scholarly journals ADSORPSI-DESORPSI ZAT WARNA AZO JENIS REMAZOL BLACK B MENGGUNAKAN MEMBRAN POLIELEKTROLIT (PEC) KITOSAN-PEKTIN

2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Ni Putu Sri Ayuni ◽  
Ni Wayan Yuningrat ◽  
Ketut Yesi Andriani
Keyword(s):  
Optimum Condition ◽  
Azo Dyes ◽  
Contact Time ◽  
Freundlich Isotherm ◽  
Maximum Capacity ◽  
Isotherm Equation ◽  
Remazol Black B ◽  
Remazol Black ◽  
Membrane Characteristic

Abstrak Sekitar 2-50% dari zat warna azo yang digunakan selama proses pencelupan ini tidak mengikat serat dan langsung dilepaskan ke lingkungan melalui instalasi pengolahan limbah. Hal ini perlu dilakukan pengolahan limbah cair yang mengandung zat warna azo jenis Remazol Black B sebelum dibuang ke lingkungan. Penelitian ini bertujuan untuk mengetahui kondisi optimum membran PEC kitosan-pektin yang dapat digunakan untuk mengadsorpsi zat warna azo jenis Remazol Black B .Untuk memperoleh kondisi optimum akan dilakukan adsorpsi zat warna azo jenis Remazol Black B dengan variasi waktu kontak (5-150 menit), pH (5-9) dan konsentrasi larutan zat warna azo jenis Remazol Black B (5, 10, 15, 20, dan 25 mg/L). Untuk mengetahui karakteristik zat warna jenis Remazol Black B oleh membran PEC kitosan-pektin di analisis dengan persamaan isoterm adsorpsi Langmuir dan isoterm adsorpsi Freundlich sedangkan daya adsorpsi maksimum dari membran PEC kitosan pektin ditentukan dari kurva berdasarkan karakteristik membran yang diperoleh. Hasil penelitian menunjukkan bahwa adsorpsi zat warna azo jenis Remazol Black B terjadi pada kondisi optimum dengan pH 5, waktu 120 menit dan konsentrasi larutan zat warna azo jenis Remazol Black B 10 mg/L (62,75 %). Pola adsorpsi mengikuti pola adsorpsi isoterm Freundlich dengan daya adsorpsi maksimum 0,02 (mg/g). Untuk efisiensi desorpsi maksimal diperoleh pada larutan NaCl 1 M (11,17 %) Kata Kunci: adsorpsi, membran polielektrolit kitosan pektin, Remazol Black B Abstract Azo dyes produced approximately 2-50% from dying process were thrown through effluent to the environment without any treatment. The objective of this research were to know the optimum condition of PEC chitosan pectin membrane using to adsorp Remazol Black B with various contact time (5-150 min), pH (5-9) and Remazol Black B concentration (5, 10, 15, 20, dan 25 mg/L). Adsorption charactheristic of Remazol Black B by PEC chitosan pectin membrane were determined by Langmuir and Freundlich isotherm equation. Maximum capacity adsorption was determined by the graph of membrane characteristic. The results show that optimum condition of Remazol Black B adsorption by PEC chitosan pectin membrane at pH 5, 10 mg/L remazol black B for 120 minutes (62,75 %). The adsorption pattern is Freundlich isoterm with maximum capacity 0,02 (mg/g).Maximal Desorption efisiency at NaCl 1 M (11,17 %) Keywords : adsorption, PEC chitosan pectin membrane, Remazol Black B

scholarly journals Decolorization of Remazol Black B Solution by PbO2 Modified Fenton Method in a Scaled Up Reactor

2018 ◽  
Vol 21 (2) ◽  
pp. 59-63
Author(s):  
Muhamad Abduh Hasibuan ◽  
Didik Setiyo Widodo ◽  
Retno Ariadi Lusiana
Keyword(s):  
Optimum Condition ◽  
Azo Dyes ◽  
Environmental Conditions ◽  
Scale Up ◽  
Aquatic System ◽  
Remazol Black B ◽  
Modified Fenton ◽  
Remazol Black

Study on decolourization of remazol black B (RBB) solution has been performed in a scale up reactor. As an artificial waste, the dye sample that contains azo groups is difficult to decompose under ordinary environmental conditions so it requires further treatment before discharging to open aquatic system. Many efforts have been reported and further developed toward other azo dyes. One of an outstanding approach is Fenton method. This study modified the method with PbO2 rather than Fe2+. In this modification, the dyestuff was degraded by radical •OH resulting from reaction between H2O2 and Pb2+ ion generated from PbO2. In Preliminary works, decolourization was performed and optimized in lab-scaled. Analysis were conducted and the best condition was applied to decolorize the sample in a scale-up size. Characteristics of the reactor was also determined. Results showed that at optimum condition, 100 mL of 50 ppm remazol black B was decolorized up to 98.82 % within 15 minutes. On scale up to 1 L-sized reactor, within the time highest percentages of remazol black B decolourization was reached 82.02 % by addition of 10 % H2O2 and COD decrease to 98.96 %. In the 1 L reactor, RBB sample with concentration of 50 ppm, PbO2 1 gram and H2O2 10 % obey the proposed decolourization equation of D = -0,0011x2 + 0.5705x – 0.6788 with x = volume peroxide (in mL), D = percent of decolourization.

scholarly journals A Comparative Study for Adsorptive Removal of Remazol Red R and Remazol Black B from Aqueous Solution by ZnO

2018 ◽  
Vol 66 (2) ◽  
pp. 121-127
Author(s):  
AZM Mainul Islam Mazumder ◽  
Chowdhury Raihan Bikash ◽  
Md Ataur Rahman ◽  
Md Mufazzal Hossain
Keyword(s):  
Freundlich Isotherm ◽  
Order Kinetic ◽  
Adsorptive Removal ◽  
First Order ◽  
Remazol Black B ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Pseudo First Order ◽  
Remazol Red ◽  
Remazol Black

Adsorptive removal of remazol red R (RRR) and remazol black B (RBB) from aqueous solution has been investigated by using ZnO as an adsorbent. Time for adsorption equilibrium, kinetics of adsorption at different initial concentrations of dyes and adsorption isotherms at different temperatures have been studied. Adsorption capacity increased with increasing initial dye concentration. The pseudo first-order and pseudo second-order kinetics were used to describe kinetic data and the rate constants were evaluated. Experimental data fits better in the pseudo second-order kinetic model than in the pseudo first-order kinetic model for both the dyes. Langmuir and Freundlich isotherm models were applied to describe the adsorption of RRR and RBB onto ZnO powders. Langmuir isotherm model provided a better correlation for the experimental data in comparison to the Freundlich isotherm model. Adsorption of both RRR and RBB on ZnO are physical in nature and increases with decreasing temperature. The equilibrium adsorption capacity decreases from 3.43 mg/g at 200C to 2.36 mg/g at 400C for RRR whereas that in the case of RBB changes from 0.77 mg/g at 300C to 0.75 mg/g at 400C. Adsorption of RRR on ZnO was found to be three times higher than the adsorption of RBB at a particular temperature. A model for adsorption of both the dyes has been proposed. Dhaka Univ. J. Sci. 66(2): 121-127, 2018 (July)

scholarly journals KONDISI OPTIMUM ADSORPSI-FLUIDISASI ZAT WARNA LIMBAH TEKSTIL MENGGUNAKAN ADSORBEN JANTUNG PISANG

2018 ◽  
Vol 2 (1) ◽  
pp. 1
Author(s):  
Dheasy Herawati ◽  
Setyo Dwi Santoso ◽  
Ilma Amalina
Keyword(s):  
Methylene Blue ◽  
Optimum Condition ◽  
Congo Red ◽  
Contact Time ◽  
Degradation Products ◽  
New Technology ◽  
Textile Dyes ◽  
Dyes Adsorption ◽  
Red Dye ◽  
Remazol Black

To show that banana inflorescence has effective adsorbent for the adsorption of dyes (congo red, remazol yellow, remazol black and methylene blue) from textile dyes waste and also to detrmine the optimum conditions of variety of pH (4-10), temperature (30°C-90°C), and contact time (15-105 minute) on the percentage adsorption capacity of banana inflorescence. Textile dyes waste and their degradation products such as aromatic amines are highhly carcinogenic. Adsorption-fluidization is a new technology for treatment of waste water containing different types of dyes. Adsorption-fluidization process is adopted for adsorption of dyes from the textile dyes waste using banana inflorescence in treated form and were analysed by Utraviolet-Visible Spectroscopy. The results showed that the optimum condition from adsorption process of Congo Red dye by banana inflorescence was reached at pH 5 (1.78%), temperature 60°C (1.51%) and 45 minute contact time (1.63%). While Remazol Yellow dye optimum at pH 9 (4.29%), temperature 50°C (4.65%) and 75 min (1.83%). Another dye, Methylene Blue showed the optimum condition at pH 9 (0.36%), temperature 40°C (0.22%) and 45 min contact time of adsorption (0.43%). The last, Remazol Black dye was reached at pH 5 (0.56%), temperature 40°C (0.56%) and 75 min contact time (0.56%).

Exploring the potential of halophilic archaea for the decolorization of azo dyes

2018 ◽  
Vol 77 (6) ◽  
pp. 1602-1611 ◽  
Author(s):  
Masoomeh Selseleh Hassan Kiadehi ◽  
Mohammad Ali Amoozegar ◽  
Sedigheh Asad ◽  
Maryam Siroosi
Keyword(s):  
Azo Dyes ◽  
Halophilic Archaea ◽  
Nitrogen Sources ◽  
Proper Solution ◽  
Carbon And Nitrogen Sources ◽  
Carbon And Nitrogen ◽  
Remazol Black B ◽  
Textile Industries ◽  
Acid Blue ◽  
Remazol Black

Abstract Azo dyes are being extensively used in textile industries, so finding a proper solution to decolorize them is of high importance. In order to find azo dye decolorizing strains among haloarchaea, which are well known for their tolerance to harsh environmental conditions, fifteen haloarchaeal strains were screened. Halogeometricum sp. strain A and Haloferax sp. strain B with the highest decolorization ability (95% and 91% for Remazol black B; both about 60% for Acid blue 161, respectively) were selected for further studies. It was shown that both strains were able to grow and decolorize the dye in a medium containing up to 5 M NaCl, with optimum decolorization activity at 2.5–3.4 M, pH 7, and a wide temperature range between 30 to 45 °C. Moreover, both strains were able to tolerate and decolorize up to 1,000 mg l−1 Remazol black B. Also, they were able to survive in 5,000 mg l−1 of the dye after 20 days' incubation. Glucose and yeast extract were found to be the best carbon and nitrogen sources in the decolorization medium for both strains. This is the first report studying decolorization of azo dyes using halophilic archaea.

Fuchsine Adsorption from Aqueous Solution by Epichlorohydrin Crosslinked Peanut Husk

2012 ◽  
Vol 549 ◽  
pp. 362-365 ◽  
Author(s):  
Ying Hua Song ◽  
Sheng Ming Chen ◽  
Jian Min Ren ◽  
Yuan Gao ◽  
Hui Xu
Keyword(s):  
Aqueous Solution ◽  
Contact Time ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Freundlich Isotherm ◽  
Order Model ◽  
Isotherm Equation ◽  
Thermodynamic Constants ◽  
Pseudo Second Order ◽  
Uptake Studies

The adsorption of fuchsine by peanut husk, which was crosslinked by epichlorohydrin was studied with variation in the parameters of contact time, pH, initial fuchsine concentration and temperature. They were used for equilibrium adsorption uptake studies with fuchsine. The results indicate that adsorption equilibrium could be well described by both the Langmuir and the Freundlich isotherm equation. The adsorption followed the pseudo-second order model. The thermodynamic constants of the adsorption process were also evaluated, which suggest an endothermic adsorption process which runs spontaneously.

scholarly journals Determination of Optimum pH and Contact Time from the Adsorption Process of Cu(II) Ions by Corn Cob (Zea mays) Biomass

2011 ◽  
Vol 9 (4) ◽  
pp. 224-229
Author(s):  
Riska T. Windiastuti ◽  
Tri Santoso
Keyword(s):  
Contact Time ◽  
Adsorption Process ◽  
Ph Value ◽  
Toxic Waste ◽  
Maximum Adsorption Capacity ◽  
Corn Cob ◽  
Maximum Capacity ◽  
Isotherm Equation ◽  
Corn Cobs ◽  
Optimum Ph

The use of Cu in daily life and industry can produce toxic waste, both for the human body and the environment. This study aimed to determine the optimum pH value and contact time, and the maximum capacity of the adsorption process of Cu(II) ions by corn cob biomass. The optimum pH and contact time were determined based on the adsorption graph of the adsorbent obtained from the optimization of pH and time, while the maximum adsorption capacity was determined using the Langmuir adsorption isotherm equation. The results showed that the optimum pH adsorption of Cu(II) ions by corn cob absorbent occurred at pH 7 with the absorption of 98.34%. Optimum contact time occurred at the 60th minute with the percentage of copper absorbed was 96.37%. Besides, the maximum capacity adsorption of corn cobs toward Cu(II) ions was 2.416 mg/g. This study concluded that corn cobs can be used as an adsorbent of Cu(II) ions.

Biosorption of Eosin by Chemically Modified Peanut Husk

2011 ◽  
Vol 233-235 ◽  
pp. 439-443
Author(s):  
Ying Hua Song ◽  
Sheng Ming Chen
Keyword(s):  
Freundlich Isotherm ◽  
Sorption Process ◽  
Intraparticle Diffusion ◽  
Transfer Model ◽  
Experimental Conditions ◽  
Isotherm Equation ◽  
Chemically Modified ◽  
Pseudo Second Order ◽  
Uptake Studies ◽  
Rate Controlling Step

The sorption of eosin by peanut husk, which was chemically modified by formaldehyde in acidic medium was studied with variation in the parameters of contact time, pH, initial eosin concentration and temperature. They were used for equilibrium sorption uptake studies with eosin. The results indicate that sorption equilibrium could be well described by the Freundlich isotherm equation. The sorption followed the pseudo-second order model. The mass transfer model as intraparticle diffusion was applied to the experimental data to examine the mechanisms of the rate controlling step. It was found that the intraparticle diffusion is becoming the significant controlling step under the experimental conditions. The thermodynamic constants of the sorption process were also evaluated, which suggest an endothermic physical sorption process which runs spontaneously.

scholarly journals IMMOBILIZATION OF Saccharomycess cereviceae BIOMASS ON CHITOSAN AND ITS APPLICATION AS AN ADSORBENT FOR Pb(II) ION

2011 ◽  
Vol 11 (2) ◽  
pp. 174-179 ◽  
Author(s):  
Hasri Hasri ◽  
Mudasir Mudasir ◽  
Nurul Hidayat Aprilita ◽  
Roto Roto
Keyword(s):  
Optimum Condition ◽  
Functional Groups ◽  
Contact Time ◽  
Metal Ion ◽  
Mass Ratio ◽  
Adsorption Experiment ◽  
Ion Removal ◽  
Before And After ◽  
The Difference

An application of Saccharomycess cereviceae biomass immobilized on chitosan (SC-Chi adsorbent) for Pb(II) ion removal was demonstrated. Adsorption experiment was conducted at various mass ratio of Saccharomycess cereviceae biomass to chitosan, contact time, pH of solution and concentration of cation. Total Pb(II) metal ion adsorbed was calculated from the difference of the amount of metal ion before and after adsorption which was measured by AAS. The results showed that optimum condition for adsorption of Pb(II) ion by the SC-Chi was achieved using mass ratio of Saccharomycess cereviceae to chitosan of 50% (w/w), pH solution of 7, contact time of 60 min and concentration of 25 mgL-1. The hydroxyl (-OH) and amino (-NH2) functional groups are believed to be responsible for the adsorption of Pb(II) ion by the adsorbent.

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