scholarly journals Thermally induced intramolecular hydrogen atom transfer and the study of the flash vacuum pyrolysis of various cyclic and non-cyclic organic molecules related to, and including, o-allyltoluene

2003 ◽  
Author(s):  
Arthur Bruno Ferruzzi
Keyword(s):  
Hydrogen Atom ◽  
Organic Molecules ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Thermally Induced ◽  
Flash Vacuum Pyrolysis ◽  
Vacuum Pyrolysis ◽  
Intramolecular Hydrogen

Flash Vacuum Pyrolysis of Some N-Benzylbenzotriazoles and N-Benzylbenzisoxazolones

1998 ◽  
Vol 51 (10) ◽  
pp. 925 ◽  
Author(s):  
Jabbar Khalafy ◽  
Rolf H Prager
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Addition Reactions ◽  
Atom Transfer ◽  
Pyrolysis Products ◽  
Flash Vacuum Pyrolysis ◽  
Vacuum Pyrolysis ◽  
Intramolecular Hydrogen

The flash vacuum pyrolysis products of 2-(benzotriazol-1-ylmethyl)benzonitrile, methyl 2-(benzotriazol-1-ylmethyl)benzoate and the corresponding benzisoxazolones have been characterized. The benzotriazoles lose nitrogen to give diradicals which undergo intramolecular hydrogen-atom transfer or cyclization, while the benzisoxazolones rearrange initially to the corresponding benzaldehyde N-(2-carboxyphenyl)imines which undergo subsequent intramolecular addition reactions.

scholarly journals Alkyl Ethers as Traceless Hydride Donors in Brønsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer

2018 ◽  
Vol 57 (21) ◽  
pp. 6181-6185 ◽  
Author(s):  
Dhika Aditya Gandamana ◽  
Bin Wang ◽  
Ciputra Tejo ◽  
Benoit Bolte ◽  
Fabien Gagosz ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Alkyl Ethers ◽  
Acid Catalyzed ◽  
Intramolecular Hydrogen
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