Synthesis of Flavor 3-Methylthiopropionaldehyde Diethyl Acetal

2011 ◽  
Vol 335-336 ◽  
pp. 1352-1357
Author(s):  
Wei Guan ◽  
Yu Ping Liu ◽  
Zhi Wei Miao ◽  
De Li Shen ◽  
Yu Cao
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Gas Chromatography ◽  
Infrared Spectroscopy ◽  
Reaction Time ◽  
Magnetic Resonance ◽  
Raw Materials ◽  
Triethyl Orthoformate ◽  
Diethyl Acetal ◽  
Mechanism Of The Reaction

3-Methylthiopropionaldehyde diethyl acetal was synthesized from the reaction of 3-methylthiopropional with ethanol and triethyl orthoformate. The effecting factors including the kinds of catalyst, the mole ratio of raw materials, the amount of catalyst and the reaction time were optimized. The structure of product was characterized by gas chromatography, infrared spectroscopy, mass spectrometry, and nuclear magnetic resonance. Additionally, the mechanism of the reaction was speculated; the odor characteristics were evaluated.

Ring-Opening Polymerization of Lactide Using Aluminum Salen-Type Initiators

2014 ◽  
Vol 915-916 ◽  
pp. 713-716
Author(s):  
Qing Zhang ◽  
Jing Tian ◽  
Zhi Qi Cao ◽  
Ru Xia Xu ◽  
Zhen Zhen Sun ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Infrared Spectroscopy ◽  
Reaction Time ◽  
Magnetic Resonance ◽  
Schiff Bases ◽  
Reaction Temperature ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Resonance Spectroscopy ◽  
Aluminum Complex

In this investigation, Schiff bases aluminum complex was synthesized and used as the initiator in the polymerization of D,L-lactide. The aluminum complex was characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The influences of different factors, including reaction time, reaction temperature, and the ratio of D, L-lactide/Al3+ on the synthesis of polylactide were described. The results showed that Schiff bases aluminum complex could be successfully applied in the ring opening polymerization. The optimum condition of the ring opening polymerization of D,L-lactide, which included D,L-lactide/Al3+ (mol/mol) ratio of 250, reaction temperature of 120 °C, and reaction time of 16 hours.

scholarly journals Synthesis and characterization of solid 2-methoxycinnamylidenepyruvic acid

2008 ◽  
Vol 33 (4) ◽  
pp. 61-68 ◽  
Author(s):  
C. T. de Carvalho ◽  
A. B. Siqueira ◽  
E. Y. Ionashiro ◽  
M. Pivatto ◽  
M. Ionashiro
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Differential Scanning Calorimetry ◽  
Infrared Spectroscopy ◽  
Magnetic Resonance ◽  
Molecular Geometry ◽  
Synthesis And Characterization ◽  
Scanning Calorimetry ◽  
Purity Determination

The 2-methoxycinnamylidenepyruvic acid (2-MeO-HCP) was synthesized and characterized for nuclear magnetic resonance (¹H and 13C NMR), mass spectrometry (MS), Infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The application of DSC for purity determination is well documented in literature and is used in the analysis of pure organic compounds. The molecular geometry and vibrational frequencies of 2-MeO-HCP have been calculated.

Comparison of hydrogenolysis with thioacidolysis for lignin structural analysis

Holzforschung ◽  
2014 ◽  
Vol 68 (2) ◽  
pp. 151-155 ◽  
Author(s):  
Daniel J. van de Pas ◽  
Bernadette Nanayakkara ◽  
Ian D. Suckling ◽  
Kirk M. Torr
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Gas Chromatography ◽  
Nmr Spectroscopy ◽  
Structural Analysis ◽  
Magnetic Resonance ◽  
Gas Chromatography Mass Spectrometry ◽  
Aryl Ether ◽  
Chromatography Mass Spectrometry

Abstract Mild hydrogenolysis has been compared with thioacidolysis as a method for degrading lignins in situ and in isolated form before analysis by gas chromatography/mass spectrometry and quantitative 31P nuclear magnetic resonance (NMR) spectroscopy. Both degradation methods gave similar levels of β-aryl ether-linked phenylpropane units that were released as monomers. Degradation by hydrogenolysis generally gave lower levels of total phenylpropane units when analyzed by 31P NMR, especially in the case of lignins with high levels of condensed units. Overall, these results indicate that mild hydrogenolysis could offer an alternative to thioacidolysis for probing lignin structure.

scholarly journals Chemical Composition of Needle, Cone, and Branch Oils From Vietnamese Pinus cernua

2019 ◽  
Vol 14 (5) ◽  
pp. 1934578X1985099 ◽  
Author(s):  
Tran Hui Thai ◽  
Nguyen Thi Hien ◽  
Le Ngoc Diep ◽  
Mathieu Paoli ◽  
Joseph Casanova ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Gas Chromatography ◽  
Chemical Composition ◽  
Magnetic Resonance ◽  
Retention Index ◽  
Gas Chromatography Mass Spectrometry ◽  
Chromatography Mass Spectrometry ◽  
Main Component ◽  
Pine Species

Conifers are well represented in Vietnam where a new pine species has been recently discovered in Son La province: Pinus cernua, synonym P. armandii ssp. xuannhaensis. The compositions of needle, cone, and branch oils have been investigated by gas chromatography (retention index), gas chromatography-mass spectrometry, and 13C nuclear magnetic resonance. Myrcene (47.0%) was the main component of needle oil, followed by β-pinene (28.4%) and α-pinene (12.5%). Branch oil also contained myrcene (32.8%), α-pinene (17.9%), β-pinene (9.8%), and a high content of limonene (20.0%). Finally, cone oil displayed α-pinene (44.1%) beside myrcene (11.5%), β-pinene (8.1%), and limonene (5.8%).

Eine ungewöhnliche intramolekulare Photoreaktion eines Hexachlorhexahydromethanonaphthalins / An Unusual Intramolecular Photoreaction of a Hexachlorohexahydromethanonaphthaline

1978 ◽  
Vol 33 (12) ◽  
pp. 1563-1564
Author(s):  
H. Parlar
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Infrared Spectroscopy ◽  
Magnetic Resonance ◽  
Spectral Data ◽  
Column Chromatography ◽  
Nuclear Magnetic

Photoreactions of 2-exo-bromo-5,6,7,8,9,9- hexachloro-1,2,4 a, 5,8,8 a-hexahydro-5,8-methanonaphthaline (1) were studied in the presence of acetophenone. With the help of column chromatography an unusual isomerisation product (3) was isolated, whose structure was established by spectral data obtained by mass spectrometry, infrared spectroscopy, and 1H nuclear magnetic resonance measurements.

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