MOLECULAR INTERACTION STUDY USING ULTRASONIC TECHNIQUE OF BINARY LIQUID SOLUTION

2020 ◽  
Vol 14 (5) ◽  
2009 ◽  
Vol 6 (4) ◽  
pp. 1150-1152 ◽  
Author(s):  
R. Uvarani ◽  
J. Sivapragasam

Molecular interaction studies using ultrasonic technique in the binary liquid mixtures of cyclohexanone witho-cresol andp-cresol have been carried out at 303 K. Using the measured values of ultrasonic velocity, density and viscosity, acoustical parameters and their excess values are evaluated. From the properties of these excess parameters the nature and strength of the interactions in these binary systems are discussed.


Author(s):  
A. Raguraman ◽  
N. Santhi

The acoustical parameters for the binary liquid mixtures containing Pyrazoline derivatives in DMF have been estimated at 303.15 K, from the measured values of ultrasonic velocity (U), density (ρ) and viscosity (η). From these data some of acoustical parameters such as adiabatic compressibility (β), free length (Lf), acoustic impedance (Z), Rao’s constant (R), molar compressibility (W), relaxation time (τ), free volume (Vf) and internal pressure (πi), etc., have been computed using the standard relations. The results have been discussed in terms of molecular interactions.


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