scholarly journals A comprehensive biogeochemical record and annual flux estimates for the Sabaki River (Kenya)

2018 ◽  
Vol 15 (6) ◽  
pp. 1683-1700
Author(s):  
Trent R. Marwick ◽  
Fredrick Tamooh ◽  
Bernard Ogwoka ◽  
Alberto V. Borges ◽  
François Darchambeau ◽  
...  

Abstract. Inland waters impart considerable influence on nutrient cycling and budget estimates across local, regional and global scales, whilst anthropogenic pressures, such as rising populations and the appropriation of land and water resources, are undoubtedly modulating the flux of carbon (C), nitrogen (N) and phosphorus (P) between terrestrial biomes to inland waters, and the subsequent flux of these nutrients to the marine and atmospheric domains. Here, we present a 2-year biogeochemical record (October 2011–December 2013) at biweekly sampling resolution for the lower Sabaki River, Kenya, and provide estimates for suspended sediment and nutrient export fluxes from the lower Sabaki River under pre-dam conditions, and in light of the approved construction of the Thwake Multipurpose Dam on its upper reaches (Athi River). Erratic seasonal variation was typical for most parameters, with generally poor correlation between discharge and material concentrations, and stable isotope values of C (δ13C) and N (δ15N). Although high total suspended matter (TSM) concentrations are reported here (up to ∼ 3.8 g L−1), peak concentrations of TSM rarely coincided with peak discharge. The contribution of particulate organic C (POC) to the TSM pool indicates a wide biannual variation in suspended sediment load from OC poor (0.3 %) to OC rich (14.9 %), with the highest %POC occurring when discharge is < 100 m3 s−1 and at lower TSM concentrations. The consistent 15N enrichment of the particulate nitrogen (PN) pool compared to other river systems indicates anthropogenic N loading is a year-round driver of N export from the Sabaki Basin. The lower Sabaki River was consistently oversaturated in dissolved methane (CH4; from 499 to 135 111 %) and nitrous oxide (N2O; 100 to 463 %) relative to atmospheric concentrations. Wet season flows (October–December and March–May) carried > 80 % of the total load for TSM (∼ 86 %), POC (∼ 89 %), dissolved organic carbon (DOC; ∼ 81 %), PN (∼ 89 %) and particulate phosphorus (TPP; ∼ 82 %), with > 50 % of each fraction exported during the long wet season (March–May). Our estimated sediment yield (85 Mg km−2 yr−1) is relatively low on the global scale and is considerably less than the recently reported average sediment yield of ∼ 630 Mg km−2 yr−1 for African river basins. Regardless, sediment and OC yields were all at least equivalent or greater than reported yields for the neighbouring dammed Tana River. Rapid pulses of heavily 13C-enriched POC coincided with peak concentrations of PN, ammonium, CH4 and low dissolved oxygen saturation, suggesting that large mammalian herbivores (e.g. hippopotami) may mediate the delivery of C4 organic matter to the river during the dry season. Given recent projections for increasing dissolved nutrient export from African rivers, as well as the planned damming of the Athi River, these first estimates of material fluxes from the Sabaki River provide base-line data for future research initiatives assessing anthropogenic perturbation of the Sabaki Basin.

2017 ◽  
Author(s):  
Trent R. Marwick ◽  
Fredrick Tamooh ◽  
Bernard Ogwoka ◽  
Alberto V. Borges ◽  
François Darchambeau ◽  
...  

Abstract. Inland waters impart considerable influence on nutrient cycling and budget estimates across local, regional and global scales, whilst anthropogenic pressures, such as rising populations and the appropriation of land and water resources, are undoubtedly modulating the flux of carbon (C), nitrogen (N), and phosphorus (P) between terrestrial biomes to inland waters, and the subsequent flux of these nutrients to the marine and atmospheric domains. Here, we present a two year biogeochemical record (October 2011–December 2013) at bi-weekly sampling resolution for the lower Sabaki River, Kenya, and provide estimates for suspended sediment and nutrient export fluxes from the Athi-Galana-Sabaki (A-G-S) river basin under pre-dam conditions, and in light of the approved construction of the Thwake Multi-purpose Dam on the Athi River. Erratic seasonal variation was typical for most parameters, with generally poor correlation between discharge and material concentrations and stable isotopic signatures of C (δ13C) and N (δ15N). Although high total suspended matter (TSM) concentrations are reported here (up to ~ 3.8 g L−1), peak concentrations of TSM rarely coincided with peak discharge. The contribution of particulate organic C (POC) to the TSM pool indicates a wide bi-annual variation in suspended sediment load from OC-poor (0.3 %) to OC-rich (14.9 %), with the highest %POC occurring when discharge is  80 % of the total load for TSM (~ 86 %), POC (~ 89 %), DOC (~ 81 %), PN (~ 89 %) and TPP (~ 82 %), with > 50 % of each fraction exported during the long wet season (March–May). Our estimated sediment yield of 85 Mg km−2 yr−1 is relatively low on the global scale and is considerably less than the recently reported average sediment yield of ~ 630 Mg km−2 yr−1 for African river basins. Regardless, sediment and OC yields were all at least equivalent or greater than reported yields for the neighbouring and flow-regulated Tana River. Rapid pulses of heavily 13C-enriched POC coincided with peak concentrations of PN, ammonium, CH4 and low dissolved oxygen saturation, lead to the suggestion that large mammalian herbivores (e.g. hippopotami) may mediate the delivery of C4 organic matter to the river during the dry season. Given recent projections for increasing dissolved nutrient export from African rivers, as well as planned flow regulation on the Athi River, these first estimates of material fluxes from the Sabaki River provide base-line data for future research initiatives assessing anthropogenic perturbation of the A-G-S river basin.


1999 ◽  
Vol 39 (12) ◽  
pp. 41-45 ◽  
Author(s):  
A. I. Fraser ◽  
T. R. Harrod ◽  
P. M. Haygarth

Soil erosion, in the form of transported suspended sediment in overland flow, is often associated with high rates of particulate phosphorus (PP) (total P&gt;0.45 μm) transfer from land to watercourses. Particulate P may provide a long-term source of P for aquatic biota. Twenty-two sites for winter overland flow monitoring were selected in south-west England within fields ranging from 0.2–3.8 ha on conventionally-managed arable land. Fields were situated on highly porous, light textured soils, lacking impermeable horizons and often overlying major aquifers. Long arable use and modern cultivation methods result in these soils capping under rain impact. Overland flow was observed when rainfall intensity approached the modest rate of 0.8 mm hr−1 on land at or near to field capacity. Low intensity rainfall (&lt;2 mm hr−1) produced mean suspended sediment losses of 14 kg ha−1 hr−1, with associated PP transfer rates of 16 g ha−1 hr−1. In high intensity rainfall (&gt;9 mm hr−1) mean PP losses of 319 g ha−1 hr−1 leaving the field were observed. As might be expected, there was a good relationship between PP and suspended sediment transfer in overland flow leaving the sites. The capacity of light soils to cap when in arable use, combined with heavy or prolonged rainfall, resulted in substantial discharges, soil erosion and associated PP transfer. Storms with heavy rain, typically of only a few hours duration, were characterised by considerable losses of PP. Such events, with return periods of once or twice a winter, may account for a significant proportion of total annual P transfer from agricultural soils under arable crops. However, contributions from less intense rain with much longer duration (around 100 hours per winter in many arable districts of the UK) are also demonstrated here.


2014 ◽  
Vol 18 (6) ◽  
pp. 2191-2200 ◽  
Author(s):  
S. T. Harrington ◽  
J. R. Harrington

Abstract. The objective of this research was to investigate the relationship between water and sediment discharge on the transport of nutrients: nitrogen and phosphorus. Water discharge, suspended sediment concentration and dissolved and particulate forms of nitrogen and phosphorus were monitored on the 105 km2 River Owenabue catchment in Ireland. Water discharge was found to have an influence on both particulate and dissolved nutrient transport, but more so for particulate nutrients. The particulate portion of N and P in collected samples was found to be 24 and 39%, respectively. Increased particulate nitrogen concentrations were found at the onset of high discharge events, but did not correlate well to discharge. High concentrations of phosphorus were associated with increased discharge rates and the coefficient of determination (r2) between most forms of phosphorus and both discharge and suspended sediment concentrations were observed to be greater than 0.5. The mean TN yield is 4004 kg km−2 yr−1 for the full 29-month monitoring period with a mean PN yield of 982 kg km−2 yr−1, 25% of the TN yield with the contribution to the yield of PN and PP estimated to be 25 and 53% respectively. These yields represent a PN and PP contribution to the suspended sediment load of 5.6 and 0.28% respectively for the monitoring period. While total nitrogen and total phosphorus levels were similar to other European catchments, levels of bio-available phosphorus were elevated indicating a potential risk of eutrophication within the river.


Water ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1831 ◽  
Author(s):  
Donatella Pavanelli ◽  
Claudio Cavazza ◽  
Stevo Lavrnić ◽  
Attilio Toscano

Anthropogenic activities, and in particular land use/land cover (LULC) changes, have a considerable effect on rivers’ flow rates and their morphologies. A representative example of those changes and resulting impacts on the fluvial environment is the Reno Mountain Basin (RMB), located in Northern Italy. Characterized by forest exploitation and agricultural production until World War II, today the RMB consists predominantly of meadows, forests and uncultivated land, as a result of agricultural land abandonment. This study focuses on the changes of the Reno river’s morphology since the 1950s, with an objective of analyzing the factors that caused and influenced those changes. The factors considered were LULC changes, the Reno river flow rate and suspended sediment yield, and local climate data (precipitation and temperature). It was concluded that LUCL changes caused some important modifications in the riparian corridor, riverbed size, and river flow rate. A 40–80% reduction in the river bed area was observed, vegetation developed in the riparian buffer strips, and the river channel changed from braided to a single channel. The main causes identified are reductions in the river flow rate and suspended sediment yield (−36% and −38%, respectively), while climate change did not have a significant effect.


2013 ◽  
Vol 17 (11) ◽  
pp. 4641-4657 ◽  
Author(s):  
S. B. Morera ◽  
T. Condom ◽  
P. Vauchel ◽  
J.-L. Guyot ◽  
C. Galvez ◽  
...  

Abstract. Hydro-sedimentology development is a great challenge in Peru due to limited data as well as sparse and confidential information. This study aimed to quantify and to understand the suspended sediment yield from the west-central Andes Mountains and to identify the main erosion-control factors and their relevance. The Tablachaca River (3132 km2) and the Santa River (6815 km2), located in two adjacent Andes catchments, showed similar statistical daily rainfall and discharge variability but large differences in specific suspended-sediment yield (SSY). In order to investigate the main erosion factors, daily water discharge and suspended sediment concentration (SSC) datasets of the Santa and Tablachaca rivers were analysed. Mining activity in specific lithologies was identified as the major factor that controls the high SSY of the Tablachaca (2204 t km2 yr−1), which is four times greater than the Santa's SSY. These results show that the analysis of control factors of regional SSY at the Andes scale should be done carefully. Indeed, spatial data at kilometric scale and also daily water discharge and SSC time series are needed to define the main erosion factors along the entire Andean range.


Elem Sci Anth ◽  
2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Montserrat Roca-Martí ◽  
Claudia R. Benitez-Nelson ◽  
Blaire P. Umhau ◽  
Abigale M. Wyatt ◽  
Samantha J. Clevenger ◽  
...  

Fluxes of major bioelements associated with sinking particles were quantified in late summer 2018 as part of the EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) field campaign near Ocean Station Papa in the subarctic northeast Pacific. The thorium-234 method was used in conjunction with size-fractionated (1–5, 5–51, and &gt;51 μm) concentrations of particulate nitrogen (PN), total particulate phosphorus (TPP), biogenic silica (bSi), and particulate inorganic carbon (PIC) collected using large volume filtration via in situ pumps. We build upon recent work quantifying POC fluxes during EXPORTS. Similar remineralization length scales were observed for both POC and PN across all particle size classes from depths of 50–500 m. Unlike bSi and PIC, the soft tissue–associated POC, PN, and TPP fluxes strongly attenuated from 50 m to the base of the euphotic zone (approximately 120 m). Cruise-average thorium-234-derived fluxes (mmol m–2 d–1) at 120 m were 1.7 ± 0.6 for POC, 0.22 ± 0.07 for PN, 0.019 ± 0.007 for TPP, 0.69 ± 0.26 for bSi, and 0.055 ± 0.022 for PIC. These bioelement fluxes were similar to previous observations at this site, with the exception of PIC, which was 1 to 2 orders of magnitude lower. Transfer efficiencies within the upper twilight zone (flux 220 m/flux 120 m) were highest for PIC (84%) and bSi (79%), followed by POC (61%), PN (58%), and TPP (49%). These differences indicate preferential remineralization of TPP relative to POC or PN and larger losses of soft tissue relative to biominerals in sinking particles below the euphotic zone. Comprehensive characterization of the particulate bioelement fluxes obtained here will support future efforts linking phytoplankton community composition and food-web dynamics to the composition, magnitude, and attenuation of material that sinks to deeper waters.


Water ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3173
Author(s):  
Valentin Golosov ◽  
Anatoly Tsyplenkov

This paper discusses the joint impact of catchment complexity in topography, tectonics, climate, landuse patterns, and lithology on the suspended sediment yield (SSY, t km−2 year−1) in the Caucasus region using measurements from 244 gauging stations (GS). A Partial Least Square Regression (PLSR) was used to reveal the relationships between SSY and explanatory variables. Despite possible significant uncertainties on the SSY values, analysis of this database indicates clear spatial patterns of SSY in the Caucasus. Most catchments in the Lesser Caucasia and Ciscaucasia are characterized by relatively low SSY values (<100–150 t km−2 year−1), the Greater Caucasus region generally have higher SSY values (more than 150–300 t km−2 year−1). Partial correlation analyses demonstrated that such proxies of topography as height above nearest drainage (HAND) and normalized steepness index (Ksn) tend to be among the most important ones. However, a PLSR analysis suggested that these variables’ influence is likely associated with peak ground acceleration (PGA). We also found a strong relationship between land cover types (e.g., barren areas and cropland) and SSY in different elevation zones. Nonetheless, adding more gauging stations into analyses and more refined characterizations of the catchments may reveal additional trends.


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