scholarly journals Sorting Liquid Droplets by Surface Tension Using Devices with Quasi-Superamphiphobic Coatings

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 820 ◽  
Author(s):  
Yu-Ping Zhang ◽  
Di Fan ◽  
Xiu-Zhi Bai ◽  
Cheng-Xing Cui ◽  
Jun Chen ◽  
...  

Any solid surface with homogenous or varying surface energy can spontaneously show variable wettability to liquid droplets with different or identical surface tensions. Here, we studied a glass slide sprayed with a quasi-superamphiphobic coating consisting of a hexane suspension of perfluorosilane-coated nanoparticles. Four areas on the glass slide with a total length of 7.5 cm were precisely tuned via ultraviolet (UV) irradiation, and droplets with surface tensions of 72.1–33.9 mN m−1 were categorized at a tilting angle of 3°. Then, we fabricated a U-shaped device sprayed with the same coating and used it to sort the droplets more finely by rolling them in the guide groove of the device to measure their total rolling time and distance. We found a correlation between ethanol content/surface tension and rolling time/distance, so we used the same device to estimate the alcoholic strength of Chinese liquors and to predict the surface tension of ethanol aqueous solutions.

Author(s):  
Hong Chen ◽  
Toru Yamada ◽  
Mohammad Faghri

Capillary burst valve (CBV), a counterpart to an elastomeric diaphragm microvalve, handles fluid in microchannels by capillarity. Thus, it avoids integration of mechanical components. We experimentally estimated the burst pressure, beyond which CBV cannot hold fluid, using fluids with distinct surface tensions in CBVs grafted with distinct surface constitutions in microchannels. We found that both the fluid surface tension and the solid surface constitution influence the burst pressure. The burst pressure reduces more significantly under the influence of the fluid surface tension.


1987 ◽  
Vol 42 (7) ◽  
pp. 690-694 ◽  
Author(s):  
K. Igarashi

Molar volumes and surface tensions of molten LaCl3-KCl mixtures were measured by dilatometry and the maxim um bubble pressure method, respectively. The molar volume isotherms were found to deviate positively from additivity over the whole composition range, with the maxim um deviation at ca. 30 mol% LaCl3. At the same concentration the isotherms of surface tension at temperatures below 950 °C show a minimum . Surface energy of mixing per unit area calculated from the surface tensions shows a large negative excess at the corresponding composition. These observations are related to the existence o f LaCl63- in the KCl-rich melt.


1922 ◽  
Vol 4 (4) ◽  
pp. 373-385 ◽  
Author(s):  
Wallace O. Fenn

The theoretical behavior of a hypothetical fluid cell in contact with flat and curved solid surfaces is discussed from the point of view of surface tension. An equation is derived for calculating the equilibrium position of the cell on a flat surface in terms of the surface tensions between the cell and the plasma, the plasma and the solid surface, and the solid surface and the cell. It is shown that the same equilibrium is predicted from consideration of the contact angle between the cell and the solid body. The relative surface energy has been calculated at various stages in the ingestion of a solid particle by a fluid cell four times as large in diameter, and it is thus shown that no particle will be ingested until the surface tensions are such that the cell would spread to infinity on a flat surface of the same substance. Here again the same equilibrium is predicted from considerations of the contact angle. The adhesiveness of blood cells to solid substances is shown to be a pure surface tension phenomenon, but in most reactions between living cells and solid bodies the fluidity of the protoplasm is also a factor of prime importance. The frequent occurrence of adhesiveness as a property of cells in contact with solid bodies is due in part to the fact that, by so adhering, the surface area of the cell not touching the solid is decreased.


Author(s):  
P. J. Goodhew

Cavity nucleation and growth at grain and phase boundaries is of concern because it can lead to failure during creep and can lead to embrittlement as a result of radiation damage. Two major types of cavity are usually distinguished: The term bubble is applied to a cavity which contains gas at a pressure which is at least sufficient to support the surface tension (2g/r for a spherical bubble of radius r and surface energy g). The term void is generally applied to any cavity which contains less gas than this, but is not necessarily empty of gas. A void would therefore tend to shrink in the absence of any imposed driving force for growth, whereas a bubble would be stable or would tend to grow. It is widely considered that cavity nucleation always requires the presence of one or more gas atoms. However since it is extremely difficult to prepare experimental materials with a gas impurity concentration lower than their eventual cavity concentration there is little to be gained by debating this point.


Author(s):  
Shuai Meng ◽  
Qian Wang ◽  
Rui Yang

The phenomenon of impaction between liquid droplets and solid particles is involved in many scientific problems and engineering applications, such as impaction between sprayed droplet and solid particles in limestone injection desulfurization system and the collision between a droplet of the liquid to be granulated and a seed particle in fluidized bed spray granulation process. There are a lot of factors affected this phenomenon: droplet and particle size, momentum of both liquid droplet and solid particles, materials, surface conditions of the solid particles and so on. However the experimental or numerical researches have been done mostly pay attention to Specific application or process, so the impaction phenomenon has not been through studied, for example how different factors affected the impaction process with its effect on different applications. This paper focuses on the basic issue of interaction between droplet and solid particles. Three main factors were considered: ratio of diameter between the droplet and solid particle, relative velocity and the surface tension (including the contact angle between droplet and solid particle). All the study is based on simulation using SPH (smoothed particle hydrodynamics) method, and the surface tension is simulated by particle-particle interaction.


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