scholarly journals Fast Fabrication of Conductive Copper Structure on Glass Material Using Laser-Induced Chemical Liquid Phase Deposition

2021 ◽  
Vol 11 (18) ◽  
pp. 8695
Author(s):  
Han-Guel Kim ◽  
Min-Soo Park
Keyword(s):  
Liquid Phase ◽  
Laser Energy ◽  
Chemical Reduction ◽  
High Energy ◽  
Reduction Reaction ◽  
Liquid Phase Deposition ◽  
Stable Chemical ◽  
High Laser ◽  
Scanning Path ◽  
Good Productivity

Glass is a very stable material at room temperature and has good resistance to gas, bacteria, and organisms. Due to the development of the electronic industry, the industrial demand for creating a conductive pattern on glass is increasing rapidly. To create conductive circuit patterns on the glass surface, non-contact methods based on high energy sources or chemical methods are generally used. However, these methods have disadvantages such as low conductivity, high cost, and size limitations. Processes such as LCLD (laser-induced chemical liquid phase deposition) have been widely studied to solve this problem. However, it has a fatal disadvantage of being slow. Therefore, in this study, various process changes were attempted to improve productivity and conductivity. In particular, sufficient thermal energy was supplied with high laser power for a stable chemical reduction, and the scanning path was changed in various shapes to minimize the ablation that occurs at this time. Through this, it was possible to disperse the overlapped laser energy of high power to widen the activation area of the reduction reaction. With this proposed LCLD process, it is possible to achieve good productivity and fabricate conductive circuit patterns faster than in previous studies.

scholarly journals Efficient Catalytic Conversion of Polysulfides by Biomimetic Design of “Branch-Leaf” Electrode for High-Energy Sodium–Sulfur Batteries

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Wenyan Du ◽  
Kangqi Shen ◽  
Yuruo Qi ◽  
Wei Gao ◽  
Mengli Tao ◽  
...  
Keyword(s):  
Active Sites ◽  
High Performance ◽  
Electrochemical Reaction ◽  
Molecular Layer ◽  
Specific Capacity ◽  
High Energy ◽  
Reduction Reaction ◽  
Biomimetic Design ◽  
Co Nanoparticles ◽  
Sodium Sulfur

AbstractRechargeable room temperature sodium–sulfur (RT Na–S) batteries are seriously limited by low sulfur utilization and sluggish electrochemical reaction activity of polysulfide intermediates. Herein, a 3D “branch-leaf” biomimetic design proposed for high performance Na–S batteries, where the leaves constructed from Co nanoparticles on carbon nanofibers (CNF) are fully to expose the active sites of Co. The CNF network acts as conductive “branches” to ensure adequate electron and electrolyte supply for the Co leaves. As an effective electrocatalytic battery system, the 3D “branch-leaf” conductive network with abundant active sites and voids can effectively trap polysulfides and provide plentiful electron/ions pathways for electrochemical reaction. DFT calculation reveals that the Co nanoparticles can induce the formation of a unique Co–S–Na molecular layer on the Co surface, which can enable a fast reduction reaction of the polysulfides. Therefore, the prepared “branch-leaf” CNF-L@Co/S electrode exhibits a high initial specific capacity of 1201 mAh g−1 at 0.1 C and superior rate performance.

Surface overgrowth on gold nanoparticles modulating high-energy facets for efficient electrochemical CO2 reduction

Nanoscale ◽  
2021 ◽  
Author(s):  
Woong Choi ◽  
Joon Woo Park ◽  
Woonghyeon Park ◽  
Yousung Jung ◽  
Hyunjoon Song
Keyword(s):  
Gold Nanoparticles ◽  
Renewable Energy ◽  
Renewable Energy Sources ◽  
Co2 Reduction ◽  
High Energy ◽  
Reduction Reaction ◽  
Chemical Energy ◽  
Energy Sources ◽  
Electrochemical Co2 Reduction

Electrochemical CO2 reduction reaction (eCO2RR) has been considered one of the potential technologies to store electricity from renewable energy sources into chemical energy. For this aim, designing catalysts with high...

scholarly journals Radiation effects on shock propagation in Al target relevant to equation of state measurements

2007 ◽  
Vol 25 (1) ◽  
pp. 23-30 ◽  
Author(s):  
T. DESAI ◽  
R. DEZULIAN ◽  
D. BATANI
Keyword(s):  
Equation Of State ◽  
Reference Material ◽  
Radiation Effects ◽  
Laser Energy ◽  
Strong Shock ◽  
Shock Propagation ◽  
Laser Irradiance ◽  
X Rays ◽  
High Laser ◽  
High Intensity Laser

We present one-dimensional simulations performed using the multi group radiation hydro code MULTI with the goal of analyzing the target preheating effect under conditions similar to those of recent experiments aimed at studying the Equation of State (EOS) of various materials. In such experiments, aluminum is often used as reference material; therefore its behavior under strong shock compression and high-intensity laser irradiation (1013–1014 W/cm2) should be studied in detail. Our results reveal that at high laser irradiance, the laser energy available to induce shock pressure is reduced due to high X-rays generation. Simultaneously X-rays preheat the bulk of the reference material causing significant heating prior to shock propagation. Such effects induce deviations in shock propagation with respect to cold aluminum.

Photoelectrochemical Properties of Anatase TiO2 Films Prepared by Improved Liquid Phase Deposition

2015 ◽  
Vol 1120-1121 ◽  
pp. 419-423
Author(s):  
Cai Xia Lei ◽  
X.L. Jiang ◽  
Y. Liu ◽  
X. Liu ◽  
Y.T. Ma ◽  
...  
Keyword(s):  
Electron Microscope ◽  
Liquid Phase ◽  
Scanning Electron Microscope ◽  
Reaction Temperature ◽  
White Light ◽  
Photoelectrochemical Properties ◽  
Liquid Phase Deposition ◽  
X Ray ◽  
Good Crystallinity ◽  
Scanning Electron

In this paper, the hydrothermal-assisted liquid phase deposition (HT-LPD) method has been developed to prepare TiO2 films. The crystalline structures and morphologies of as-prepared TiO2 films were analyzed using an X-ray diffractometer (XRD) and scanning electron microscope (SEM). It was found that the HT-LPD TiO2 film showed good crystallinity with preferrred orientation along c-axis. Moreover, the as-prepared TiO2 films consisted of two layers, with the tiny nanoparticles as the underlying layer and the flower-like clusters as the upper layer. The photoelectrochemical measurements revealed that, when illuminated by the white light, the HT-LPD TiO2 films exhibited a more negative photopotential value and an increased photocurrent value with elevated reaction temperature, excepting for the sample prerared at 150 °C. In summary, the TiO2 films prepared by the improved LPD method could be served as the promising photoanode for the photoelectrochemical applications.

SrTiO3 Functional Ceramics Thin Film Prepared by Self-Assembled Monolayers with the Liquid Phase Deposition Method on Silicon Substrates

2010 ◽  
Vol 105-106 ◽  
pp. 270-273
Author(s):  
Hui Jun Ren ◽  
Guo Qiang Tan ◽  
Hong Yan Miao ◽  
Ya Yu Song ◽  
Ao Xia
Keyword(s):  
Thin Film ◽  
Contact Angle ◽  
Liquid Phase ◽  
Deposition Temperature ◽  
Precursor Solution ◽  
Self Assembled Monolayers ◽  
Silicon Substrates ◽  
Liquid Phase Deposition ◽  
Assembled Monolayers ◽  
Surface Contact Angle

In this article, (NH4)2TiF6, SrNO3 and H3BO3 were used as raw materials to prepare the precursor solution with the ratio of AHFT/SN/BA=1:1:3. The thin films of SrTiO3 were fabricated on the functional silicon substrates (100) by self-assembled monolayers (SAMs) with the liquid phase deposition (LPD). This article also studied the effects of wet state and the deposition temperature of the precursor solution before and after the functionalization of silicon substrate on the thin film growth. The results indicated that after the immersion in OTS for 30min, the surface contact angle of the silicon substrate changed from 24.64° to 100.91°. The substrate appeared hydrophobic property and it was irradiated by UV light for 30min. Then the surface contact angle of the substrate decreased to 5.00°. The substrate appeared hydrophilicity. The concentration of the precursor solution was 0.025 mol/L, the deposition temperature was 40°C and the deposition time was 9h, which were all helpful to SrTiO3 crystallization. XRD and SEM were used to characterize the physical phase of thin film and surface morphology at 600 °C with annealing and heat retaining for 2h. The results indicated that the thin film prepared by the mono-crystal Si substrate was SrTiO3 thin film with better crystalline. On the crystal surfaces of (110), (100), (200) and (211), there appeared the obvious diffraction peaks. The SrTiO3 grains on the surface had the clear outline and were regular and long columnar crystals.

Liquid phase deposition of iron and cobalt doped TiO2 epitaxial thin films

2008 ◽  
Vol 205 (10) ◽  
pp. 2405-2408 ◽  
Author(s):  
K. Y. S. Chan ◽  
G. K. L. Goh ◽  
M. Y. Han
Keyword(s):  
Thin Films ◽  
Liquid Phase ◽  
Epitaxial Thin Films ◽  
Liquid Phase Deposition ◽  
Doped Tio2
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