scholarly journals Distribution of N<sub>2</sub>O in the Baltic Sea during transition from anoxic to oxic conditions

2006 ◽  
Vol 3 (4) ◽  
pp. 557-570 ◽  
Author(s):  
S. Walter ◽  
U. Breitenbach ◽  
H. W. Bange ◽  
G. Nausch ◽  
D. W. R. Wallace

Abstract. In January 2003, a major inflow of cold and oxygen-rich North Sea Water terminated an ongoing stagnation period in parts of the central Baltic Sea. In order to investigate the role of North Sea Water inflow in the production of nitrous oxide (N2O), we measured dissolved and atmospheric N

2006 ◽  
Vol 3 (3) ◽  
pp. 729-764 ◽  
Author(s):  
S. Walter ◽  
U. Breitenbach ◽  
H. W. Bange ◽  
G. Nausch ◽  
D. W. R. Wallace

Abstract. In January 2003, a major inflow of cold and oxygen-rich North Sea Water in the Baltic Sea terminated an ongoing stagnation period in parts of the central Baltic Sea. In order to investigate the role of North Sea Water inflow to the Baltic Sea with regard to the production of nitrous oxide (N2O), we measured dissolved and atmospheric N2O at 26 stations in the southern and central Baltic Sea in October 2003. At the time of our cruise, water renewal had proceeded to the eastern Gotland Basin, whereas the western Gotland Basin was still unaffected by the inflow. The deep water renewal was detectable in the distributions of temperature, salinity, and oxygen concentrations as well as in the distribution of the N2O concentrations: Shallow stations in the Kiel Bight and Pomeranian Bight were well-ventilated with uniform N2O concentrations near equilibrium throughout the water column. In contrast, stations in the deep basins, such as the Bornholm and the Gotland Deep, showed a clear stratification with deep water affected by North Sea Water. Inflowing North Sea Water led to changed environmental conditions, especially enhanced oxygen (O2) or declining hydrogen sulfide (H2S) concentrations, thus, affecting the conditions for the production of N2O. Pattern of N2O profiles and correlations with parameters like oxygen and nitrate differed between the basins. The dominant production pathway seems to be nitrification rather than denitrification. No indications for advection of N2O by North Sea Water were found. A rough budget revealed a significant surplus of in situ produced N2O after the inflow. However, due to the permanent halocline, it can be assumed that the formed N2O does not reach the atmosphere. Hydrographic aspects therefore are decisive factors determining the final release of produced N2O to the atmosphere.


Forests ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 317
Author(s):  
Darius Danusevičius ◽  
Jurata Buchovska ◽  
Vladas Žulkus ◽  
Linas Daugnora ◽  
Algirdas Girininkas

We aimed to extract DNA and amplify PCR fragments at the mitochondrial DNA Nad7.1 locus and 11 nuclear microsatellite loci in nine circa 11,000-year-old individuals of Scots pine found at the bottom of the Baltic sea and test the genetic associations with the present-day gene pool of Scots pine in Lithuania. We followed a strict anticontamination protocol in the lab and, simultaneously with the aDNA specimens, tested DNA-free controls. The DNA was extracted by an ATMAB protocol from the ancient wood specimens sampled underwater from Scots pine stumps located circa 20–30 m deep and circa 12 km ashore in western Lithuania. As the references, we used 30 present-day Lithuanian populations of Scots pine with 25–50 individuals each. The aDNA yield was 11–41 ng/μL. The PCR amplification for the mtDNA Nad7.1 locus and the nDNA loci yielded reliable aDNA fragments for three and seven out of nine ancient pines, respectively. The electrophoresis profiles of all the PCR tested DNA-free controls contained the sizing standard only, indicating low likelihood for contamination. At the mtDNA Nad7.1 locus, all three ancient Scots pine individuals had the type A (300 bp) allele, indicating postglacial migration from the refugia in Balkan peninsula. The GENECLASS Bayesian assignment tests revealed relatively stringer and consistent genetic associations between the ancient Scots pine trees and the present-day southern Lithuanian populations (assignment probability 0.37–0.55) and several wetlands in Lithuania. Our study shows that salty sea water efficiently preserves ancient DNA in wood at the quality levels suitable for genetic testing of trees dated back as far as 11,000 years before present.


Oceanologia ◽  
2020 ◽  
Author(s):  
Alexander Krek ◽  
Andrey Gusev ◽  
Elena Krek ◽  
Viktor Krechik ◽  
Mariia Kapustina ◽  
...  

2009 ◽  
Vol 6 (2) ◽  
pp. 1757-1817 ◽  
Author(s):  
R. Feistel ◽  
S. Weinreben ◽  
H. Wolf ◽  
S. Seitz ◽  
P. Spitzer ◽  
...  

Abstract. The brackish water of the Baltic Sea is a mixture of ocean water from the Atlantic/North Sea with fresh water from various rivers draining a large area of lowlands and mountain ranges. The evaporation-precipitation balance results in an additional but minor excess of fresh water. The rivers carry different loads of salts washed out of the ground, in particular calcium carbonate, which cause a composition anomaly of the salt dissolved in the Baltic Sea in comparison to Standard Seawater. Directly measured seawater density shows a related anomaly when compared to the density computed from the equation of state as a function of Practical Salinity, temperature and pressure. Samples collected from different regions of the Baltic Sea during 2006–2009 were analysed for their density anomaly. The results obtained for the river load deviate significantly from similar measurements carried out forty years ago; the reasons for this decadal variability are not yet fully understood. An empirical formula is derived which estimates Absolute from Practical Salinity of Baltic Sea water, to be used in conjunction with the new Thermodynamic Equation of Seawater 2010 (TEOS-10), endorsed by IOC/UNESCO in June 2009 as the substitute for the 1980 International Equation of State, EOS-80. Our routine measurements of the samples were accompanied by studies of additional selected properties which are reported here: conductivity, density, chloride, bromide and sulphate content, total CO2 and alkalinity.


2014 ◽  
Vol 14 (15) ◽  
pp. 21943-21974 ◽  
Author(s):  
J. E. Jonson ◽  
J. P. Jalkanen ◽  
L. Johansson ◽  
M. Gauss ◽  
H. A. C. Denier van der Gon

Abstract. Land-based emissions of air pollutants in Europe have steadily decreased over the past two decades, and this decrease is expected to continue. Within the same time span emissions from shipping have increased, although recently sulphur emissions, and subsequently particle emissions, have decreased in EU ports and in the Baltic Sea and the North Sea, defined as SECAs (Sulphur Emission Control Areas). The maximum allowed sulphur content in marine fuels in EU ports is now 0.1%, as required by the European Union sulphur directive. In the SECAs the maximum fuel content of sulphur is currently 1% (the global average is about 2.4%). This will be reduced to 0.1% from 2015, following the new IMO rules (International Maritime Organisation). In order to assess the effects of ship emissions in and around the Baltic Sea and the North Sea, regional model calculations with the EMEP air pollution model have been made on a 1/4° longitude × 1/8° latitude resolution, using ship emissions in the Baltic Sea and the North Sea that are based on accurate ship positioning data. The effects on depositions and air pollution and the resulting number of years of life lost (YOLL) have been calculated by comparing model calculations with and without ship emissions in the two sea areas. The calculations have been made with emissions representative of 2009 and 2011, i.e. before and after the implementation of stricter controls on sulphur emissions from mid 2010. The calculations with present emissions show that per person, an additional 0.1–0.2 years of life lost is estimated in areas close to the major ship tracks with present emission levels. Comparisons of model calculations with emissions before and after the implementation of stricter emission control on sulphur show a general decrease in calculated particle concentration. At the same time, however, an increase in ship activity has resulted in higher emissions and subsequently air concentrations, in particular of NOx, especially in and around several major ports. Additional model calculations have been made with land based and ship emissions representative of year 2030. Following a decrease in emissions, air quality is expected to improve, and depositions to be reduced. Particles from shipping are expected to decrease as a result of emission controls in the SECAs. Further controls of NOx emissions from shipping are not decided, and calculations are presented with and without such controls.


2014 ◽  
Vol 16 (1) ◽  
pp. 139-147 ◽  
Author(s):  
Jens Rydell ◽  
Lothar Bach ◽  
Petra Bach ◽  
Laura Guia Diaz ◽  
Joanna Furmankiewicz ◽  
...  

2019 ◽  
Vol 9 (16) ◽  
pp. 9225-9238 ◽  
Author(s):  
Francisco R. Barboza ◽  
Jonne Kotta ◽  
Florian Weinberger ◽  
Veijo Jormalainen ◽  
Patrik Kraufvelin ◽  
...  

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