Insight into the sediment dynamics of a high-impact low-frequency mass movement event using single-grain feldspar luminescence in the Pokhara valley, Nepal

Author(s):  
Anna-Maartje de Boer ◽  
Wolfgang Schwanghart ◽  
Jürgen Mey ◽  
Jakob Wallinga ◽  
Basanta Raj Adhikari ◽  
...  

<p>Mass movements play an important role in landscape evolution of high mountain areas such as the Himalayas. Yet, establishing numerical age control and reconstructing transport dynamics of past events is challenging. To fill this research gap, we investigated the potential of Optically Stimulated Luminescence (OSL) dating and tracing methods. OSL dating analyses of Himalayan sediments is extremely challenging due to two main reasons: i) the OSL sensitivity of quartz, typically the mineral of choice for dating sediments younger than 100 ka, is poor, and ii) highly turbid conditions during mass movement transport hamper sufficient OSL signal resetting prior to deposition which eventually results in age overestimation. In this study, we aim to bring OSL dating to the test in an extremely challenging environment. First, we assess the applicability of single-grain feldspar dating of mass movement deposits in the Pokhara valley, Nepal. Second, we exploit the poor bleaching mechanisms to get insight into the sediment dynamics of this paleo-mass movement through bleaching proxies. The Pokhara valley is a unique setting for our case-study, considering the availability of an extensive independent radiocarbon dataset (Schwanghart et al., 2016) as a geochronological benchmark.</p><p>Single-grain infrared stimulated luminescence signals were measured at 50°C (IRSL50) and post-infrared infrared stimulated luminescence signals at 150°C (pIRIR-150). As expected, results show that the IRSL50 signal is better bleached than the pIRIR150 signal. A bootstrapped Minimum Age Model (bMAM) is applied to retrieve the youngest subpopulation to estimate the palaeodose. However, burial ages calculated based on this palaeodose overestimate the radiocarbon ages by an average factor of ~8 (IRSL50) and ~35 (pIRIR150). This shows that dating of the Pokhara Formation with our single-grain approach was not successful. Large inheritances in combination with the scatter in the single-grain dose distributions show that the sediments have been transported prior to deposition under extreme limited light exposure which corresponds well with the highly turbid nature of the sediment laden flood and debris flows that emplaced the Pokhara Formation.</p><p>To investigate the sediment transport dynamics in more detail we studied three bleaching proxies: the percentage of grains in saturation (2D0 criteria), percentage of well-bleached grains (2σ range of bMAM-De) and the overdispersion (OD). Neither of the three bleaching proxies indicate a spatial relationship with run-out distances of the mass movement deposits. We interpret this as virtual absence of bleaching during transport, which reflects the catastrophic nature of the event. While single-grain feldspar dating did not provide reliable burial ages of the Pokhara mass movement deposits, our approach has great potential to provide insight in sediment transport dynamics of high-impact low-frequency mass movement events in mountainous region.</p><p><em>References</em></p><p>Schwanghart, W., Bernhardt, A., Stolle, A., Hoelzmann, P., Adhikari, B. R., Andermann, C., ... & Korup, O. (2016). Repeated catastrophic valley infill following medieval earthquakes in the Nepal Himalaya. Science, 351(6269), 147-150.</p>

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Yuji Ishii ◽  
Toru Tamura ◽  
Daniel S. Collins ◽  
Bunnarin Ben

AbstractOptically stimulated luminescence (OSL) dating of fine-grained (4–11 μm) fluvial sediments is rarely attempted but is crucial for constraining the evolution of mud-dominated floodplains. This study investigated the applicability of OSL dating to fine-grained deposits in the Mekong River, Cambodia based on a very young (<600 yr) point-bar to riverbank succession and modern flood deposits. In succession, fine-grained quartz OSL provided the youngest ages, whereas age estimates by multi-grain sand-sized quartz OSL, and feldspar and polymineral infrared-stimulated luminescence are >200 years older than the fine-grained quartz OSL age estimates. Ages of fine-grained quartz OSL are concordant with the minimum ages obtained from the single-grain quartz OSL. These results are supported by the generally small residual doses (<0.1 Gy) measured in modern fine-grained floodplain deposits. This indicates that fine-grained sediments in the Mekong River (Cambodia) are sufficiently bleached at deposition and can yield reliable quartz OSL ages for establishing the chronology of the floodplain. The sufficient bleaching of fine-grained quartz partly results from the long transport distance and may also occur in other large river systems.


2018 ◽  
Author(s):  
Qi Li ◽  
Adam J. Zaczek ◽  
Timothy M. Korter ◽  
J. Axel Zeitler ◽  
Michael T. Ruggiero

<div>Understanding the nature of the interatomic interactions present within the pores of metal-organic frameworks</div><div>is critical in order to design and utilize advanced materials</div><div>with desirable applications. In ZIF-8 and its cobalt analogue</div><div>ZIF-67, the imidazolate methyl-groups, which point directly</div><div>into the void space, have been shown to freely rotate - even</div><div>down to cryogenic temperatures. Using a combination of ex-</div><div>perimental terahertz time-domain spectroscopy, low-frequency</div><div>Raman spectroscopy, and state-of-the-art ab initio simulations,</div><div>the methyl-rotor dynamics in ZIF-8 and ZIF-67 are fully charac-</div><div>terized within the context of a quantum-mechanical hindered-</div><div>rotor model. The results lend insight into the fundamental</div><div>origins of the experimentally observed methyl-rotor dynamics,</div><div>and provide valuable insight into the nature of the weak inter-</div><div>actions present within this important class of materials.</div>


Geochronology ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 229-245
Author(s):  
Guillaume Guérin ◽  
Christelle Lahaye ◽  
Maryam Heydari ◽  
Martin Autzen ◽  
Jan-Pieter Buylaert ◽  
...  

Abstract. Statistical analysis has become increasingly important in optically stimulated luminescence (OSL) dating since it has become possible to measure signals at the single-grain scale. The accuracy of large chronological datasets can benefit from the inclusion, in chronological modelling, of stratigraphic constraints and shared systematic errors. Recently, a number of Bayesian models have been developed for OSL age calculation; the R package “BayLum” presented herein allows different models of this type to be implemented, particularly for samples in stratigraphic order which share systematic errors. We first show how to introduce stratigraphic constraints in BayLum; then, we focus on the construction, based on measurement uncertainties, of dose covariance matrices to account for systematic errors specific to OSL dating. The nature (systematic versus random) of errors affecting OSL ages is discussed, based – as an example – on the dose rate determination procedure at the IRAMAT-CRP2A laboratory (Bordeaux). The effects of the stratigraphic constraints and dose covariance matrices are illustrated on example datasets. In particular, the benefit of combining the modelling of systematic errors with independent ages, unaffected by these errors, is demonstrated. Finally, we discuss other common ways of estimating dose rates and how they may be taken into account in the covariance matrix by other potential users and laboratories. Test datasets are provided as a Supplement to the reader, together with an R markdown tutorial allowing the reproduction of all calculations and figures presented in this study.


2000 ◽  
Vol 644 ◽  
Author(s):  
Takao Kobayashi ◽  
Donald A. Shockey

AbstractAdvanced diagnostic instruments and analyses applied to failure surfaces and cross sections of bulk metallic glasses (BMGs) can provide insight into the deformation and failure of these materials and assist in prototyping new materials with improved failure resistance. Confocal- optics scanning laser microscopic analysis of conjugate fracture surface topographs suggests that the formation and stretching of ligaments are likely keys to the high impact toughness of Vitreloy.


Materials ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 555 ◽  
Author(s):  
Michael Snure ◽  
Timothy Prusnick ◽  
Elisabeth Bianco ◽  
Stefan Badescu

In a combined experimental and theoretical study of gold phosphide (Au2P3), we investigate its vibrational properties, band structure, and dielectric properties, providing new insight into the properties of this underexplored material. Using a simple synthesis route, Au2P3 thin films were produced, enabling the first reported Raman analysis of this material. Coupled with first-principles calculations of these Raman modes, this analysis reveals that low-frequency vibrations are due to Au or mixed Au to P, and at higher frequencies, they are due to P vibrations. Further band structure and dielectric calculations reveal Au2P3 to be a narrow band (0.16 eV) indirect semiconductor. This work helps to fill major gaps in our understanding of key properties in this material that will benefit future research in this field.


RMD Open ◽  
2018 ◽  
Vol 4 (2) ◽  
pp. e000755 ◽  
Author(s):  
Maike Imkamp ◽  
Valéria Lima Passos ◽  
Annelies Boonen ◽  
Suzanne Arends ◽  
Maxime Dougados ◽  
...  

ObjectiveThe goal of managing axial spondyloarthritis (axSpA) is to improve and maintain patients’ health-related quality of life (HRQoL), mainly through targeting towards low disease activity. Here, we aim to gain insight into the joint evolution of HRQoL and disease activity by identifying and characterising latent subgroups of patients with longstanding disease displaying similar trajectories throughout 8  years of follow-up.MethodsData from Outcome in Ankylosing Spondylitis (AS) International Study (n=161) and Groningen Leeuwarden AS cohort (n=264) were used. Biennially, HRQoL was assessed by AS Quality of Life (ASQoL) and disease activity by AS Disease Activity Score—C reactive protein (ASDAS-CRP). Bivariate trajectories of these outcomes were estimated by group-based trajectory modelling. Next, trajectories were profiled by comparing the latent groups with respect to baseline factors using analysis of variance and χ² test.ResultsFive bivariate trajectories were distinguished, in which ASQoL and ASDAS-CRP were tightly linked: (t1) low impact of disease; (t2) moderate impact; (t3) high impact with major improvement; (t4) high impact with some improvement; (t5) very high impact. Profiling revealed, for example, that (t1) was characterised by male gender and Human Leucocyte Antigen B27 positivity; (t3) by younger age, shorter symptom duration and biological intake and (t5) by the highest proportion of females.ConclusionsWe identified five bivariate trajectories of HRQoL and disease activity demonstrating a clear mutual relationship. The profiles revealed that both individual-related and disease-related features define the type of disease course in respect to HRQoL and disease activity in axSpA. This may provide clinicians insight into the differences among patients and help in the management of the disease.


2001 ◽  
Vol 26 (13) ◽  
pp. 1367-1368
Author(s):  
Michael Church ◽  
Marwan A. Hassan

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