
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Phase Relations ◽  
Silicon Alloys ◽  
Iron Silicon

Metamorphic chronology of the Precambrian provinces of South India

1968 ◽  
Vol 5 (3) ◽  
pp. 591-600 ◽  
Author(s):  
U. Aswathanarayana
Keyword(s):  
South India ◽  
Regional Metamorphism ◽  
Southern India ◽  
Eastern Ghats ◽  
Cuddapah Basin ◽  
Upper Limit

There are three Precambrian provinces in southern India — the Dharwars (metavolcanics, metasediments, charnockites and granites), the Eastern Ghats (metasediments, charnockites and granites), and the Cuddapahs (essentially flat-lying continental sediments disturbed at the margins) — with chronostratigraphic histories dovetailing into one another. The Dharwars bear the impress of three episodes (about 3000 m.y., 2600–2300 m.y., and about 2000 m.y.) of folding, metamorphism, and emplacement of granites, the second being the most important. The pelitic sediments deposited in the Eastern Ghats geosyncline during the post-Dharwar times (upper limit, 2600 m.y.) were later folded and metamorphosed about 1600 m.y. ago into garnet-sillimanite-graphite gneisses (khondalites). Important deposits of mica pegmatites developed during this episode. Charnockites and granites associated with the Eastern Ghats were emplaced 1520–1300 m.y. ago. The Eastern Ghats rocks were subsequently cross-folded and metamorphosed about 500 m.y. ago. The sedimentation in the Cuddapah Basin was initiated sometime after the Eastern Ghats orogeny (1600 m.y. ago) but before 1160 m.y. ago. The Cuddapahs were subjected to regional metamorphism about 500 m.y. ago.

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