Determination of chemical oxygen demand for phenolic compounds from oil refinery wastewater implementing different methods

2021 ◽  
Vol 231 ◽  
pp. 44-53
Author(s):  
Shaimaa T. Kadhum ◽  
Ghayda Yassen Alkindi ◽  
Talib M. Albayati
Keyword(s):  
Phenolic Compounds ◽  
Chemical Oxygen Demand ◽  
Oxygen Demand ◽  
Oil Refinery ◽  
Refinery Wastewater ◽  
Oil Refinery Wastewater

The use of steel slags in the heterogeneous Fenton process for decreasing the chemical oxygen demand of oil refinery wastewater

2018 ◽  
Vol 78 (5) ◽  
pp. 1159-1167 ◽  
Author(s):  
Behnam Heidari ◽  
Mohsen Soleimani ◽  
Nourollah Mirghaffari
Keyword(s):  
Microwave Irradiation ◽  
Chemical Oxygen Demand ◽  
Steel Slag ◽  
Oxygen Demand ◽  
Oil Refinery ◽  
Fenton Process ◽  
Refinery Wastewater ◽  
Optimum Conditions ◽  
Heterogeneous Fenton ◽  
Oil Refinery Wastewater

Abstract The Fenton process is a useful and inexpensive type of advanced oxidation process for industrial wastewater treatment. This study was performed with the aim of using the steel slag as a catalyst in the heterogeneous Fenton process in order to reduce the chemical oxygen demand (COD) of oil refinery wastewater. The effects of various parameters including the reaction time (0.5, 1.0, 2.0, 3.0 and 4.0 h), pH (2.0, 3.0, 4.0, 5.0, 6.0 and 7.0), the concentration of steel slag (12.5, 25.0 and 37.5 g/L), and H2O2 concentration (100, 250, 400 and 500 mg/L) on the Fenton process were investigated. Furthermore, the effect of microwave irradiation on the process efficiency was studied by considering the optimum conditions of the mentioned parameters. The results showed that using 25.0 g/L of steel slag and 250 mg/L H2O2, at pH = 3.0, could reduce COD by up to 64% after 2.0 h. Also, microwave irradiation decreased the time of the process from 120 min to 25 min in the optimum conditions, but it consumed a high amount of energy. It could be concluded that steel slags had a high potential in the treatment of oil refinery wastewater through the Fenton process.

scholarly journals Oil refinery wastewater treatment in biofilm reactor followed by sand filtration aiming water reuse

2012 ◽  
Vol 2 (2) ◽  
pp. 84-91 ◽  
Author(s):  
Isabelli N. Dias ◽  
Ana C. Cerqueira ◽  
Geraldo L. Sant'Anna ◽  
Marcia Dezotti
Keyword(s):  
Water Reuse ◽  
Slow Rate ◽  
Combined Treatment ◽  
Oxygen Demand ◽  
Biofilm Reactor ◽  
Oil Refinery ◽  
Treated Wastewater ◽  
Refinery Wastewater ◽  
Oil Refinery Wastewater

Oil refinery wastewater was sequentially treated in a moving-bed biofilm reactor (MBBR) and a slow-rate sand filter (SF) in order to obtain an effluent with adequate characteristics for downstream reverse osmosis (RO) operation. Experiments were conducted in bench scale units and the results showed that the MBBR was able to remove 90% chemical oxygen demand (COD), 75% NH4+, 95% phenols, operating with a hydraulic retention time (HRT) of 9 h. Additional removal of COD (15–40%) and ammonia (30–60%) was achieved in the slow-rate SF that was also effective for removing microorganisms. The silt density index (SDI) of the treated wastewater (4.5) was below the maximum limit recommended for RO operation. The quality of the effluent from the combined treatment system (MBBR+SF) was already adequate for cooling tower make-up. The RO produced an effluent with quality compatible with that required for use in boilers.

Characterization and removal of phenolic compounds from condensate-oil refinery wastewater

2014 ◽  
Vol 54 (3) ◽  
pp. 660-671 ◽  
Author(s):  
W. Al Hashemi ◽  
M.A. Maraqa ◽  
M.V. Rao ◽  
Md M. Hossain
Keyword(s):  
Phenolic Compounds ◽  
Oil Refinery ◽  
Refinery Wastewater ◽  
Oil Refinery Wastewater

Determination of the priority indexes for the oil refinery wastewater treatment process

2017 ◽  
Author(s):  
M. G. Chesnokova ◽  
A. V. Myshlyavtsev ◽  
A. S. Kriga ◽  
A. P. Shaporenko ◽  
V. V. Markelov
Keyword(s):  
Wastewater Treatment ◽  
Treatment Process ◽  
Oil Refinery ◽  
Refinery Wastewater ◽  
Wastewater Treatment Process ◽  
Oil Refinery Wastewater

scholarly journals Photosynthetic Microbial Desalination Cell to Treat Oily Wastewater Using Microalgae Chlorella Vulgaris

2019 ◽  
Vol 5 (12) ◽  
pp. 2686-2699 ◽  
Author(s):  
Suhad Shamil Jaroo ◽  
Ghufran F. Jumaah ◽  
Talib R. Abbas
Keyword(s):  
Optical Density ◽  
Chlorella Vulgaris ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Oil Refinery ◽  
Cathode Chamber ◽  
Refinery Wastewater ◽  
Operation Period ◽  
Microbial Desalination Cell ◽  
Oil Refinery Wastewater

Microbial desalination cell (MDC) offers a new and sustainable approach to desalinate saltwater by directly utilizing the electrical power generated by bacteria during organic matter oxidation. In this study, we used microalgae Chlorella Vulgaris in the cathode chamber to produce oxygen as an electron accepter by photosynthesis process for generate bioelectricity power and treat oil refinery wastewater by microorganisms in both anode and cathode.The power density generated by this Photosynthetic Microbial Desalination Cell (PMDC) with 1KΩ external resistance at the first 4th hr. of operation period was 0.678 W/m3 of anode volume and 0.63 W/m3 of cathode volume. It increased after one day to a peak value of (4.32 W/m3 of anode volume and 4.013 W/m3 of cathode volume). The microalgae growth in the biocathode chamber followed in terms of optical density. The optical density increased from 0.546 at the beginning of the system operation to 1.71 after 24 days of operation period. The percentage removal of chemical oxygen demand (COD) of oil refinery wastewater was 97.33% and 79.22% in anode and cathode chamber, respectively. The microalgae in the biocathode were able to remove volatile compounds causing odor from the influent wastewater. TDS removal rate 159.722 ppm/h with initial TDS in desalination chamber of 35000 ppm.

scholarly journals Photodegradation and kinetics of edible oil refinery wastewater using titanium dioxide

2021 ◽  
Vol 117 (11/12) ◽  
Author(s):  
Eki T. Aisien ◽  
Felix A. Aisien
Keyword(s):  
Titanium Dioxide ◽  
Diffusion Mechanism ◽  
Oxygen Demand ◽  
Order Equation ◽  
Edible Oil ◽  
Oil Refinery ◽  
Refinery Wastewater ◽  
Significant Difference ◽  
Kinetics Of ◽  
Oil Refinery Wastewater

Edible oil refinery wastewater (EORW) is one source of environmental pollution in Nigeria. The treatment of EORW before discharge into the environment remains a significant challenge in the edible oil refinery industries. This research was aimed at photocatalytic treatment of EORW using a batch photocatalytic reactor with titanium dioxide photocatalyst. We investigated the physicochemical parameters: chemical oxygen demand (COD), biological oxygen demand (BOD5), oil and grease, phenol, chloride (Cl-), total suspended solids, sulfate (SO42-), and phosphate (PO43-) using American Public Health Association methods. The results showed that the reduction efficiency of the treated EORW with TiO2 catalyst ranged between 65.8% (PO43-) and 87.0% (COD), and the improvement in efficiency was 54.1% (pH) and 60.8% dissolved oxygen. However, the results showed no significant difference (p<0.05) in the control treatment without catalyst. The biodegradability of EORW increased from 0.196 to 0.32. It was observed that the optimum values were an initial EORW concentration of 100 mL/L, irradiation time of 90min, catalyst dose of 1.25 g/L, and an agitation speed of 900 rpm. The kinetics of the photodegradation process was well described by the pseudo-first-order equation (R2>0.96) and pseudo-second-order equation (R2>0.98). The intra-particle diffusion model fairly represented the diffusion mechanism with an R2 value of 0.806. The treated EORW met the most acceptable water quality standards for discharged effluent according to the maximum permissible limits of the Nigerian National Environmental Standards and Regulations Enforcement Agency.

Rapid Determination of Chemical Oxygen Demand in Sugar Refinery Wastewater by Short-Wave Near-Infrared Spectroscopy

2012 ◽  
Vol 549 ◽  
pp. 167-171 ◽  
Author(s):  
Tao Pan ◽  
Zeng Hai Chen
Keyword(s):  
Chemical Oxygen Demand ◽  
Near Infrared ◽  
Rapid Determination ◽  
Oxygen Demand ◽  
Short Wave ◽  
Good Prediction ◽  
Refinery Wastewater ◽  
Analysis Model ◽  
Sugar Refinery

Near-infrared (NIR) spectroscopy combined with partial least squares (PLS) regression and Savitzky-Golay (SG) smoothing was successfully applied for the rapid no-reagent determination of chemical oxygen demand (COD) in sugar refinery wastewater. Among 141 samples, 60 were randomly selected as the validation set. The remaining 81 samples were divided into the calibration set (50 samples) and the prediction set (31 samples) for a total of 20 times with certain similarities. The results showed that the short-wave NIR region (780 nm to 1100 nm) can be used as information waveband of COD in sugar refinery wastewater. The optimal SG smoothing parameters and PLS factors OD, DP, NSP, and F were 5, 5, 7, and 6, respectively. The modeling effects M-SEPAve, M-RP,Ave, M-SEPStd, and M-RP,Stdwere 24.3 mg/L, 0.971, 2.7 mg/L, and 0.007, respectively. The validation effects V-SEP and V-RP were 25.9 mg/L and 0.963, respectively. The results indicated that the method has good prediction effect and stability, and provided a reliable analysis model and valuable references for designing specialized instruments.

scholarly journals The operation characteristics of air cathode Microbial Desalination Cell to treat oil refinery wastewater

2021 ◽  
Vol 877 (1) ◽  
pp. 012002
Author(s):  
S S Jaroo ◽  
G F Jumaah ◽  
T R Abbas
Keyword(s):  
Removal Rate ◽  
Electrical Power ◽  
Anaerobic Bacteria ◽  
Oxygen Demand ◽  
Oil Refinery ◽  
Anode Chamber ◽  
Refinery Wastewater ◽  
Air Cathode ◽  
Microbial Desalination Cell ◽  
Oil Refinery Wastewater

Abstract This system [microbial desalination cell (MDC)] is considered an excellent sustainable process to treat wastewater by biological anaerobic oxidation of the organic material by electroactive bacteria, desalinate saltwater, and electrical power generation. In the present work, MDC was used for treating oil refinery wastewater in the anode chamber by anaerobic bacteria. Simultaneously, an air pump was used to provide the oxygen to the cathode chamber as an electron acceptor to generate bioelectricity power. The power density generated by this air cathode MDC with 1KΩ external resistance at the 1st experiment was 71.11 μW/m2. It increased to a peak value of 570.86 μW/m2 at the last experiment. The maximum chemical oxygen demand (COD) removal percent of oily wastewater was 96%. The higher salinity removal rate 150.39 ppm/h with a first salt concentration in a desalinating chamber of 35000 ppm.

scholarly journals Treatment of the oilfield-produced water and oil refinery wastewater by using inverse fluidization - A review

2019 ◽  
Keyword(s):  
Produced Water ◽  
Complex Mixture ◽  
Oxygen Demand ◽  
Soil Surface ◽  
Oil Refinery ◽  
Refinery Wastewater ◽  
Inorganic Matter ◽  
Inverse Fluidization ◽  
Oilfield Produced Water ◽  
Oil Refinery Wastewater

<p>Oilfield wastewater or produced water is a complex mixture contains oil, organic and inorganic matter and other compounds dissolved in water that ranges from fresh to brine. Discharging produced water pollute soil surface and underground water and create environment hassle. The objective of this study is to investigate and summarize the novel method of fluidization processes, used for the treatment of oilfield produced water and oil refinery wastewater. Characteristics of oilfield produced water and oil refinery wastewater from different field and various methods for treating these wastewaters are discussed. Oilfield produced water and oil refinery wastewater are strongly acidic (pH 3-4), have a high chemical oxygen demand (1200-2600 mg/L), high polyphenol content (23 mg/L) and are highly variable. Primary attention is focused on the fluidization treatment of oilfield produced water and oil refinery wastewater, mainly by inverse fluidization. Finally, areas where further research and attention are required are identified.</p>

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