scholarly journals Humic substances of differently matured composts produced from municipal solid wastes and biomass of energetic plants

2019 ◽  
Vol 70 (4) ◽  
pp. 292-297 ◽  
Author(s):  
Andrea Kałuża-Haładyn ◽  
Elżbieta Jamroz ◽  
Jakub Bekier

Abstract The aim of the study was to assess the transformation of humic substances during composting of biomass of energetic plants and municipal solid waste. The type of the organic material to be composted and the type of technology used affect the course of the humic substances transformation and formation of compost maturity parameters. Compost produced from the mixture of energetic willow and hay biomass contained humic substances with higher share of low-molecular fractions and lower share of humic acids in total organic carbon than those produced from municipal solid wastes. Obtained results also showed that insoluble alkali fraction plays an important role in humification process by its convertion to a new humic substances. Share of humic and fulvic fractions in relation to the total organic carbon appears to be reliable indicator of composting as a process of enhancing organic matter humification.

2019 ◽  
Vol 64 (2) ◽  
pp. 230-237
Author(s):  
Renata Rauch ◽  
Rita Foldenyi

It is not only Total Organic Carbon content (TOC) but also the type of Organic Matter (OM) that the sorption of organic pollutants by soils or other natural absorbents is correlated with. Therefore, the characterization of organic components in the adsorbents is very important to elucidate sorption mechanisms.Oil shale samples were collected in Pula, Hungary. The TOC content of the investigated samples was approximately 6.8-40.1 m/m %. The characterization of the organic matter in samples was carried out by using Scanning Electron Microscopy (SEM), elemental analysis, thermal analysis, and GC-MS technics. The results predominantly indicated the presence of a low degree of the branching of aliphatic chain components in the samples. The Humic Substances (HS) content of the samples was only 1-6 m/m %, which could be determined after the treatment of oil shale with hydrogen peroxide.The influence of the amount and type of organic material in oil shale samples was studied on the adsorption of 2,4-dichlorophenol (2,4-DCP) as a model contaminant. For this aim a series of batch equilibration experiments was carried out. The results show that the total organic carbon content of samples is a strong indicator of 2,4-DCP adsorption, while the HS content is an important feature controlling sorption capacity. The study suggests that the special organic matter (kerogen) content of the oil shale plays a major role in its high adsorption capacity and in the nonlinearity of the isotherms. The HS covering the surface could decrease the sorption capacities despite the fact that though the amount of this organic material is quite low.


2020 ◽  
pp. 1-11
Author(s):  
S. A. Nta ◽  
M. J. Ayotamuno ◽  
A. H. Igoni ◽  
R. H. Okparanma

This paper presents soil quality as affected by dumped municipal solid waste. Landfill leachate was collected from a hole dug 10 m away from the waste dump site for laboratory analysis. Soil samples were also collected from four trial pits in the dumpsites at the depth of 0.3, 0.6 and 0.9 m and at a distance of 10, 20, 30 m and the control 100 m away from the dumping site. The collected soil samples were subjected to physiochemical and geotechnical analysis. This includes particle size distribution, pH, EC, total organic carbon, total organic matter, extractable micronutrients and heavy metals (Zn, Cu, Mn, Fe, Pb, Cd, Cr, Cl and Ni), Attterberg limits, specific gravity and hydraulic conductivity. The physicochemical concentration was then compared with the maximum allowable concentrations of chemical constituents in uncontaminated soil. The Laboratory analysis shows high value of pH (8.51) DO (0.17 mg/l), COD (68mg/l), BOD5 (324 mg/l), Pb (0.31 mg/l) and Cd (0.06 mg/l) in the leachate sample. The physical properties of the soil near the dumpsite indicated that the soil belongs to sandy loam in texture. pH (6.3-8.32), Electrical conductivity (241-2018 s/cm), total organic carbon (0.24-2.16 ) and total organic matter (0.41-3.73%) were higher near the vicinity of the dumpsite and decreased with increase in the depth and distance. Extractable micro nutrient and heavy metal concentration (Zn, Cu, Mn, Fe, Pb, Cd, Cr, Cl and Ni) were also found to be high near the dumpsite and decreased along the soil depth and distance from the dumping site. The variance in the geotechnical properties of soil revealed by the test results was impacted by the dumped municipal solid waste. These effects decrease with increase in depth. These findings will help in facilitating the invention and introduction of site specific technologies. 


2017 ◽  
Vol 866 ◽  
pp. 132-135
Author(s):  
Varinthorn Boonyaroj ◽  
Melin Khonthee ◽  
Nuanjira Maneewong ◽  
Chatchai Doungkaew

This research aims to evaluate the performance of laboratory-scale in-vessel composting bioreactor for the organic wastes fraction of municipal solid wastes in Faculty of Science and Technology, Rajamangala University of Technology Phra Nakhon, Bangkok. The bioreactor was special designed and used for this research with working volume of the reactor was 10 L, and it was operated with varied press air and organic wastes fraction. Obtained results showed that organic fraction of municipal solid waste could be composted successfully in 20 days. The qualities of compost in terms of the ratio of carbon to nitrogen (C/N), temperature, pH value, moisture content (%M), total nitrogen (%N), potassium (K2O), phosphorus (P2O5), organic matter (%OM), and organic carbon (%OC) were investigated.


2017 ◽  
Vol 9 (12) ◽  
pp. 152
Author(s):  
Carlos Augusto Rocha de Moraes Rego ◽  
Jonas Francisco Egewarth ◽  
Marcio André Francziskowski ◽  
Felipe Eliazar Cremonez ◽  
Paulo Sérgio Rabello de Oliveira ◽  
...  

Soil organic matter is degraded and easily altered by the type of management. The objective of this work is to determine the total organic carbon and humic substance fractions in the organic matter of the soil with different management types and depths in the western region of Paraná, Brazil. The work was carried out in the Experimental Farm “Professor Antônio Carlos dos Santos Pessoa”, belonging to the State University of the West of Paraná. Five soil management systems were evaluated: one area with corn cultivation for silage (CS); other area with succession of crops, with soybean in summer and corn in winter (SC); the next area also with succession of crops, with soy in the summer and oat in the winter (SO); the following area with permanent pasture with Tifton (PP); and the last area with crop-livestock integration (ILC). For each management system, four plots were randomly selected, in each plot three simple samples were collected in a diagonal direction to form a composite sample for the depth of 0.00-0.05 m, 0.05-0.10 m and 0.10-0.15 m. Total organic carbon, fractionation of the humic substances and the AH/AF and EA/HUM ratios were calculated. For most of the analyzed variables, it was verified that there were significant differences (P < 0.05) between the systems evaluated in the studied depths. In the evaluated areas, the PP, SO and ILC systems presented the highest carbon content for all attributes analyzed.


2020 ◽  
Vol 5 (4) ◽  
pp. 202-209
Author(s):  
Alexander Topal ◽  
◽  
Iryna Holenko ◽  
Luidmyla Haponych ◽  
◽  
...  

For the municipal solid waste (MSW) to be used in a proper way, it is necessary to implement clean technologies capable of thermal treatment of MSW and RDF in order to produce heat and electricity while meeting current ecological requirements. Nowadays, a number of technologies for MSW/RDF thermal treating are being used worldwide. Among them, the most proven technologies, applicable for industrial introduction, have been considered while analyzing their advantages/ disadvantages accounting for local conditions of Ukraine.


Author(s):  
Nabil Kechaou ◽  
E Ammar

The Municipal Solid Waste of Agareb (Sfax –Tunisia), characterized by high organic fraction and moisture contents is the most worrying pollution source that must be managed by innovative treatment and recycling technologies. Bio-drying, as a waste to energy conversion technology, aims at reducing moisture content of this organic matter. This concept,  similar to composting, is accomplished by using the heat generated from the microbial degradation of the waste matrix, while forced aeration is used. The purpose of this work was to reduce the moisture content of the waste, by maximizing drying and minimizing organic matter biodegradation, in order to produce a solid recovered fuel with high calorific value.Keywords: Municipal solid wastes; organic matter; biodrying; composting; energy recovery.


2018 ◽  
Vol 36 (5) ◽  
pp. 1157-1171
Author(s):  
Agostinho Mussa ◽  
Deolinda Flores ◽  
Joana Ribeiro ◽  
Ana MP Mizusaki ◽  
Mónica Chamussa ◽  
...  

The Mozambique Basin, which occurs onshore and offshore in the central and southern parts of Mozambique, contains a thick sequence of volcanic and sedimentary rocks that range in age from the Jurassic to Cenozoic. This basin, along with the Rovuma basin to the north, has been the main target for hydrocarbon exploration; however, published data on hydrocarbon occurrences do not exist. In this context, the present study aims to contribute to the understanding of the nature of the organic matter of a sedimentary sequence intercepted by the Nemo-1X exploration well located in the offshore area of the Mozambique Basin. The well reached a depth of 4127 m, and 33 samples were collected from a depth of 2219–3676 m ranging in age from early to Late Cretaceous. In this study, petrographic and geochemical analytical methods were applied to assess the level of vitrinite reflectance and the organic matter type as well as the total organic carbon, total sulfur, and CaCO3 contents. The results show that the total organic carbon content ranges from 0.41 to 1.34 wt%, with the highest values determined in the samples from the Lower Domo Shale and Sena Formations, which may be related to the presence of the solid bitumens that occur in the carbonate fraction of those samples. The vitrinite random reflectances range from 0.65 to 0.86%Rrandom, suggesting that the organic matter in all of the samples is in the peak phase of the “oil generation window” (0.65–0.9%Rrandom). The organic matter is mainly composed of vitrinite and inertinite macerals, with a minor contribution of sporinite from the liptinite group, which is typical of kerogen type III. Although all of the samples have vitrinite reflectances corresponding to the oil window, the formation of liquid hydrocarbons is rather limited because the organic matter is dominated by gas-prone kerogen type III.


2004 ◽  
Vol 64 (3b) ◽  
pp. 583-590 ◽  
Author(s):  
M. B. Cunha-Santino ◽  
I. Bianchini JR.

Assays were carried out to evaluate the dissolved oxygen uptake resulting from mineralization of humic substances (fulvic acid (FA) and humic acid (HA)) from different sources: sediment, dissolved organic matter (DOM) of 120-day decomposed aquatic macrophyte (Scirpus cubensis and Cabomba piauhyensis), and lagoon DOM. The experiments were also aimed at estimating the oxygen uptake coefficient of the mineralization. About 20-30 mg of substrate were added to 1.1 liters of water from Infernão Lagoon (21º33' to 21º37'S; 47º45' to 47º51'W). The solutions were aerated and the dissolved oxygen (DO) was monitored during 40 days. Dissolved organic carbon (DOC) and particulate organic carbon (POC) were estimated after 80 days of the experiment. Anaerobic processes were avoided by aerating the solutions. The results were fitted to a first-order kinetics model, from which the uptake of oxygen parameters was obtained. Oxygen consumption (OC) ranged from 4.24 mg L-1 (HA - S. cubensis) to 33.76 mg L-1 (FA - sediment). The highest deoxygenation coefficient (kD) was observed during mineralization of FA - DOM (0.299 day-1), followed in decreasing order by FA - S. cubensis, HA - sediment, HA - S. cubensis, FA - sediment, and FA - C. piauhyensis (0.282; 0.255; 0.178; 0.130, and 0.123 day-1, respectively). The carbon analyses indicated that the FA and HA samples at the end of the experiment presented a decay that varied from 15.23% to 42.35% and that the FA and HA conversions into POC were relatively low (from 0.76% to 3.94%).


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