scholarly journals Towards a Large-Area Freestanding Single-Crystal Ferroelectric BaTiO3 Membrane

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 733
Author(s):  
Qixiang Wang ◽  
Hong Fang ◽  
Di Wang ◽  
Jie Wang ◽  
Nana Zhang ◽  
...  

The fabrication and transfer of freestanding single-crystal ferroelectric membranes deserve intensive investigations as to their potential applications in flexible wearable devices, such as flexible data storage devices and varied sensors in E-skin configurations. In this report, we have shown a comprehensive study approach to the acquisition of a large-area freestanding single-crystal ferroelectric BaTiO3 by the Sr3Al2O6 scarification layer method. By controlling the thickness of the BaTiO3 and Sr3Al2O6, the exposed area of the Sr3Al2O6 interlayer, and the utilization of an additional electrode La2/3Sr1/3MnO3 layer, the crack density on the freestanding BaTiO3 can be dramatically decreased from 24.53% to almost none; then, a more than 700 × 530 μm2 area high-quality freestanding BaTiO3 membrane can be achieved. Our results offer a clear and repeatable technology routine for the acquisition of a flexible large-area ferroelectric membrane, which should be instructive to other transition metal oxides as well. Our study can confidently boost flexible device fabrication based on single-crystal transition metal oxides.

2018 ◽  
Vol 6 (1) ◽  
pp. 1801160 ◽  
Author(s):  
Tong Yang ◽  
Ting Ting Song ◽  
Martin Callsen ◽  
Jun Zhou ◽  
Jian Wei Chai ◽  
...  

1989 ◽  
Vol 156 ◽  
Author(s):  
Aaron Wold ◽  
Kirby Dwight

ABSTRACTThe structure-property relationships of several conducting transition metal oxides, as well as their preparative methods, are presented in this paper. The importance of preparing homogeneous phases with precisely known stoichiometry is emphasized. A comparison is also made of the various techniques used to prepare both polycrystalline and single crystal samples. For transition metal oxides, the metallic properties are discussed either in terms of metal-metal distances which are short enough to result in metallic behavior, or in terms of the formation of a П* conduction band resulting from covalent metal-oxygen interactions. Metallic behavior is observed when the conduction bands are populated with either electrons or holes. The concentration of these carriers can be affected by either cation or anion substitutions. The discussion in this presentation will be limited to the elements Re, Ti, V, Cr, Mo, and Cu.


1995 ◽  
Vol 397 ◽  
Author(s):  
R. Martin Villarica ◽  
Fazio Nash ◽  
J. Chaiken ◽  
Joe Osman ◽  
Rebecca Bussjager

ABSTRACTWe describe a novel laser chemical process having potential for optical data storage and processing applications. Reversible oxygen exchange involving WO3, using readily available laser sources offers improved durability and versatility over existing erasable optical data storage media. Being interconvertable using heat and blue-green laser sources, the well known yellow WO3 and blue W2O5 can function as erased and written states.


2014 ◽  
Vol 2 (12) ◽  
pp. 2266-2271 ◽  
Author(s):  
Liangzhuan Wu ◽  
Yuan Yu ◽  
Xianying Han ◽  
Yuan Zhang ◽  
Yang Zhang ◽  
...  

We report an electroless-plating-like solution deposition approach for large-area flexible thin films of crystalline transition metal oxides.


2012 ◽  
Vol 42 (11) ◽  
pp. 1185-1195 ◽  
Author(s):  
YiPing YAO ◽  
YueWei YIN ◽  
XiaoGuang LI

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
F. Freund ◽  
S. C. Williams ◽  
R. D. Johnson ◽  
R. Coldea ◽  
P. Gegenwart ◽  
...  

2008 ◽  
Vol 140 ◽  
pp. 37-46 ◽  
Author(s):  
Wu Zong Zhou

Using mesoporous silicas as hard templates and facilitating crystal growth of transition metal oxides inside the pores, some mesoporous crystals can be produced after removing the templates. This paper gives a brief review of the research of mesoporous crystals of transition metal oxides in the last five years, including the technical development and potential applications of the new form of oxides.


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