Nitrogen transformations and ammonia volatilization losses from 15N-urea as affected by the co-application of composted pig manure

2007 ◽  
Vol 87 (5) ◽  
pp. 485-493 ◽  
Author(s):  
Woo-Jung Choi ◽  
Scott X Chang ◽  
Jin-Hyeob Kwak ◽  
Jae-Woon Jung ◽  
Sang-Sun Lim ◽  
...  
Keyword(s):  
Organic Matter ◽  
Urease Activity ◽  
Ammonia Volatilization ◽  
Order Rate Constant ◽  
Urea Hydrolysis ◽  
Pig Manure ◽  
Nitrogen Transformations ◽  
N Loss ◽  
N Losses ◽  
15N Urea

Co-application of composted manure (compost) and urea is considered an environment-friendly fertilization practice; however, the high urease activity in compost may stimulate NH3 volatilization and cause N loss from co-applied urea. To test the above hypothesis, we investigated the fate of urea co-applied with compost in a loam-textured soil through two laboratory incubation experiments. Urea (150 mg N kg-1) was co-applied with 0, 4.9, 9.8, and 14.6 g of compost (oven-dry basis) kg-1 of soil, designated as treatments UC0, UC1, UC2, and UC3, respectively. Co-application of compost and urea enhanced urea hydrolysis and increased the 1st order rate constant of urea hydrolysis from 0.047 h-1 in the UC0 to 0.139 h-1 in the UC3 treatments. Soil pH increased from 7.0 for UC0 to 7.6 for UC3, leading to greater NH3 volatilization (up to two times more) in the soils receiving 9.8 g kg-1 or more of compost. Compost co-application also increased the immobilization of urea-derived N, probably because the organic matter added in compost stimulated microbial growth or NH4+ fixation. Between 15 and 17% of urea-N was not recovered at the end of the incubation, but there was no difference in N loss among the treatments resulting from the contrasting effects (NH3 volatilization vs. NH4+ immobilization) of compost on N losses. Our results clearly show that application of compost with high urease activity increases NH3 volatilization loss of N from the co-applied urea, but the total amount of N lost is also affected by immobilization of NH4+ by the organic matter added to the soil through the applied compost. Key words: Ammonia volatilization, nitrogen dynamics, nitrogen-15 recovery, organic carbon, urease activity

EFFECTS OF CATECHOL AND P-BENZOQUINONE ON THE HYDROLYSIS OF UREA AND ENERGY BARRIERS OF UREASE ACTIVITY IN SOILS

1984 ◽  
Vol 64 (1) ◽  
pp. 51-60 ◽  
Author(s):  
J. S. TOMAR ◽  
A. F. MacKENZIE
Keyword(s):  
Activation Energy ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Key Words ◽  
Urease Activity ◽  
Urea Hydrolysis ◽  
Urease Inhibitors ◽  
Soil Urease ◽  
Hydrolysis Of ◽  
Hydrolysis Of Urea

The effects of the urease inhibitors, catechol and p-benzoquinone, and temperature on the hydrolysis of urea in five soils were investigated in a laboratory study. Urea hydrolysis decreased significantly with the amount of inhibitors applied and increased significantly with each 5 °C increase in temperature from 5 to 25 °C. The effectiveness of inhibitors generally decreased with increases in temperature from 5 to 25 °C. The correlation of hydrolysis of urea with organic matter contents of the soils was highly significant (r = 0.67** to 0.86**). Both catechol and p-benzoquinone tended to increase the energies and entropies of activation of soil urease and the effect was enhanced with a decrease in soil organic matter. It is suggested that an increase in the activation energy of the soil urease as a result of inhibitor use was related to an increase in the effectiveness of the inhibitor. Key words: Urease inhibitors, urea hydrolysis, energy of activation

scholarly journals Ammonia volatilization losses in Tanzania grass fertilized with urea

2015 ◽  
Vol 16 (1) ◽  
pp. 253-264 ◽  
Author(s):  
Cecílio Viega SOARES FILHO ◽  
Ulysses CECATO ◽  
Ossival Lolato RIBEIRO ◽  
Cláudio Fabrício da Cruz ROMA ◽  
Tatiane BELONI
Keyword(s):  
Ammonia Volatilization ◽  
Repeated Measurements ◽  
N Loss ◽  
N Losses ◽  
Total N ◽  
Factors Affecting ◽  
Randomized Design ◽  
Different Seasons ◽  
Completely Randomized Design ◽  
N Volatilization

<p>Gaseous losses are the main factors affecting the efficiency of nitrogenous fertilizers in pastures. To evaluate NH<sub>3</sub>-N volatilization losses in Tanzania grass fertilized with urea in autumn, spring and summer, a completely randomized design with repeated measurements over time and fifteen replicates was used. Plots were represented by urea levels (50; 100 and 150 kg ha<sup>-1</sup> N) and subplots by time after fertilization (1; 2; 3; 6; 9; 12 and 15 days). The interaction between fertilization leveland time after urea application was significant for the accumulated NH<sub>3</sub>-N volatilization. Urea application leads to higher percentage N losses in the first three days after application. The average cumulative NH<sub>3</sub>-N loss for the three occasions (different seasons of the year) was 28%, 20% and 16% of N applied for fertilizer doses of 50; 100 and 150 kg ha<sup>-1</sup>of N, respectively. The season of the year influenced NH<sub>3</sub>-N loss pattern and volume, with the lowest values recorded in spring, followed by summer and autumn. The cumulative NH<sub>3</sub>-N volatilization loss varies from 78 to 90% up to the third day after application of the total N-NH3 loss.</p>

scholarly journals Ammonia volatilization of urea in the out-of-season corn

2009 ◽  
Vol 33 (6) ◽  
pp. 1685-1694 ◽  
Author(s):  
Hamilton Seron Pereira ◽  
Anabelisa Ferreira Leão ◽  
Adriana Verginassi ◽  
Marco Aurélio Carbone Carneiro
Keyword(s):  
Urease Activity ◽  
Ammonia Volatilization ◽  
Urease Inhibitors ◽  
Urease Inhibitor ◽  
N Losses ◽  
Coated Urea ◽  
Polymer Coated Urea

The aim of this study was to evaluate the N losses due to volatilization at different rates of common urea, polymer coated urea and urease inhibitor-treated urea in the out-of-season corn, using semi-open static collectors. The treatments consisted of N levels on side-dressing fertilization with urea in different treatments: (a) control (without N), (b) urea 40 kg ha-1 N, (c) urea 80 kg ha-1 N, (d) polymer coated urea 40 kg ha-1 N, (e) polymer coated urea 80 kg ha-1 N and (f) urea with the urease inhibitor (UI) N 80 kg ha-1 N. The results showed that the treatments with polymer coated urea and with urease inhibitor-treated urea reduced the volatilization of N around 50 % compared to common urea, either in the first and the second N side-dressing fertilizations. Thus, they demonstrate that the polymer coat and the urease inhibitors were effective in reducing the volatilization of urea N applied in coverage, which resulted in higher productivity. There was also increasing urease activity in the treatments with application of common urea.

scholarly journals The succession pattern of bacterial diversity in compost using pig manure mixed with wood chips analyzed by 16S rRNA gene analysis

2019 ◽  
Author(s):  
Zhengfeng Li ◽  
Yan Yang ◽  
Yuzhen Xia ◽  
Tao Wu ◽  
Jie Zhu ◽  
...  
Keyword(s):  
Organic Matter ◽  
High Temperature ◽  
Urease Activity ◽  
Early Stage ◽  
Ammonium Nitrogen ◽  
Wood Chips ◽  
Pig Manure ◽  
Rrna Gene ◽  
Carbon To Nitrogen Ratio ◽  
Nitrogen Ratio

AbstractThe pig manure mixed with wood chips and formed compost by means of fermentation. We found that the protease activity, organic matter content and ammonium nitrogen concentration were higher in the early stage of composting. Meanwhile, the urease activity was highest in the high temperature period. The carbon to nitrogen ratio of the compost decreased continuously with fermentation. The dynamic change in the composition of bacterial overtime in the compost of a 180 kg piles were explored using microbial diversity analysis. The results showed that the microbial species increased with the compost fermentation. At the early stage of composting, the phyla of Firmicutes and Actinomycetes were dominant. The microbes in the high temperature period were mainly composed of Firmicutes and Proteobacteria while the proportion of Bacteroides was increased during the cooling period. In the compost of maturity stage, the proportion of Chloroflexi increased, becoming dominant species with other microorganisms including Firmicutes, Proteobacteria, Bacteroides, Chloroflexi but not Actinomycetes. Bacteria involved in lignocellulose degradation, such as those of the Thermobifida, Cellvibrio, Mycobacterium, Streptomyces and Rhodococcus, were concentrated in the maturity stages of composting. Through correlation analysis, the environmental factors including organic matter, ammonium nitrogen and temperature were consistent with the succession of microbial including Rhodocyclaceae, Anaerolineaceae, Thiopseudomonas, Sinibacillus and Tepidimicrobium. The change of urease activity and carbon to nitrogen ratio corresponded to microbial communities, mainly containing Anaerolineaceae, Rhodocyclaceae, Luteimoas, Bacillaceae, Corynebacterium, Bacillus, Anaerococcus, Lactobacillus, Ignatzschineria, and Bacillaceae.

scholarly journals Effects of Zeolitic Urea on Nitrogen Leaching (NH4-N and NO3-N) and Volatilization (NH3) in Spodosols and Alfisols

Water ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 1921
Author(s):  
Ayaz Ahmad ◽  
Shahzada Sohail Ijaz ◽  
Zhenli He
Keyword(s):  
Soil Amendment ◽  
Ammonia Volatilization ◽  
Agricultural Soils ◽  
N Leaching ◽  
Nh3 Volatilization ◽  
N Loss ◽  
N Losses ◽  
Urea Nitrogen ◽  
Urea Fertilizer ◽  
Very High

Global use of urea nitrogen (N) fertilizer is increasing, but N losses are still very high (40–70%). Zeolites have the capability of holding NH4+, thus reducing N losses when applied as a soil amendment. However, application of a large quantity of zeolite is costly and inconvenient. In this study, zeolitic fertilizers were evaluated to select the best formulation with reduced leaching of NH4-N and NO3-N and NH3 volatilization in agricultural soils (Alfisol and Spodosol). The treatments included the following: T0 = control, T1 = urea fertilizer, T2 = zeo-urea (1:1), T3 = zeo-urea (2:1), T4 = zeo-urea (3:1), T5 = zeo-urea (1:2), and T6 = zeo-urea (1:3). Leaching was performed at 4, 8, 12, 19, 25, 32, 39 and 45 days after the soils were treated with the designated fertilizers, including control, and packed into columns. Leachate samples were collected after each leaching event and analyzed for the concentrations of NH4-N and NO3-N and the quantity of leachate. Ammonia volatilization was recorded at days 1, 5, 9, 13 and 20 of soil treatments. Results indicate that zeolitic fertilizer formulations effectively reduced N losses. NH4-N loss was reduced by 13% and 28% by zeo-urea (1:1) in Alfisol and Spodosol soils, respectively, whereas zeo-urea (2:1) and zeo-urea (3:1) effectively decreased NO3-N leaching in Alfisol. Volatilization loss of NH3 was reduced by 47% in Spodosol and 32% in Alfisol soil with zeo-urea (1:1) as compared with that of urea fertilizer. The results suggest that zeo-urea (1:1) is an effective fertilizer formulation for reducing N losses, especially in Alfisol, as compared with conventional urea fertilizer.

Nitrogen turnover and loss during storage of slurry and composting of solid manure under typical Vietnamese farming conditions

2010 ◽  
Vol 149 (3) ◽  
pp. 285-296 ◽  
Author(s):  
M. T. TRAN ◽  
T. K. V. VU ◽  
S. G. SOMMER ◽  
L. S. JENSEN
Keyword(s):  
Animal Feed ◽  
Plant Nutrients ◽  
Pig Manure ◽  
Pig Slurry ◽  
N Loss ◽  
N Losses ◽  
N Content ◽  
Total N ◽  
Available N ◽  
Slurry Storage

SUMMARYA high proportion of plant nutrients present in animal feed are excreted and therefore animal manure can be an important source of nitrogen (N) for crop production if losses of plant nutrients to the environment during storage and processing are minimized. The present study examines gaseous N losses from stored pig slurry and during composting of solid manure as affected by protein and fibre content in the feed and manure management. Two slurry storage treatments (with and without cover) and three additives to solid manure composting (straw only, straw+lime and straw+superphosphate) were examined for three common types of pig feed in Vietnam (low-protein high-fibre, medium-protein medium-fibre and high-protein low-fibre).Feed type was found to affect the N content in pig slurry or manure and thus potential N losses. The fraction of N loss caused by N emission from covered slurry storage was 0·25–0·30 of initial N content, while that from uncovered slurry was 0·60–0·70. After 90 days of storage, 1·15–1·20 times the initial ammonium-N (NH4-N) was found in the covered slurry and 0·40–0·50 in the uncovered. The fraction of N lost during composting with superphosphate was 0·25–0·35 of initial total N, while with lime or straw the total N loss was 0·45–0·55. With added superphosphate, 1·25–1·60 times the initial NH4-N in manure was found in the compost after 80 days compared with only 0·11–0·22 for lime and 0·22–0·36 for straw only. Covering stored slurry and addition of superphosphate when composting solid pig manure are thus important methods for Vietnamese farmers to minimize N losses and produce compost with a high content of plant-available N.

Rétention de l'azote et évolution des propriétés d'un humus brut de station de pin gris (Pinusbanksiana Lamb.) après application d'engrais azotés

1981 ◽  
Vol 11 (1) ◽  
pp. 51-61 ◽  
Author(s):  
C. Camiré ◽  
B. Bernier
Keyword(s):  
Organic Matter ◽  
Ammonia Volatilization ◽  
Jack Pine ◽  
Exchange Capacity ◽  
Urea Hydrolysis ◽  
Mineral Nitrogen ◽  
Mineral Fertilizers ◽  
Cationic Exchange

The addition of urea invitro to the coarse humus of a jack pine nursery has led to an increased pH following urea hydrolysis, with the result that the cationic exchange capacity was increased while the organic matter in the humus was partly dissolved. Furthermore, considerable losses of nitrogen due to ammonia volatilization are likely to occur following the application of urea. The use of nitrate mineral fertilizers ((NH4)2SO4, NH4NO3, or (NO3)2Ca), though these are not subject to losses through ammonia volatilization, produces a significant displacement of soil elements. Moreover, the nitrogen in such fertilizers is more prone to leaching than mineral nitrogen freed by urea hydrolysis.

scholarly journals Urease Inhibitors Effects on the Nitrogen Use Efficiency in a Maize–Wheat Rotation with or without Water Deficit

Agriculture ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 684
Author(s):  
Raúl Allende-Montalbán ◽  
Diana Martín-Lammerding ◽  
María del Mar Delgado ◽  
Miguel A. Porcel ◽  
José L. Gabriel
Keyword(s):  
Ammonia Volatilization ◽  
Urease Inhibitors ◽  
Urease Inhibitor ◽  
Adaptation To Climate Change ◽  
N Loss ◽  
N Losses ◽  
Wheat Field ◽  
Promising Strategy ◽  
Use Efficiency ◽  
N Use

The use of urease inhibitors in irrigated systems decreases both soil ammonium (NH4+) and nitrate (NO3−) availability, and, thus, could be an easy tool to reduce N loss due to ammonia volatilization and NO3− leaching. The main goal of this experiment was to assess the effect of urease inhibitors on N use efficiency, N losses, and their economic impact in a maize-wheat field experiment. In this study, 10 treatments were compared, combining the urea fertilizer with or without urease inhibitor, applied in one or two dressings, and under optimal or sub-optimal irrigation. A single application of urease inhibitor (IN1d), coupled with the conventional urea, helped to reduce the nitrate leaching risk both during the maize period (even when compared to the two dressing treatment) and after harvest. In addition, this improvement was achieved together with an increase in economic benefit, even when compared with the application of the same amount of regular urea split into two dressings. Under low water availability systems, the benefits of applying urease inhibitors increased with respect to the application of regular urea, making this technique a very promising strategy for adaptation to climate change in arid and semiarid regions.

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