scholarly journals Prediction of Aqueous Solution Surface Tension of Some Surfactant Mixtures and Composition of Their Monolayers at the Solution–Air Interface

2021 ◽  
Vol 5 (4) ◽  
pp. 53
Author(s):  
Bronisław Jańczuk ◽  
Anna Zdziennicka ◽  
Katarzyna Szymczyk ◽  
Maria Luisa González-Martín
Keyword(s):  
Aqueous Solution ◽  
Surface Tension ◽  
Aqueous Solutions ◽  
Ternary Mixtures ◽  
Mixture Component ◽  
Surfactant Mixtures ◽  
Surface Tension Reduction ◽  
Air Interface ◽  
Binary And Ternary Mixtures ◽  
Solution Surface

Measurements of the surface tension of the aqueous solution of SDDS mixture with fluorocarbon surfactants (FC) were carried out and considered in light of the surface tension of aqueous solutions of individual surfactants. Similar analyses were made for many other aqueous solutions of binary and ternary mixtures, taking into account the literature data of the surface tension of aqueous solutions of TX100, TX114, TX165, SDDS, SDS, CTAB, CPyB and FC. The possibility of predicting the surface tension of the aqueous solution of many surfactant mixtures from that of the mixture components using both the Szyszkowski, Fainerman and Miller and Joos concepts was analyzed. The surface tension of the aqueous solutions of surfactant mixtures was also considered based on the particular mixture component contribution to the water surface tension reduction. As a result, the composition of the mixed surface layer at the solution–air interface was discussed and compared to that which was determined using the Hua and Rosen concept. As follows from considerations, the surface tension of the aqueous solution of binary and ternary surfactant mixtures can be described and/or predicted.

scholarly journals Adsorption Properties of Hydrocarbon and Fluorocarbon Surfactants Ternary Mixture at the Water-Air Interface

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4313
Author(s):  
Bronisław Jańczuk ◽  
Katarzyna Szymczyk ◽  
Anna Zdziennicka
Keyword(s):  
Surface Tension ◽  
Water Surface ◽  
Standard Free Energy ◽  
Ternary Mixtures ◽  
Free Energy Of Adsorption ◽  
Interface Tension ◽  
Air Interface ◽  
Surface Excess Concentration ◽  
Tail Water ◽  
Triton X

Measurements were made of the surface tension of the aqueous solutions of p-(1,1,3,3-tetramethylbutyl) phenoxypoly(ethylene glycols) having 10 oxyethylene groups in the molecule (Triton X-100, TX100) and cetyltrimethylammonium bromide (CTAB) with Zonyl FSN-100 (FC6EO14, FC1) as well as with Zonyl FSO-100 (FC5EO10, FC2) ternary mixtures. The obtained results were compared to those provided by the Fainerman and Miller equation and to the values of the solution surface tension calculated, based on the contribution of a particular surfactant in the mixture to the reduction of water surface tension. The changes of the aqueous solution ternary surfactants mixture surface tension at the constant concentration of TX100 and CTAB mixture at which the water surface tension was reduced to 60 and 50 mN/m as a function of fluorocarbon surfactant concentration, were considered with regard to the composition of the mixed monolayer at the water-air interface. Next, this composition was applied for the calculation of the concentration of the particular surfactants in the monolayer using the Frumkin equation. On the other hand, the Gibbs surface excess concentration was determined only for the fluorocarbon surfactants. The tendency of the particular surfactants to adsorb at the water-air interface was discussed, based on the Gibbs standard free energy of adsorption which was determined using different methods. This energy was also deduced, based on the surfactant tail surface tension and tail-water interface tension.

Surface Tension of Decane Binary and Ternary Mixtures with Eicosane, Docosane, and Tetracosane

2005 ◽  
Vol 50 (3) ◽  
pp. 1043-1046 ◽  
Author(s):  
António J. Queimada ◽  
Ana I. Caço ◽  
Isabel M. Marrucho ◽  
João A. P. Coutinho
Keyword(s):  
Surface Tension ◽  
Ternary Mixtures ◽  
Binary And Ternary Mixtures

scholarly journals Effectiveness of lactate-containing processing aids application in vegetable treatment

2019 ◽  
Vol 48 (2) ◽  
pp. 28-35
Author(s):  
Вера Евелева ◽  
Vera Eveleva ◽  
Татьяна Черпалова ◽  
Tatyana Cherpalova ◽  
Елена Шиповская ◽  
...  
Keyword(s):  
Surface Tension ◽  
Aqueous Solutions ◽  
Storage Stability ◽  
Raw Materials ◽  
Physical Parameters ◽  
Air Interface ◽  
Deep Layers ◽  
New Processing ◽  
Vegetable Raw Materials ◽  
Processing Aids

Common characteristic of salad products is presence of cut raw vegetables in its composition. Cold cutting helps surface microorganisms penetrate into deep layers of the product. Hygienic cleanliness of raw ingredients is the major factor which contributes to storage stability of salad products. One of the most effective methods that helps enhance salad storage stability is initial treatment of vegetable raw materials with antimicrobial solutions. The author presents information on using solutions of hydrogen peroxide and peroxyacetic acid, sodium hypochlorite and compositions containing peroxide compounds and acetic, benzoic, sorbic, ascorbic, citric, lactic and other acids as well as their salts and containing guanidylic compounds. The article reveals that antimicrobial action of lactate-containing processing aids improves sufficiently if polymer cation-active compounds are introduced into their composition. The goal of the research is to study application effectiveness of new processing aids for treatment of raw peeled cut vegetables to reduce bacterial content and enhance storage stability before thermal treatment (boiling). The author tested the aids based on lactate-containing components. Physicochemical and physical parameters of the aids and their aqueous solutions are the following: active acidity (pH), titratab6le acidity, water and volatiles mass fraction, dynamic viscosity, surface tension. The article presents the data which characterize change in surface tension of aqueous solutions of the aids at the water-air interface depending on their concentration. It also gives quality indicators and microbial parameters of raw peeled cut vegetables after their processing with solutions of the aids. It was found out that treatment of raw peeled cut vegetables with processing aids based on lactate containing components prolongs their shelf life from 3 hours according to the applicable technology up to 48 hours.

scholarly journals Anomalous Behavior of Fluorocarbon-Hydrocarbon Hybrid Surfactant in its Aqueous Solution. Surface Tension and Micropolarity.

1996 ◽  
Vol 45 (5) ◽  
pp. 479-482 ◽  
Author(s):  
Atsushi ITO ◽  
Keiji KAMOGAWA ◽  
Hideki SAKAI ◽  
Yukishige KONDO ◽  
Norio YOSHINO ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Surface Tension ◽  
Anomalous Behavior ◽  
Solution Surface ◽  
Hybrid Surfactant
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