scholarly journals Recovery of Copper(II) and Silver(I) from Nitrate Leaching Solution of Industrial Dust via Solvent Extraction with LIX63

Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1300
Author(s):  
Pan-Pan Sun ◽  
Tae-Young Kim ◽  
Hyeon Seo ◽  
Sung-Yong Cho
Keyword(s):  
Nitric Acid ◽  
Solvent Extraction ◽  
Metal Ions ◽  
Nitrate Leaching ◽  
Extraction Efficiency ◽  
Feed Solution ◽  
Industrial Dust ◽  
Complete Extraction ◽  
Leaching Solution ◽  
Counter Current

A nitrate leachate containing Cu(II), Ag(I), Ni(II), Mg(II), and Al(III) was obtained during the leaching of industrial dust, which arises during the pyrometallurgy of spent camera modules. To separate and recover Cu(II) and Ag(I) from the leaching solution, solvent extraction experiments using 5,8-diethyl-7-hydroxydodecan-6-oxime (LIX63) were conducted. LIX63 was found to selectively extract Cu(II) and Ag(I) over other metal ions (Ni(II), Mg(II), and Al(III)) at low nitric acid concentrations. The extraction efficiency of Cu(II) was more affected than that of Ag(I) by the acidity of the feed solution and the LIX63 concentration in the organic phase. Cu(II) and Ag(I) were simultaneously extracted using 2 mol/L LIX63. Cu(II) was separated from the loaded LIX63 via stripping with 4 mol/L HNO3, whereas Ag(I) was recovered via stripping with 0.1 mol/L thiourea after the removal of Cu(II). McCabe–Thiele diagrams for the extraction and stripping of Cu(II) and Ag(I) were constructed. The complete extraction of Cu(II) and Ag(I) was confirmed via counter-current extraction. Moreover, stripping simulation tests confirmed that higher than 99.99% of Cu(II) and 99.2% of Ag(I) were stripped. The purities of Cu(II) and Ag(I) in the recovered solution were 95.2% and 99.993%, respectively. A process flow chart for the recovery of Cu(II) and Ag(I) from the nitrate leachate of the target industrial dust was also provided.

Extraction of tetra- and hexavalent actinide ions from nitric acid solutions using some diglycolamide functionalized calix[4]arenes

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Rajesh B. Gujar ◽  
Parveen K. Verma ◽  
Prasanta K. Mohapatra ◽  
Mudassir Iqbal ◽  
Jurriaan Huskens ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Solvent Extraction ◽  
Extraction Efficiency ◽  
Minor Actinide ◽  
Acid Solutions ◽  
Extraction Mechanism ◽  
Nitrate Ion ◽  
Nitric Acid Solutions ◽  
Actinide Ions ◽  
Acid Extractant

Abstract Neptunium is one of the most important minor actinide elements with some of its isotopes having very long half-lives, therefore necessitating its separation from acidic radioactive wastes. Solvent extraction of Np4+ and NpO2 2+ was studied using three multiple diglycolamide (DGA) extractants with n-propyl, n-octyl and 3-pentyl substituents termed as L I , L II and L III , respectively, in a mixed diluent of 5% isodecanol and 95% n-dodecane. For comparison purpose, the extraction of Pu4+ and UO2 2+ was carried out under identical conditions. The extraction efficiency of the ligands for the tetravalent ions followed the trend: L II  > L I  > L III , which changed to L III  > L II  > L I for the hexavalent ions. While the extraction of the tetravalent ions was reasonably good (ca. 90–98%) with an extremely low (5.0 × 10−5 M) ligand concentration, poor extraction (ca. 5–16%) of the hexavalent ions was seen even with a 20 times higher concentration of the ligand. In general, Pu4+ was better extracted than Np4+, while NpO2 2+ was marginally better extracted then UO2 2+. A ‘solvation’ type extraction mechanism was proposed based on the extraction profiles obtained as a function of the concentrations of the feed nitric acid, extractant as well as nitrate ion. The extracted species were found out to be M(NO3)4·mL and MO2(NO3)2·nL (M = Np or Pu, 1 < m < 2, n ≃ 1).

scholarly journals Separation of Ag(I) by Ion Exchange and Cementation from a Raffinate Containing Ag(I), Ni(II) and Zn(II) and Traces of Cu(II) and Sn(II)

Processes ◽  
2018 ◽  
Vol 6 (8) ◽  
pp. 112 ◽  
Author(s):  
Wei Xing ◽  
Man Lee ◽  
Seung Choi
Keyword(s):  
Ascorbic Acid ◽  
Nitric Acid ◽  
Solvent Extraction ◽  
Ion Exchange ◽  
Anode Slime ◽  
Silver Particles ◽  
Copper Sheet ◽  
Agno3 Solution ◽  
Micron Size ◽  
Leaching Solution

Ion exchange and cementation experiments were done to separate silver(I) from a raffinate containing silver(I), nickel(II), and zinc(II) and small amounts of copper(II) and tin(II). The raffinate resulted from the recovery of gold(III), tin(II) and copper(II) by solvent extraction from a leaching solution of anode slime. Ion exchange with anionic resins was not effective in separating silver(I) because tin(II) and zinc(II) were selectively adsorbed into the anionic resins. It was possible to separate silver(I) by cementation with copper sheet. Treatment of the cemented silver with nitric acid solution increased the purity of silver(I) in the solution from 50.9% to 99.99%. Adjusting the pH of the AgNO3 solution to higher than 6, followed by adding ascorbic acid as a reducing agent, led to the synthesis of silver particles with micron size.

scholarly journals A Process for the Separation of Noble Metals from HCl Liquor Containing Gold(III), Palladium(II), Platinum(IV), Rhodium(III), and Iridium(IV) by Solvent Extraction

Processes ◽  
2019 ◽  
Vol 7 (5) ◽  
pp. 243 ◽  
Author(s):  
Wei Dong Xing ◽  
Man Seung Lee
Keyword(s):  
Solvent Extraction ◽  
Metal Ions ◽  
Noble Metals ◽  
The Other ◽  
Secondary Resources ◽  
Cyanex 272 ◽  
Leaching Solution ◽  
Hcl Concentration ◽  
Hcl Solution ◽  
Excellent Chemical

The demand for noble metals is increasing, owing to their excellent chemical and physical properties. In order to meet the demand, the recovery of noble metals with high purity from diverse secondary resources, which contain small amounts of noble metals, is of immense value. In this work, the possibility of the separation of Au(III), Pd(II), Pt(IV), Rh(III), and Ir(IV) by solvent extraction from a synthetic HCl solution is investigated. Only Au(III) was selectively extracted by Cyanex 272 in the HCl concentration range from 0.5 M to 9 M, leaving the other metal ions in the raffinate. The loaded Au(III) in Cyanex 272 was efficiently stripped by (NH2)2CS. The other four noble metals were sequentially separated on the basis of the procedures reported in the previous work. The mass balance showed that about 98% of each metal, except Pt(IV), was recovered by the proposed process. An efficient process for the recovery of the five noble metal ions from the HCl leaching solution of secondary resources containing these metals can be developed.

scholarly journals The Manufacture of Synthetic Rutile by Solvent Extraction of Tri-Alkyl Phosphine Oxide from HCl Leaching Solution of Soda-Roasted Ilmenite Ore

Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 588
Author(s):  
Sung-Ho Joo ◽  
Dong Ju Shin ◽  
Dongseok Lee ◽  
Jungshin Kang ◽  
Min-seuk Kim ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Organic Phase ◽  
Phosphine Oxide ◽  
Inductively Coupled Plasma ◽  
Spherical Shape ◽  
Feed Solution ◽  
Synthetic Rutile ◽  
Inductively Coupled ◽  
Leaching Solution ◽  
Series Of Experiments

To manufacture TiO2, a high-purity synthetic rutile, the recovery of Ti was investigated using a hydro-metallurgical process. Using a feed solution containing 32050 mg/L Ti, 110 mg/L Si, 88 mg/L Nb, 2614 mg/L Fe, and 130 mg/L Zr, solvent-extraction experiments were conducted with alkyl phosphine oxide in conjunction with diluents such as kerosene and xylene. The results showed that the extraction mechanism of both diluents was very similar to slope analysis, which had a value of 1.9; however, the extraction equilibrium constant value of organic–metallic species in xylene as a diluent was lower than in kerosene as a diluent. This result affected the stripping efficiency of Ti in particular; therefore, xylene was selected as a diluent. To recover Ti ion from a leaching solution, a series of experiments was conducted, such as the McCabe–Thiele method and countercurrent simulation test for extraction and stripping of Ti. As a result, Ti and impurities such as Fe and Zr were extracted to 99.9% from Si and Nb under optimal conditions using countercurrent four-stage extraction, with 1 M Cyanex 923 at a ratio of organic phase/ aqueous phase=3. In the stripping test, Ti was selectively stripped to 90.1% from Fe and Zr in the organic phase by 1 M HCl. The obtained powder, which was hydrolyzed from an impurity-free solution, was analyzed to a purity of 99.9% by inductively coupled plasma. The TiO2, which has a spherical shape and a diameter of approximately 2 µm according to SEM, was evident by XRD.

Synthesis of a Novel Dibenzylamide Derivative of p-tert-Octylcalix[4]arene and its Extraction Properties Towards Noble Metal Ions

2017 ◽  
Vol 70 (5) ◽  
pp. 450 ◽  
Author(s):  
Jee Young Kim ◽  
Yoga Priastomo ◽  
Shintaro Morisada ◽  
Hidetaka Kawakita ◽  
Keisuke Ohto ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Solvent Extraction ◽  
Metal Ions ◽  
Contact Time ◽  
Nitric Acid Concentration ◽  
Precious Metals ◽  
Extractant Concentration ◽  
Acid Media ◽  
Slope Analysis ◽  
Extraction Properties

A N,N-dibenzylacetoamide derivative of p-tert-octylcalix[4]arene was synthesised and its solvent extraction of precious metals in nitric acid media was investigated for determining the effects of extractant concentration and contact time as well as nitric acid concentration in comparison with a N,N-diethylacetoamide derivative. The extraction properties with both derivatives exhibited a slight difference. The extraction reaction of divalent palladium with both derivatives is discussed by slope analysis. The stripping behaviour of the extractant loaded with silver and palladium is also described using various stripping solutions.

Recovery of Silver from the Nitrate Leaching Solution of the Spent Ag/α-Al2O3 Catalyst by Solvent Extraction

2014 ◽  
Vol 53 (52) ◽  
pp. 20241-20246 ◽  
Author(s):  
Pan-Pan Sun ◽  
Hyoung-Il Song ◽  
Tae-Young Kim ◽  
Byoung-Jun Min ◽  
Sung-Yong Cho
Keyword(s):  
Solvent Extraction ◽  
Nitrate Leaching ◽  
Leaching Solution ◽  
Α Al2o3 ◽  
Al2o3 Catalyst

Comparative study on Ce (III) and La (III) solvent extraction and separation from a nitric acid medium by D2EHPA and Cyanex272

2018 ◽  
Vol 115 (2) ◽  
pp. 207 ◽  
Author(s):  
R. Habibpour ◽  
M. Dargahi ◽  
E. Kashi ◽  
M. Bagherpour
Keyword(s):  
Nitric Acid ◽  
Solvent Extraction ◽  
Metal Ion ◽  
Chemical Speciation ◽  
Extraction Efficiency ◽  
Nitric Acid Medium ◽  
Extraction And Separation ◽  
Multi Stage ◽  
Three Stages ◽  
Ion Species

The solvent extraction of Cerium(III) and Lanthanum(III) from nitric acid solution using the organophosphorous extractants Di-(2-ethyl hexyl) phosphate (D2EHPA) and di-2,4,4- trimethylpentyl phosphoric acid (Cyanex272) in kerosene was investigated. In this study, the magnitude of the extraction of Ce(III) was found to be more significant with Cyanex272 than D2EHPA. D2EHPA was found to be a better extractant for La(III). Among the two extractants, Cyanex272 was used for the separation of Ce from La in three stages with an extraction efficiency of 90.2% for Ce. A 556 mg/L Ce solution was used for the scrubbing of La with an efficiency of ≈34%, which required multi stage scrubbing. The study of thermodynamic parameters such as enthalpy, entropy, and Gibbs free energy impart the exothermic and non-spontaneous process. The chemical speciation curves for lanthanum and cerium in the aqueous phase as a function of pH showed that the free La(III) and Ce(III) metal ion species were largely predominate between a pH = 0 and pH = 7.

scholarly journals Non-aqueous solvent extraction of indium from an ethylene glycol feed solution by the ionic liquid Cyphos IL 101: speciation study and continuous counter-current process in mixer–settlers

RSC Advances ◽  
2020 ◽  
Vol 10 (41) ◽  
pp. 24595-24612 ◽  
Author(s):  
Clio Deferm ◽  
Bieke Onghena ◽  
Viet Tu Nguyen ◽  
Dipanjan Banerjee ◽  
Jan Fransaer ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solvent Extraction ◽  
Ethylene Glycol ◽  
Feed Solution ◽  
Aqueous Solvent ◽  
Speciation Study ◽  
Cyphos Il 101 ◽  
Glycol Solution ◽  
Counter Current ◽  
Insight Into

Speciation studies give insight into the mechanism of non-aqueous solvent extraction of indium from ethylene glycol solution by the ionic liquid Cyphos IL 101.

Crown ether as size selective synergist in the solvent extraction of thorium(IV) and uranium(VI) with 3-phenyl-4-(4-fluorobenzoyl)-5-isoxazolone

2001 ◽  
Vol 89 (7) ◽  
Author(s):  
M.L.P. Reddy ◽  
R. Meera
Keyword(s):  
Nitric Acid ◽  
Solvent Extraction ◽  
Crown Ether ◽  
Metal Ions ◽  
Synergistic Extraction ◽  
Acid Solutions ◽  
Nitric Acid Solutions

The synergistic extraction of thorium(IV) and uranium(VI) from nitric acid solutions has been investigated using mixtures of 3-phenyl-4-(4-fluorobenzoyl)-5-isoxazolone (HFBPI) and dicyclohexano-18-crown-6 (DC18C6), dibenzo-18-crown-6 (DB18C6) or benzo-15-crown-5 (B15C5). The results demonstrate that these metal ions are extracted into chloroform as Th(FBPI)

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