scholarly journals Synthesis of an Addition-Crosslinkable, Silicon-Modified Polyolefin via Reactive Extrusion Monitored by In-Line Raman Spectroscopy

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1246
Author(s):  
Steffen Ulitzsch ◽  
Tim Bäuerle ◽  
Mona Stefanakis ◽  
Marc Brecht ◽  
Thomas Chassé ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
High Performance ◽  
Process Analytical Technology ◽  
Statistical Design ◽  
Reactive Extrusion ◽  
Statistical Design Of Experiments ◽  
Grafting Efficiency ◽  
Grafting Reaction ◽  
Central Composite Experimental Design ◽  
Process Factors

We present the modification of ethylene-propylene rubber (EPM) with vinyltetra-methydisiloxane (VTMDS) via reactive extrusion to create a new silicone-based material with the potential for high-performance applications in the automotive, industrial and biomedical sectors. The radical-initiated modification is achieved with a peroxide catalyst starting the grafting reaction. The preparation process of the VTMDS-grafted EPM was systematically investigated using process analytical technology (in-line Raman spectroscopy) and the statistical design of experiments (DoE). By applying an orthogonal factorial array based on a face-centered central composite experimental design, the identification, quantification and mathematical modeling of the effects of the process factors on the grafting result were undertaken. Based on response surface models, process windows were defined that yield high grafting degrees and good grafting efficiency in terms of grafting agent utilization. To control the grafting process in terms of grafting degree and grafting efficiency, the chemical changes taking place during the modification procedure in the extruder were observed in real-time using a spectroscopic in-line Raman probe which was directly inserted into the extruder. Successful grafting of the EPM was validated in the final product by 1H-NMR and FTIR spectroscopy.

Optimization of operating parameters for efficient photocatalytic inactivation of Escherichia coli based on a statistical design of experiments

2015 ◽  
Vol 71 (6) ◽  
pp. 823-831 ◽  
Author(s):  
Mehrzad Feilizadeh ◽  
Iran Alemzadeh ◽  
Amin Delparish ◽  
M. R. Karimi Estahbanati ◽  
Mahdi Soleimani ◽  
...  
Keyword(s):  
Escherichia Coli ◽  
Reaction Temperature ◽  
High Performance ◽  
Statistical Design ◽  
Water Disinfection ◽  
Response Analysis ◽  
Operating Parameters ◽  
Statistical Design Of Experiments ◽  
Photocatalytic Disinfection ◽  
Initial Ph

In this work, the individual and interaction effects of three key operating parameters of the photocatalytic disinfection process were evaluated and optimized using response surface methodology (RSM) for the first time. The chosen operating parameters were: reaction temperature, initial pH of the reaction mixture and TiO2 P-25 photocatalyst loading. Escherichia coli concentration, after 90 minutes irradiation of UV-A light, was selected as the response. Twenty sets of photocatalytic disinfection experiments were conducted by adjusting operating parameters at five levels using the central composite design. Based on the experimental data, a semi-empirical expression was established and applied to predict the response. Analysis of variance revealed a strong correlation between predicted and experimental values of the response. The optimum values of the reaction temperature, initial pH of the reaction mixture and photocatalyst loading were found to be 40.3 °C, 5.9 g/L, and 1.0 g/L, respectively. Under the optimized conditions, E. coli concentration was observed to reduce from 107 to about 11 CFU/mL during the photocatalytic process. Moreover, all these results showed the great significance of the RSM in developing high performance processes for photocatalytic water disinfection.

scholarly journals Optimization of Arabian-Shield-Based Natural Pozzolan and Silica Fume for High-Performance Concrete Using Statistical Design of Experiments

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Yassir M. Abbas ◽  
M. Iqbal Khan
Keyword(s):  
Silica Fume ◽  
High Performance ◽  
Prediction Models ◽  
High Performance Concrete ◽  
Blended Cement ◽  
Statistical Design ◽  
Partial Replacement ◽  
Statistical Design Of Experiments ◽  
Natural Pozzolan ◽  
Surface Design

In this study, the optimum dosages of silica fume (SF) and natural pozzolan (NP) were experimentally and statistically assessed for the best strength and durability properties of high-performance concrete (HPC). SF and NP were used as partial replacement Portland cement (PC) by up to 12 and 25 wt.%, respectively. Additionally, the prediction models based on second-level factorial (SLF) and response surface design (RSD) were formulated to estimate the HPC properties and their validation. The SLF-based model was further employed to investigate the significance and interactions of the PC, SF, and NP blends. The 28-day strength of the blended-cement HPC with a water-to-binder ratio w / b of 0.25 was generally higher than that of the control concrete. The positive synergy of PC–NP–SF was also observed in the HPC permeability. The paired t -test of the mean square error (MSE) of the SLF- and RSD-based models revealed that the MSE of the former was notably less than that of the latter. These results established the superiority of the SLF-based model over the RSD-based model. Therefore, the SLF-based model was further employed to investigate the importance of various binders.

STATISTICAL DESIGN OF EXPERIMENTS FOR THE Cr(VI) ADSORPTION ON WEED Salvinia cucullata

2013 ◽  
Vol 12 (3) ◽  
pp. 465-474 ◽  
Author(s):  
Saroj Sundar Baral ◽  
Ganesan Surendran ◽  
Namrata Das ◽  
Polisetty Venkateswara Rao
Keyword(s):  
Design Of Experiments ◽  
Statistical Design ◽  
Statistical Design Of Experiments

scholarly journals Flux Method Growth of Large Size Group IV–V 2D GeP Single Crystals and Photoresponse Application

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 235
Author(s):  
Shuqi Zhao ◽  
Tongtong Yu ◽  
Ziming Wang ◽  
Shilei Wang ◽  
Limei Wei ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Single Crystals ◽  
High Performance ◽  
Group Iv ◽  
X Ray Diffraction ◽  
High Quality ◽  
Practical Applications ◽  
Large Size ◽  
Growth Method ◽  
Polarized Raman

Two-dimensional (2D) materials driven by their unique electronic and optoelectronic properties have opened up possibilities for their various applications. The large and high-quality single crystals are essential to fabricate high-performance 2D devices for practical applications. Herein, IV-V 2D GeP single crystals with high-quality and large size of 20 × 15 × 5 mm3 were successfully grown by the Bi flux growth method. The crystalline quality of GeP was confirmed by high-resolution X-ray diffraction (HRXRD), Laue diffraction, electron probe microanalysis (EPMA) and Raman spectroscopy. Additionally, intrinsic anisotropic optical properties were investigated by angle-resolved polarized Raman spectroscopy (ARPRS) and transmission spectra in detail. Furthermore, we fabricated high-performance photodetectors based on GeP, presenting a relatively large photocurrent over 3 mA. More generally, our results will significantly contribute the GeP crystal to the wide optoelectronic applications.

scholarly journals Evaluation of Cutting-Tool Coating on the Surface Roughness and Hole Dimensional Tolerances during Drilling of Al6061-T651 Alloy

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1783
Author(s):  
Hamza A. Al-Tameemi ◽  
Thamir Al-Dulaimi ◽  
Michael Oluwatobiloba Awe ◽  
Shubham Sharma ◽  
Danil Yurievich Pimenov ◽  
...  
Keyword(s):  
Surface Roughness ◽  
Cutting Tool ◽  
Good Practice ◽  
Cutting Tools ◽  
Statistical Design ◽  
Cutting Parameters ◽  
Statistical Design Of Experiments ◽  
Hole Quality ◽  
Coated Tools ◽  
Tool Coating

Aluminum alloys are soft and have low melting temperatures; therefore, machining them often results in cut material fusing to the cutting tool due to heat and friction, and thus lowering the hole quality. A good practice is to use coated cutting tools to overcome such issues and maintain good hole quality. Therefore, the current study investigates the effect of cutting parameters (spindle speed and feed rate) and three types of cutting-tool coating (TiN/TiAlN, TiAlN, and TiN) on the surface finish, form, and dimensional tolerances of holes drilled in Al6061-T651 alloy. The study employed statistical design of experiments and ANOVA (analysis of variance) to evaluate the contribution of each of the input parameters on the measured hole-quality outputs (surface-roughness metrics Ra and Rz, hole size, circularity, perpendicularity, and cylindricity). The highest surface roughness occurred when using TiN-coated tools. All holes in this study were oversized regardless of the tool coating or cutting parameters used. TiN tools, which have a lower coating hardness, gave lower hole circularity at the entry and higher cylindricity, while TiN/TiAlN and TiAlN seemed to be more effective in reducing hole particularity when drilling at higher spindle speeds. Finally, optical microscopes revealed that a built-up edge and adhesions were most likely to form on TiN-coated tools due to TiN’s chemical affinity and low oxidation temperature compared to the TiN/TiAlN and TiAlN coatings.

Study of surface modification of recycled ultrafiltration membranes using statistical design of experiments

2021 ◽  
Vol 23 ◽  
pp. 100978
Author(s):  
L. Rodríguez-Sáez ◽  
J. Landaburu-Aguirre ◽  
S. Molina ◽  
M.C. García-Payo ◽  
E. García-Calvo
Keyword(s):  
Surface Modification ◽  
Design Of Experiments ◽  
Statistical Design ◽  
Statistical Design Of Experiments ◽  
Ultrafiltration Membranes

Role of Magnesium Salts in Coal De-Ashing by Flotation

2021 ◽  
Vol 58 (1) ◽  
pp. 51-58
Author(s):  
Rawya Gamal ◽  
Nader A.A. Edress ◽  
Khaled A. Abuhasel ◽  
Ayman A. El-Midany ◽  
Salah E. El-Mofty
Keyword(s):  
Particle Size ◽  
Strong Interaction ◽  
Statistical Design ◽  
Ash Content ◽  
The Other ◽  
Pulp Density ◽  
Statistical Design Of Experiments ◽  
Coal Flotation ◽  
Magnesium Salts

Abstract The most frequently investigated salts in coal flotation are chlorides. However, seawater contains additional salts such as sulfates. In coal flotation, magnesium chlorides showed the best results in terms of higher yield and lower ash content compared to the other magnesium salts studied. Therefore, two magnesium salts were tested in this investigation, namely magnesium chloride and magnesium sulfate. The effect of the magnesium salts as well as the optimization of coal flotation were investigated by statistical design of experiments in terms of pulp density, particle size, conditioning time and different dosages of MgCl2 and MgSO4. The flotation results obtained by statistical design show that the ash content was lowest at 8.2% when a mixture of 2 kg/t MgSO4 and 2 kg/t MgCl2 has been used, with pulp density 20%, particle size 400 lm and conditioning time 15 min. The particle size plays an important role in reducing the ash content when the conditioning time has been extended and pulp density has been reduced. The strong interaction between the salts hinders the reduction of the ash content to less than 8.2%.

Sign in / Sign up

Export Citation Format

Share Document