scholarly journals A Study of the Frequency Domain Induced Polarisation Effects Displayed by Clay and by Cation Exchange Resin, Model Soil Systems

2021 ◽  
Author(s):  
◽  
Michael Charles Harold McKubre
Keyword(s):  
Cation Exchange ◽  
Frequency Domain ◽  
Field Observation ◽  
Exchange Resin ◽  
Cation Exchange Resin ◽  
Impedance Spectra ◽  
Frequency Range ◽  
Model Soil ◽  
Soil Systems ◽  
Induced Polarisation

<p>Work is reported of the development of clay and resin model soil systems for the observation of induced polarisation phenomena. A measuring technique is developed to determine impedance spectra of such models over the frequency range of 10-3 to 10 4 Hz, and a variety of model cells tested varying such parameters as temperature, electrolyte type and concentration, and bead size of resin. An increase in impedance with decrease in frequency is observed, consistent with field observation of the induced polarisation phenomenon associated with moist, non-mineralised soils, and a number of empirical observations of the form of this are made.</p>

scholarly journals A Study of the Frequency Domain Induced Polarisation Effects Displayed by Clay and by Cation Exchange Resin, Model Soil Systems

2021 ◽  
Author(s):  
◽  
Michael Charles Harold McKubre
Keyword(s):  
Cation Exchange ◽  
Frequency Domain ◽  
Field Observation ◽  
Exchange Resin ◽  
Cation Exchange Resin ◽  
Impedance Spectra ◽  
Frequency Range ◽  
Model Soil ◽  
Soil Systems ◽  
Induced Polarisation

<p>Work is reported of the development of clay and resin model soil systems for the observation of induced polarisation phenomena. A measuring technique is developed to determine impedance spectra of such models over the frequency range of 10-3 to 10 4 Hz, and a variety of model cells tested varying such parameters as temperature, electrolyte type and concentration, and bead size of resin. An increase in impedance with decrease in frequency is observed, consistent with field observation of the induced polarisation phenomenon associated with moist, non-mineralised soils, and a number of empirical observations of the form of this are made.</p>

Synthesis of 3,4-Dihydropyrano[c]chromenes Using Carbon Microsphere Supported Copper Nanoparticles (Cu-NP/C) Prepared from Loaded Cation Exchange Resin as a Catalyst

2019 ◽  
Vol 16 (2) ◽  
pp. 288-293
Author(s):  
Yogesh W. More ◽  
Sunil U. Tekale ◽  
Nitishkumar S. Kaminwar ◽  
László Kótai ◽  
Tibor Pasinszki ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Cation Exchange ◽  
Copper Nanoparticles ◽  
Exchange Resin ◽  
Cation Exchange Resin ◽  
Environmentally Benign ◽  
High Yield ◽  
Carbon Microsphere ◽  
Catalytic Material ◽  
Operational Simplicity

Aim and Objective: The present study was performed with the aim to develop an efficient and environmentally benign protocol for the synthesis of biologically siginifcant 3, 4-dihydropyrano[c]chromenes using a new catalytic material. The protocol involves the use of a reusable, environment friendly materials and solvents with operational simplicity. Materials and Methods: Carbon microsphere supported copper nanoparticles (Cu-NP/C) prepared from loaded cation exchange resin were synthesized, characterized with well versed analytical techniques such as XRD, SEM and Raman spectroscopy and the synthesized material was used as a catalyst for the environmentally benign synthesis of 3,4-dihydropyrano[c]chromenes. Results: The formation of carbon microsphere supported copper nanoparticles (Cu-NP/C) prepared from loaded cation exchange resin was confirmed by XRD, SEM and Raman spectroscopy which was employed as a heterogeneous material for the synthesis of 3,4-dihydropyrano[c]chromenes. The products formed were characterized by the analysis of spectroscopic data - NMR, IR and mass. The safe catalytic system offers several advantages including operational simplicity, environmental friendliness, high yield, and reusability of catalyst and green chemical transformation. Conclusion: Herein we report an easy and efficient protocol for the one-pot synthesis of dihydropyrano[ c]chromenes using environmentally benign MCR approach in ethanol as the green solvent. The method developed herein constitutes a valuable addition to the existing methods for the synthesis of titled compounds.

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