scholarly journals Optimization of a MOF Blended with Modified Polyimide Membrane for High-Performance Gas Separation

Membranes ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 34
Author(s):  
Yushu Zhang ◽  
Hongge Jia ◽  
Qingji Wang ◽  
Wenqiang Ma ◽  
Guoxing Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Gas Separation ◽  
High Performance ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Polyimide Membrane ◽  
Amine Functionalized ◽  
Ideal Selectivity ◽  
Metal Organic ◽  
Matrix Membranes

The preparation, characterization and gas separation properties of mixed matrix membranes (MMMs) were obtained from polyimide capped with ionic liquid and blended with metal-organic frameworks (MOFs). The synthesized MOF was amine functionalized to produce UiO-66-NH2, and its amino group has a higher affinity for CO2. Mixed matrix membranes exhibited good membrane forming ability, heat resistance and mechanical properties. The polyimide membrane exclusively capped by ionic liquid exhibited good permselectivity of 74.1 for CO2/CH4, which was 6.2 times that of the pure polyimide membrane. It is worth noting that MMM blended with UiO-66-NH2 demonstrated the highest ideal selectivity for CO2/CH4 (95.1) with a CO2 permeability of 7.61 Barrer, which is close to the 2008 Robeson upper bound. The addition of UiO-66-NH2 and ionic liquid enhanced the permselectivity of MMMs, which may be one of the promising technologies for high performance CO2/CH4 gas separation.

scholarly journals Towards High Performance Metal-Organic Framework-Microporous Polymer Mixed Matrix Membranes: Addressing Compatibility and Limiting Aging by Polymer Doping

2018 ◽  
Vol 24 (49) ◽  
pp. 12796-12800 ◽  
Author(s):  
Anahid Sabetghadam ◽  
Xinlei Liu ◽  
Angelica F. Orsi ◽  
Magdalena M. Lozinska ◽  
Timothy Johnson ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Microporous Polymer ◽  
Metal Organic ◽  
Organic Framework ◽  
Matrix Membranes

Polymer functionalization to enhance interface quality of mixed matrix membranes for high CO2/CH4 gas separation

2015 ◽  
Vol 3 (29) ◽  
pp. 15202-15213 ◽  
Author(s):  
Nguyen Tien-Binh ◽  
Hoang Vinh-Thang ◽  
Xiao Yuan Chen ◽  
Denis Rodrigue ◽  
Serge Kaliaguine
Keyword(s):  
Gas Separation ◽  
Metal Organic Frameworks ◽  
Molar Ratio ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Interface Quality ◽  
High Co2 ◽  
Metal Organic ◽  
Matrix Membranes

Hydroxyl-functionalized homo- and co-polyimides 6FDA–(DAM)x–(HAB)y (with x : y molar ratio of 1 : 0; 2 : 1; 1 : 1; 1 : 2) and two metal–organic frameworks (MOFs), MIL-53(Al) and NH2-MIL-53(Al) were synthesized for preparation of mixed matrix membranes (MMMs).

Metal-organic polyhedra 18 mixed-matrix membranes for gas separation

2014 ◽  
Vol 463 ◽  
pp. 82-93 ◽  
Author(s):  
Edson V. Perez ◽  
Kenneth J. Balkus ◽  
John P. Ferraris ◽  
Inga H. Musselman
Keyword(s):  
Gas Separation ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Matrix Membranes

Synthesis and gas permselectivity of CuBTC–GO–PVDF mixed matrix membranes

2018 ◽  
Vol 42 (14) ◽  
pp. 12013-12023 ◽  
Author(s):  
Elahe Ahmadi Feijani ◽  
Hossein Mahdavi ◽  
Ahmad Tavassoli
Keyword(s):  
Graphene Oxide ◽  
Gas Separation ◽  
Metal Organic Framework ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Gas Separation Performance ◽  
Organic Framework ◽  
Matrix Membranes

A CuBTC (copper(ii) benzene-1,3,5-tricarboxylate) metal organic framework (MOF) and graphene oxide (GO) nanosheets were introduced into a semi-crystalline PVDF to produce mixed matrix membranes (MMMs) to promote gas separation performance.

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