Removal of Cr(VI) from Aqueous Solutions Using PVA/SA Blend Films

2013 ◽  
Vol 781-784 ◽  
pp. 2142-2145
Author(s):  
Wen Juan Fan ◽  
Hong Xiang Ge ◽  
Yu Pang ◽  
Hui Chang

The different ratios (PVA and SA) of PVA/SA blend films with cross-linking structure are successfully prepared by coagulating the mixture of sodium alginate (SA) and polyvinyl alcohol (PVA) in aqueous solution, then by treating with crosslinking agent CaCl2solution. The Surface morphology and flexibility of PVA/SA blend films were studied. The results indicate there is some strong interaction and good compatibility between sodium alginate and polyvinyl alcohol molecular. The physical and chemical properties of the PSA-80(PVA:SA=4:1) blend films are obviously improved owing to a molecular force and hydrogen bond interaction. The effects of parameters of the blend film was investigated in relation to its adsorption capability for low concentration ions Cr (VI) including such as SA content of the PVA/SA film, contact time, solution pH and temperature of solution. The results indicate that the maximum adsorption rate is 95.86% at the temperature 50°C under optimized pH 4 for 60min by PSA-80 films.

2021 ◽  
pp. 118286
Author(s):  
Luís Marangoni Júnior ◽  
Renan Garcia da Silva ◽  
Carlos Alberto Rodrigues Anjos ◽  
Roniérik Pioli Vieira ◽  
Rosa Maria Vercelino Alves

Author(s):  
Maria S. Fufaeva ◽  
Darya V. Fisenko ◽  
Vladimir N. Manzhay ◽  
Vladimir G. Bondaletov ◽  
Lyubov K. Altunina

The paper presents the results of studies of the flow properties of viscous compositions consisting of polyvinyl alcohol, polymeric oil resin, and water. After a freeze-thaw cycle three-component cryogels are formed from them. Mechanical, thermal, physical, and chemical properties of the resulted elastic samples are studied. The prospects of using hydrophobic cryogels filled with polymeric oil resin as a binder component for road pavement construction are presented


Author(s):  
Rinta Kusumawati ◽  
Jamal Basmal ◽  
Bagus Sediadi Bandol Utomo

Characterization of sodium alginate extracted from two species of brown seaweed (Turbinaria sp. and Sargassum sp.) has been conducted. The aim of the study was to evaluate physical and chemical properties of the two different types of sodium alginates produced from this extraction process. Extraction was conducted in alkaline solution followed by acid treatment with the following steps: sortation of seaweed, washing, alkaline extraction, bleaching, alginic acid and sodium alginate conversion, dehydration using isopropyl alcohol (IPA), drying, chopping and grinding. Each extraction was conducted in duplicate using approximately 1 kg of the raw materials. The physical and chemical properties of the final products (sodium alginate powders) were analyzed. The results of the analysis were as follows: the yield of alginate powder from Turbinaria sp. was 14.77% having water content of 13.48%; whiteness degree of 23.77%; and viscosity of 133.67 cPs while the yield of sodium alginate powder extracted from Sargassum sp. was 24.56% with water content of 12.69%; whiteness degree of 43.80%; and viscosity of 217.50 cPs. Both alginate powders had better physical characteristics compared to commercial grade alginate which had water content of 16.07%, whiteness degree of 29.37%, and viscosity of 102.67cPs.


2021 ◽  
Author(s):  
Anita Kotar ◽  
Sicong Ma ◽  
Sarah C Keane

MicroRNAs (miRNAs) are important regulators of post-transcriptional gene expression. Mature miRNAs are generated from longer transcripts (primary, pri- and precursor, pre-miRNAs) through a series of highly coordinated enzymatic processing steps. The sequence and structure of these pri- and pre-miRNAs play important roles in controlling their processing. Both pri- and pre-miRNAs adopt hairpin structures with imperfect base pairing in the helical stem. Here, we investigated the role of three base pair mismatches (A·A, G·A, and C·A) present in pre-miRNA-31. Using a combination of NMR spectroscopy and thermal denaturation, we found that the three base pair mismatches displayed unique structural properties, including varying dynamics and sensitivity to solution pH. These studies deepen our understanding of how the physical and chemical properties of base pair mismatches influence RNA structural stability.


1966 ◽  
Vol 24 ◽  
pp. 101-110
Author(s):  
W. Iwanowska

In connection with the spectrophotometric study of population-type characteristics of various kinds of stars, a statistical analysis of kinematical and distribution parameters of the same stars is performed at the Toruń Observatory. This has a twofold purpose: first, to provide a practical guide in selecting stars for observing programmes, second, to contribute to the understanding of relations existing between the physical and chemical properties of stars and their kinematics and distribution in the Galaxy.


Author(s):  
Mehmet Sarikaya ◽  
Ilhan A. Aksay

Biomimetics involves investigation of structure, function, and methods of synthesis of biological composite materials. The goal is to apply this information to the design and synthesis of materials for engineering applications.Properties of engineering materials are structure sensitive through the whole spectrum of dimensions from nanometer to macro scale. The goal in designing and processing of technological materials, therefore, is to control microstructural evolution at each of these dimensions so as to achieve predictable physical and chemical properties. Control at each successive level of dimension, however, is a major challenge as is the retention of integrity between successive levels. Engineering materials are rarely fabricated to achieve more than a few of the desired properties and the synthesis techniques usually involve high temperature or low pressure conditions that are energy inefficient and environmentally damaging.In contrast to human-made materials, organisms synthesize composites whose intricate structures are more controlled at each scale and hierarchical order.


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