A Study on the In-situ Separation of GaN by Using Thermal Decomposition

2013 ◽  
Vol 63 (11) ◽  
pp. 1290-1295
Author(s):  
Sinae KIM ◽  
Sungkuk CHOI ◽  
Jiho CHANG* ◽  
Hyunjae LEE ◽  
Siyoung KIM ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
In Situ Separation

An in situ investigation of the thermal decomposition of metal-organic framework NH2-MIL-125 (Ti)

2021 ◽  
Vol 316 ◽  
pp. 110957
Author(s):  
Mian Zahid Hussain ◽  
Mounib Bahri ◽  
Werner R. Heinz ◽  
Quanli Jia ◽  
Ovidiu Ersen ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Metal Organic Framework ◽  
In Situ Investigation ◽  
Metal Organic ◽  
Organic Framework

In-situ investigation on the thermal decomposition of van der Waals MoO3

2021 ◽  
pp. 138840
Author(s):  
Xinyue Lv ◽  
Siyuan Wang ◽  
Li Gong ◽  
Qiulan Chen ◽  
Yueli Zhang ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Van Der Waals ◽  
In Situ Investigation

TiO2/sulfonated graphene oxide/Ag nanoparticle membrane: In situ separation and photodegradation of oil/water emulsions

2018 ◽  
Vol 554 ◽  
pp. 16-25 ◽  
Author(s):  
Dongliang Qian ◽  
Dongyun Chen ◽  
Najun Li ◽  
Qingfeng Xu ◽  
Hua Li ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Ag Nanoparticle ◽  
Sulfonated Graphene ◽  
In Situ Separation ◽  
Oil Water

In situ synthesis of oxidized MXene-based metal cobalt spinel nanocomposites for an excellent promotion in thermal decomposition of ammonium perchlorate

2021 ◽  
Author(s):  
Keding Li ◽  
Jun Liao ◽  
Siqi Huang ◽  
Yuqing Lei ◽  
Yong Zhang ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ammonium Perchlorate ◽  
In Situ Synthesis ◽  
Cobalt Spinel ◽  
Calcination Method

A novel oxidized MXene-supported MCo2O4 (oxidized MXene/MCo2O4, M = Mn, Zn, Cu and Co) nanocomposite was successfully synthesized through a facile hydrothermal assisted calcination method. Various characterization results indicated that...

On the dimorphism of Pr6Mo10O39

2017 ◽  
Vol 72 (11) ◽  
pp. 765-774
Author(s):  
Daniel Rudolph ◽  
Sonja Laufer ◽  
Ingo Hartenbach
Keyword(s):  
Crystal Structure ◽  
Thermal Decomposition ◽  
Single Crystals ◽  
Main Product ◽  
Molar Ratio ◽  
Coordination Environment ◽  
Space Group ◽  
Coordination Numbers ◽  
Dense Modification

AbstractAttempts to synthesize Pr4Mo7O27 using Pr, Pr6O11 and MoO3 in a molar ratio of 8:6:77 led to a main product of scheelite-type Pr0.667[MoO4] and few single crystals of the triclinic A-type Pr6Mo10O39. The latter crystallizes in space group P1̅ (a=945.25(1), b=1058.49(2), c=1815.16(3) pm; α=104.149(1), β=95.220(1), γ=102.617(1)°, Z=2). Its crystal structure comprises six crystallographically independent Pr3+ cations, eight tetrahedral [MoO4]2− units, and one [Mo2O7]2− entity. The cations display coordination numbers of seven (1×) and eight (5×), while the [MoO4]2− tetrahedra are surrounded by five Pr3+ cations each. The [Mo2O7]2− anions exhibit a coordination environment of seven Pr3+ cations. The attempt to synthesize PrF[MoO4] using PrOF (from in situ thermal decomposition of PrF[CO3]) as reagent did not lead to the desired product but to monoclinic B-type Pr6Mo10O39. This slightly less dense modification compared to its triclinic analogue crystallizes in space group C2/c (a=1247.93(3), b=1989.68(6), c=1392.52 (4) pm, β=100.505(2)°, Z=4) with three crystallographically independent Pr3+ cations, four [MoO4]2− tetrahedra, and again one [Mo2O7]2− unit in the crystal structure. Thus, both Pr6Mo10O39 modifications are better described with the structured formula Pr6[MoO4]8[Mo2O7]. The coordination numbers around the Pr3+ cations are seven (1×) and eight (2×) while all four [MoO4]2− anions are again surrounded by five Pr3+ cations each. Six of the latter represent the coordination environment around the [Mo2O7]2− entities. Besides the thorough comparison of the crystal structures single crystal Raman spectra were recorded for both Pr6Mo10O39 phases.

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