scholarly journals Circuit Analysis of Ionizing Surface Potential Measurements of Electrolyte Solutions

Author(s):  
Tehseen Adel ◽  
Juan Velez-Alvarez ◽  
Anne C. Co ◽  
Heather Allen

Surface potential measurement values of the gas-liquid interface can be ambiguous despite the numerous electrochemical approaches used for quantification of the reported values. Calibration and normalization methods can be undefined, which often undermines the robustness of the reported values. Surface potential instrumentation and data interpretation also varies significantly across literature. Here, we propose a circuit model for an ionizing surface potential method based on the alpha decay of a radioactive americium-241 electrode. We evaluate the robustness of the circuit model for quantifying the surface potential at the air-aqueous interface. We then show successful validation of our circuit model through determination of the surface tension of the air-electrolyte interface with comparison to respective surface tension literature values. This validation reveals the reliability of surface potential measurements using the americium-241 ionizing method.<br>

2020 ◽  
Author(s):  
Tehseen Adel ◽  
Juan Velez-Alvarez ◽  
Anne C. Co ◽  
Heather Allen

Surface potential measurement values of the gas-liquid interface can be ambiguous despite the numerous electrochemical approaches used for quantification of the reported values. Calibration and normalization methods can be undefined, which often undermines the robustness of the reported values. Surface potential instrumentation and data interpretation also varies significantly across literature. Here, we propose a circuit model for an ionizing surface potential method based on the alpha decay of a radioactive americium-241 electrode. We evaluate the robustness of the circuit model for quantifying the surface potential at the air-aqueous interface. We then show successful validation of our circuit model through determination of the surface tension of the air-electrolyte interface with comparison to respective surface tension literature values. This validation reveals the reliability of surface potential measurements using the americium-241 ionizing method.<br>


1997 ◽  
Vol 42 (19) ◽  
pp. 2899-2905 ◽  
Author(s):  
J. Dabkowski ◽  
M. Dabkowska ◽  
R. Pruszkowska-Drachal ◽  
Z. Koczorowski ◽  
S. Trasatti

2016 ◽  
Vol 16 (4) ◽  
pp. 3248-3253 ◽  
Author(s):  
Eiji Itoh ◽  
Yoshinori Goto ◽  
Yusuke Saka ◽  
Katsutoshi Fukuda

We have investigated the photovoltaic properties of an inverted bulk heterojunction (BHJ) cell in a device with an indium-tin-oxide (ITO)/electron selective layer (ESL)/P3HT:PCBM active layer/MoOx/Ag multilayered structure. The insertion of only single layer of poly(diallyl-dimethylammonium chloride) (PDDA) cationic polymer film (or poly(ethyleneimine) (PEI) polymeric interfacial dipole layer) and titanium oxide nanosheet (TN) films as an ESL effectively improved cell performance. Abnormal S-shaped curves were observed in the inverted BHJ cells owing to the contact resistance across the ITO/active layer interface and the ITO/PDDA/TN/active layer interface. The series resistance across the ITO/ESL interface in the inverted BHJ cell was successfully reduced using an interfacial layer with a positively charged surface potential with respect to ITO base electrode. The positive dipole in PEI and the electronic charge phenomena at the electrophoretic deposited TN (ED-TN) films on ITO contributed to the reduction of the contact resistance at the electrode interface. The surface potential measurement revealed that the energy alignment by the transfer of electronic charges from the ED-TN to the base electrodes. The insertion of the ESL with a large positive surface potential reduced the potential barrier for the electron injection at ITO/TN interface and it improved the photovoltaic properties of the inverted cell with an ITO/TN/active layer/MoOx/Ag structure.


2009 ◽  
Vol 154 ◽  
pp. 95-100 ◽  
Author(s):  
Seiichi Miyazaki ◽  
Mitsuhisa Ikeda ◽  
Katsunori Makihara ◽  
K. Shimanoe ◽  
R. Matsumoto

We demonstrated a new fabrication method of Pt- and Ni-silicide nanodots with an areal density of the order of ~1011 cm-2 on SiO2 through the process steps of ultrathin metal film deposition on pre-grown Si-QDs and subsequent remote H2 plasma treatments at room temperature. Verification of electrical separation among silicide nanodots was made by measuring surface potential changes due to electron injection and extraction using an AFM/Kelvin probe technique. Photoemission measurements confirm a deeper potential well of silicide nanodots than Si-QDs and a resultant superior charge retention was also verified by surface potential measurements after charging to and discharging. Also, the advantage in many electron storage per silicide nanodot was demonstrated in C-V characteristics of MIS capacitors with silicide nanodots FGs.


2017 ◽  
Vol 121 (50) ◽  
pp. 28017-28030 ◽  
Author(s):  
Sarah M. Walker ◽  
Maria C. Marcano ◽  
Sooyeon Kim ◽  
Sandra D. Taylor ◽  
Udo Becker

1988 ◽  
Vol 64 (5) ◽  
pp. 2638-2647 ◽  
Author(s):  
M. P. Connolly ◽  
D. H. Michael ◽  
R. Collins

2013 ◽  
Vol 3 (1) ◽  
Author(s):  
Vishal Panchal ◽  
Ruth Pearce ◽  
Rositza Yakimova ◽  
Alexander Tzalenchuk ◽  
Olga Kazakova

Sign in / Sign up

Export Citation Format

Share Document