scholarly journals NUMERICAL CALCULATION OF PHOSPHATE TRANSPORT IN BENOA BAY, BALI

2010 ◽  
Vol 6 (1) ◽  
Author(s):  
I Gede Hendrawan ◽  
I komang Ardana
Keyword(s):  
Tidal Current ◽  
River Discharge ◽  
Phosphate Transport ◽  
Ocean Model ◽  
Tidal Level ◽  
Level Data ◽  
External Sources ◽  
Barotropic Mode ◽  
Good Agreement

A computational model to study the phosphate transport in the coastal environment was presented. It calculation involves the external sources of photosphate matter from the river discharge. The phosphjate distribution within the bay forced by tidal current, was calculated by Pricenton Ocean Model (POM) 2-dimension (barotropic mode). The tidal current obtained from simulation, shown a reasonably good agreement with in-situ tidal level data at Benoa tidal gauge station. The phosphate transport is generated by two-river discharge within the bay and three sources respected by wastewater treatment in Nusa Dua Bali, vessel parking area and waste garbage dump in suwung, respectively. The result confirm that a good agreement with the experiment data carried out within the bay. Keywords : phosphate transport, Princeton Ocean Model (POM)

scholarly journals Quantitative Relationships between the Tidal Current Limit, Tidal Level Limit and River Discharge in the Changjiang River Estuary

2021 ◽  
Vol 9 (11) ◽  
pp. 1291
Author(s):  
Chengcheng Hou ◽  
Jianrong Zhu ◽  
Ju Huang ◽  
Xinyue Cheng
Keyword(s):  
Tidal Current ◽  
River Discharge ◽  
River Estuary ◽  
Dry Season ◽  
Tidal Level ◽  
Flood Season ◽  
Current Limit ◽  
Variation Range ◽  
The Relationship ◽  
Hydrological Station

Estuaries are areas where runoff and tide interact. Tidal waves propagate upstream from river mouths and produce tidal currents and tidal level variations along rivers. Based on the hydrological frequency analysis of river discharge in the dry season and flood season at the Datong hydrological station over the past 70 years, a three-dimensional estuary numerical model was used to produce the quantitative relationships between the tidal current limit, tidal level limit and river discharge in the Changjiang River estuary. The positions of tidal current limit and tidal level limit depend not only on river discharge but also on river topography. When river discharge varies from a hydrological frequency of 95% to 5%, the relationship between the tidal current limit and river discharge is y=2×10−13x3+3 × 10−8x2− 0.0074x+359.35 in the flood season, with a variation range of 90 km, and y=−4×10−10x3−1 × 10−5x2−0.1937x − 1232.9 in the dry season, with a variation range of 200 km. The relationship between the tidal level limit and river discharge is y=6×10−8x2−0.0096x+775.94 in the flood season, with a variation range of 127 km, and y=0.3428x2−17.9x+777.55 in the dry season, with a variation range of 83 km, which is located far upstream of the Datong hydrological station.

Atomic Layer Deposition of LiF and Lithium Ion Conducting (AlF3)(LiF)x Alloys Using Trimethylaluminum, Lithium Hexamethyldisilazide and Hydrogen Fluoride

2017 ◽  
Author(s):  
Younghee Lee ◽  
Daniela M. Piper ◽  
Andrew S. Cavanagh ◽  
Matthias J. Young ◽  
Se-Hee Lee ◽  
...  
Keyword(s):  
Lithium Ion ◽  
Atomic Layer ◽  
Mass Gain ◽  
Alloy Film ◽  
Ex Situ ◽  
X Ray ◽  
Layer Deposition ◽  
Ion Conducting ◽  
Good Agreement

<div>Atomic layer deposition (ALD) of LiF and lithium ion conducting (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloys was developed using trimethylaluminum, lithium hexamethyldisilazide (LiHMDS) and hydrogen fluoride derived from HF-pyridine solution. ALD of LiF was studied using in situ quartz crystal microbalance (QCM) and in situ quadrupole mass spectrometer (QMS) at reaction temperatures between 125°C and 250°C. A mass gain per cycle of 12 ng/(cm<sup>2</sup> cycle) was obtained from QCM measurements at 150°C and decreased at higher temperatures. QMS detected FSi(CH<sub>3</sub>)<sub>3</sub> as a reaction byproduct instead of HMDS at 150°C. LiF ALD showed self-limiting behavior. Ex situ measurements using X-ray reflectivity (XRR) and spectroscopic ellipsometry (SE) showed a growth rate of 0.5-0.6 Å/cycle, in good agreement with the in situ QCM measurements.</div><div>ALD of lithium ion conducting (AlF3)(LiF)x alloys was also demonstrated using in situ QCM and in situ QMS at reaction temperatures at 150°C A mass gain per sequence of 22 ng/(cm<sup>2</sup> cycle) was obtained from QCM measurements at 150°C. Ex situ measurements using XRR and SE showed a linear growth rate of 0.9 Å/sequence, in good agreement with the in situ QCM measurements. Stoichiometry between AlF<sub>3</sub> and LiF by QCM experiment was calculated to 1:2.8. XPS showed LiF film consist of lithium and fluorine. XPS also showed (AlF<sub>3</sub>)(LiF)x alloy consists of aluminum, lithium and fluorine. Carbon, oxygen, and nitrogen impurities were both below the detection limit of XPS. Grazing incidence X-ray diffraction (GIXRD) observed that LiF and (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film have crystalline structures. Inductively coupled plasma mass spectrometry (ICP-MS) and ionic chromatography revealed atomic ratio of Li:F=1:1.1 and Al:Li:F=1:2.7: 5.4 for (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film. These atomic ratios were consistent with the calculation from QCM experiments. Finally, lithium ion conductivity (AlF<sub>3</sub>)(LiF)<sub>x</sub> alloy film was measured as σ = 7.5 × 10<sup>-6</sup> S/cm.</div>

scholarly journals Millisecond lattice gasification for high-density CO2- and O2-sieving nanopores in single-layer graphene

2021 ◽  
Vol 7 (9) ◽  
pp. eabf0116
Author(s):  
Shiqi Huang ◽  
Shaoxian Li ◽  
Luis Francisco Villalobos ◽  
Mostapha Dakhchoune ◽  
Marina Micari ◽  
...  
Keyword(s):  
Single Layer ◽  
High Density ◽  
Single Layer Graphene ◽  
Pore Density ◽  
Vacancy Defects ◽  
Carbon Gasification ◽  
Layer Graphene ◽  
Gas Molecules ◽  
Good Agreement

Etching single-layer graphene to incorporate a high pore density with sub-angstrom precision in molecular differentiation is critical to realize the promising high-flux separation of similar-sized gas molecules, e.g., CO2 from N2. However, rapid etching kinetics needed to achieve the high pore density is challenging to control for such precision. Here, we report a millisecond carbon gasification chemistry incorporating high density (>1012 cm−2) of functional oxygen clusters that then evolve in CO2-sieving vacancy defects under controlled and predictable gasification conditions. A statistical distribution of nanopore lattice isomers is observed, in good agreement with the theoretical solution to the isomer cataloging problem. The gasification technique is scalable, and a centimeter-scale membrane is demonstrated. Last, molecular cutoff could be adjusted by 0.1 Å by in situ expansion of the vacancy defects in an O2 atmosphere. Large CO2 and O2 permeances (>10,000 and 1000 GPU, respectively) are demonstrated accompanying attractive CO2/N2 and O2/N2 selectivities.

scholarly journals The Response of Turbidity Maximum to Peak River Discharge in a Macrotidal Estuary

Water ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 106
Author(s):  
Yuhan Yan ◽  
Dehai Song ◽  
Xianwen Bao ◽  
Nan Wang
Keyword(s):  
River Discharge ◽  
Recovery Time ◽  
Morphological Evolution ◽  
Spring Tide ◽  
River Estuary ◽  
Sediment Concentration ◽  
Ocean Model ◽  
Turbidity Maximum ◽  
Sediment Supply ◽  
Three Dimensional Model

The Ou River, a medium-sized river in the southeastern China, is examined to study the estuarine turbidity maximum (ETM) response to rapidly varied river discharge, i.e., peak river discharge (PRD). This study analyzes the difference in ETM and sediment transport mechanisms between low-discharge and PRD during neap and spring tides by using the Finite-Volume Community Ocean Model. The three-dimensional model is validated by in-situ measurements from 23 April to 22 May 2007. In the Ou River Estuary (ORE), ETM is generally induced by the convergence between river runoff and density-driven flow. The position of ETM for neap and spring tides is similar, but the suspended sediment concentration during spring tide is stronger than that during neap tide. The sediment source of ETM is mainly derived from the resuspension of the seabed. PRD, compared with low-discharge, can dilute the ETM, but cause more sediment to be resuspended from the seabed. The ETM is more seaward during PRD. After PRD, the larger the peak discharge, the longer the recovery time will be. Moreover, the river sediment supply helps shorten ETM recovery time. Mechanisms for this ETM during a PRD can contribute to studies of morphological evolution and pollutant flushing.

Measuring Reservoir Compaction Through Radioactive Marker Technique

2002 ◽  
Vol 124 (4) ◽  
pp. 269-275
Author(s):  
Paolo Macini ◽  
Ezio Mesini
Keyword(s):  
Land Subsidence ◽  
Reservoir Rock ◽  
Reservoir Compaction ◽  
Critical Comparison ◽  
In Situ Method ◽  
Sufficient Precision ◽  
Good Agreement

Radioactive Marker Technique (RMT), an in-situ method to measure reservoir rock compaction and to evaluate uniaxial compressibility coefficients Cm, is examined here. Recent field applications seems to confirm that RMT-derived Cm’s match with sufficient precision with those calculated from land subsidence observed over the field by means of geodetic surveys, but are not always in good agreement with those derived from lab measurements. In particular, here is reported an application of RMT in the Italian Adriatic offshore, which highlights the discrepancies of Cm’s measurements from lab and RMT. At present, these discrepancies aren’t thoroughly understood, so, from an applicative standpoint, it is still necessary to perform a critical comparison and integration between both set of data.

scholarly journals Assessment of MERRA-2 and ERA5 to Model the Snow Water Equivalent in the High Atlas (1981–2019)

Water ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 890
Author(s):  
Mohamed Wassim Baba ◽  
Abdelghani Boudhar ◽  
Simon Gascoin ◽  
Lahoucine Hanich ◽  
Ahmed Marchane ◽  
...  
Keyword(s):  
River Discharge ◽  
Snow Water Equivalent ◽  
High Elevation ◽  
Water Runoff ◽  
High Atlas ◽  
Seasonal Snow ◽  
Snow Covered Area ◽  
Covered Area ◽  
Snow Water

Melt water runoff from seasonal snow in the High Atlas range is an essential water resource in Morocco. However, there are only few meteorological stations in the high elevation areas and therefore it is challenging to estimate the distribution of snow water equivalent (SWE) based only on in situ measurements. In this work we assessed the performance of ERA5 and MERRA-2 climate reanalysis to compute the spatial distribution of SWE in the High Atlas. We forced a distributed snowpack evolution model (SnowModel) with downscaled ERA5 and MERRA-2 data at 200 m spatial resolution. The model was run over the period 1981 to 2019 (37 water years). Model outputs were assessed using observations of river discharge, snow height and MODIS snow-covered area. The results show a good performance for both MERRA-2 and ERA5 in terms of reproducing the snowpack state for the majority of water years, with a lower bias using ERA5 forcing.

Use of a three-dimensional model to predict heavy metal (copper) fluxes in the Oujiang estuary

2014 ◽  
Vol 69 (6) ◽  
pp. 1334-1343 ◽  
Author(s):  
Shasha Lu ◽  
Ruijie Li ◽  
Xiaoming Xia ◽  
Jun Zheng
Keyword(s):  
River Discharge ◽  
Water Surface ◽  
Three Dimensional ◽  
Measured Data ◽  
Dimensional Model ◽  
Three Dimensional Model ◽  
Pollutant Concentrations ◽  
Suspended Sediment Concentrations ◽  
Adsorption Desorption ◽  
Good Agreement

Measuring pollutant concentrations in major tributaries is the standard method for establishing pollutant fluxes to the sea. However, this method is costly and difficult, and may be subject to a great deal of uncertainty due to the presence of unknown sources. This uncertainty presents challenges to managers and scientists in reducing contaminant discharges to water bodies. As one less costly method, a three-dimensional model was developed and used to predict pollutant fluxes to the sea. The sorptive contaminant model was incorporated into hydrodynamic and sediment models. Adsorption–desorption of copper by sediments in the Oujiang estuary were described using Henry's law. The model was validated using measured data for water surface elevations, flow velocity/direction, suspended sediment concentrations, and the proportion of copper sorbed to sediment. The validated model was then applied to predict fluxes of copper. Combined with the measured data, the copper concentration in the Oujiang River discharge was calculated as 13.0 μg/L and copper fluxes were calculated as 52 t in 2010. This copper flux prediction was verified using measured dissolved copper concentrations. Comparisons between the modeled and measured results showed good agreement at most stations, demonstrating that copper flux prediction in the Oujiang estuary was reasonably accurate.

scholarly journals In-situ measurement of reactive hydrocarbons at Hohenpeissenberg with comprehensive gas chromatography (GCxGC-FID): use in estimating HO and NO<sub>3</sub>

2006 ◽  
Vol 6 (4) ◽  
pp. 8155-8188
Author(s):  
S. Bartenbach ◽  
J. Williams ◽  
C. Plass-Dülmer ◽  
H. Berresheim ◽  
J. Lelieveld
Keyword(s):  
Mean Value ◽  
Time Data ◽  
Night Time ◽  
Radical Species ◽  
Diurnal Cycles ◽  
Meteorological Observatory ◽  
Variate Analysis ◽  
The Relationship ◽  
Good Agreement

Abstract. During a field campaign at the Meteorological Observatory Hohenpeissenberg (MOHp) in July 2004, VOCs were measured using GCxGC-FID. Comparison to routinely made GC-MS measurements showed good agreement for a variety of anthropogenic and biogenic ambient VOCs ranging in concentration from below the detection limit (0.1 pmol mol−1) to 180 pmol mol−1. Pronounced diurnal cycles were found for both the biogenic and anthropogenic compounds, driven for the most part by the daily rise and fall of the boundary layer over the station. For the reactive compounds (lifetimes <2 days), a significant, non-zero dependency of the variability on lifetime was found, indicating that chemistry (as opposed to transport alone) was playing a role in determining the ambient VOC concentrations. The relationship was exploited using a single-variate analysis to derive a daytime mean value of HO (5.3±1.4×106 molecules cm−3), which compares well to that measured at the site, 3.2±2.3×106 molecules cm−3. The analysis was extended to the night time data to estimate concentrations for NO3 (1.47±0.2×108 molecules cm−3), which is not measured at the site. The feasibility of this approach for environments dominated by emissions of short-lived VOCs to estimate ambient levels of radical species is discussed.

scholarly journals Flight Demonstration of a 2-Micron, Double Plused CO2 IPDA Lidar Instrument

2020 ◽  
Vol 237 ◽  
pp. 03013
Author(s):  
Jirong Yu ◽  
Mulugeta Petros ◽  
Upendra Singh ◽  
Tamer Refaat ◽  
Karl Reithmaier ◽  
...  
Keyword(s):  
Column Density ◽  
High Energy ◽  
Density Difference ◽  
Lidar Measurement ◽  
Differential Absorption ◽  
Air Samples ◽  
Lidar Measurements ◽  
Langley Research Center ◽  
Good Agreement

NASA Langley Research Center (LaRC) developed a double pulsed, high energy 2-micron Integrated Path Differential Absorption (IPDA) lidar instrument to measure atmospheric CO2 column density. The 2-μm double pulsed IPDA lidar was flown ten times in March and April of 2014. It was determined that the IPDA lidar measurement is in good agreement with an in-situ CO2 measurement by a collocated NOAA flight. The average column CO2 density difference between the IPDA lidar measurements and the NOAA air samples is 1.48ppm in the flight altitudes of 3 to 6.1 km.

scholarly journals Long-Term Patterns and Trends of Shortwave Global Irradiance over the Euro-Mediterranean Region

Atmosphere ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1431
Author(s):  
Elissavet Galanaki ◽  
George Emmanouil ◽  
Konstantinos Lagouvardos ◽  
Vassiliki Kotroni
Keyword(s):  
Mediterranean Region ◽  
Spatiotemporal Variability ◽  
Reanalysis Dataset ◽  
Global Irradiance ◽  
Seasonal Basis ◽  
Region 10 ◽  
Annual Scale ◽  
Good Agreement

The spatiotemporal patterns and trends of shortwave global irradiance (SWGI) are a crucial factor affecting not only the climate but also sectors of the economy. In this work, the ERA5-Land reanalysis dataset is employed and evaluated against in situ measurements from a dense network of surface stations operated by the National Observatory of Athens over Greece, revealing a good agreement between the two datasets. Then, the spatiotemporal variability of SWGI is investigated over the Euro-Mediterranean region (10° W–42° E and 30° N–52° N) for a 40-year period (1981–2020). SWGI exhibits a smooth latitudinal variability from north to south of −5.4 W/m2/degree on an annual scale, while it varies significantly on a seasonal basis and is almost four times lower in the winter than in the summer. The SWGI trend during the analyzed period was found to be positive and statistically significant at the 95% confidence level. Spring and summer are the periods where positive and the strongest rates of SWGI trends are evident, while in the winter and autumn, negative or neutral trends were found. The increasing SWGI trend shows a slowdown during the beginning of the 2000s in all seasons, except autumn. The SWGI trend decreases by about −0.06 W/m2/decade every 100 m of elevation increase.

Sign in / Sign up

Export Citation Format

Share Document