Antioxidant ability of Chenopodium formosanum extracted using an ethanol–ammonium sulfate two-phase system

Background Chenopodium formosanum (CF) provides the human body with numerous nutritional components. This study used the two-phase system to identify an efficient method to obtain CF extracts. CF extraction was performed using an ethanol–ammonium sulfate two-phase system. The efficacy of different CF extracts with five types of antioxidant ability was tested and compared with traditional aqueous and alcohol extractions. Results The results showed that a separated top of the two-phase system extract had higher total phenol content (120.35 ± 5.80 mg gallic acid equivalent/g dry extract), total flavonoid content (447.06 ± 16.57 mg quercetin equivalent/g dry extract) and reducing ability (284.48 ± 4.60 mg vitamin C equivalent/g dry extract) than those of other extracts. Furthermore, the separated top of the two-phase system extract and the top of the two-phase system extract had higher 1,1-diphenyl-2-picrylhydrazyl free radical scavenging ability and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) free radical scavenging ability than those of the water extract, alcohol extract, bottom of two-phase system extract, and separated bottom of two-phase system extract. Conclusions The results indicate that CF has great potential for use in natural plant health supplements and skin care products and that the two-phase extraction system can yield an effective CF extract. Graphical Abstract

Analysis of Non-Minimum Phase System for AC/DC Battery Charger Power Factor Correction Converter

Electric mobility is nowadays one of the more important trends regarding pollution reduction and global warming due to fuel consumption. Big efforts are done in order to develop efficient and reliable power electronic systems for electric vehicles. In two stage on board-battery chargers, one way of improving efficiency is by means of ensuring the DC-DC isolated converter always operates in the nominal input/output voltage ratio, that could be achieved with a variable DC-link operation. In this paper, a four-switch buck-boost based AC/DC converter is deeply analyzed in order to improve its dynamic performance, the power factor and the total harmonic distortion. The converter suffers from a non-minimum phase characteristic in different input–output transfer functions, which reduces the closed-loop bandwidth of the system. Therefore, after a deep converter analysis has been done, different solutions have been evaluated and tested. Finally, a control to different output transfer functions of the converter become minimum phase, which allows us to increase the system bandwidth and, consequently, high power factor, low harmonics distortion, single control structure and fast dynamics for wide output voltage range are achieved.

Assessment of Boron Diffusivities in Nickel Borides by Two Mathematical Approaches

In the work of this contribution, two kinetics models have been employed to assess the boron diffusivities in nickel borides in case of Inconel 718 alloy. The first approach, named the alternative diffusion model (ADM), used the modified version of mass conservation equations for a three-phase system whilst the second one employed the mean diffusion coefficient (MDC) method. The boron diffusivities in nickel borides were firstly evaluated in the interval of 1123 to 1223 K for an upper boron concentration of 11.654 wt% in Ni4B3. The boron activation energies in the three phases (Ni4B3, Ni2B and Ni3B) were secondly deduced by fitting the values of boron diffusivities with Arrhenius relations. Finally, these values of energy were compared with the results from the literature for their experimental validation.

The interphase distribution of light REE Ce(III) and La(III) in system based on PEG-1500 – NaNO3 – H2O with the quaternary ammonium base addition

The problem of e-waste processing and recovery of valuable metals from such waste for the second use is attracting more and more scientists’ attention. Liquid extraction as one of hydrometallurgy steps is a traditional method for the metal recovery. However, application of solvent extraction is not meet the green chemistry principles due to organic solvents. Aqueous two-phase systems based on water-soluble polymers are promising alternative for hazardous organic solvents. In this work the dependencies of Ce(III) and La(III) distribution coefficients from process time and the initial quaternary ammonium base concentration have been achieved. Also, based on the Ce(III) and La(III) extraction isotherms it has been shown that the metals initial concentrations are highly affects the distribution coefficients of studied metals. The possibility of aqueous two-phase system application as a solvent for quaternary ammonium salt for light REE (Ce(III) and La(III)) extraction from water solution has been shown.

Исследование реакции поверхности жидкости на импульсное воздействие наклонной газовой струи при малых числах Рэйнольдса

A mathematical description of the motion of a cavity on the liquid surface under an oblique action of a gas jet is obtained using the well-known expressions for the movement of a gas bubble in a liquid. The boundary of the viscous drag force domination over the form drag force is determined. The impingement of the gas jet on the liquid surface is considered as a dynamic object of the automatic control theory. It is found that the dynamic properties of the two-phase system "gas jet - liquid" are described by the integrator equations. Using a specially designed setup, the transient response of the "gas jet - liquid" system were experimentally obtained for the aerodynamic action at angles of 20º and 50º to the surfaces of liquids with the viscosities of 0.71 and 26.1 Pa•s (Reynolds number Re < 2). The research results are necessary for the analysis of the non-contact aerodynamic method of liquid viscosity measurements.

Vanadium(IV) ions extraction in the aqueous two-phase system based on poly(ethylene glycol)

Vanadium has found wide applications in various industries: metallurgy, electronics, batteries, and others. This element, being dispersed, does not form its minerals and, therefore, is mined along the way. An alternative approach of vanadium extraction is to separate it from heavy oil, by flushing the oil with strong acids solutions and further hydrometallurgical processing. The existing methods of oil dehydration solutions processing for the vanadium extraction are not perfect - they do not meet the “green” chemistry principles. Thus, we investigated V(IV) ions extraction in the aqueous two-phase system (ATPS) based on poly(ethylene glycol) 1500 (16.3wt%) – NaNO3 (36wt%) – H2O. The dependences of V(IV) extraction efficiency on phases time contact, and dependences V(IV) distribution coefficients on salt phase acidity have been obtained. This system is shown to be a prospective solution for the vanadium(IV) recovery from acidic waste steams problem as it is possible to extract vanadium with an efficiency of more than 81.6% per one extraction step (the distribution coefficient of vanadium (IV) was 4.84).

Study of caffeine and coumarin extraction kinetics in an aqueous two-phase system based on polyethylene glycol 1500

Caffeine and coumarin are organic compounds of plant origin, which have biological activity and have found wide application in medicine, pharmaceutical, perfumery and food industries. Recovery of caffeine and coumarin from aqueous solutions using liquid-liquid extraction is the most effective method. In the present work the kinetic dependences of caffeine and coumarin in the aqueous two-phase system (ATPS) of PEG 1500 - Na2SO4 - H2O were experimentally obtained. It was established that equilibrium in the system is achieved after 17 minutes for caffeine and after 12 minutes for coumarin. The effect of ultrasound on the extraction rate of caffeine and coumarin in an aqueous two-phase system was also studied.

AN OPTIMIZED ADAPTIVE OVERCURRENT RELAY PROTECTION IN DISTRIBUTION SYSTEM USING CHAOS BASED SATIN BOWERBIRD OPTIMIZATION ALGORITHM (C-SBO)

The increased availability of protections of distributed system is a major role by ensuring the continuity of electrical power supply. The optimization process for a distributed system is to coordinate with overcurrent relay protection with adaptive overcurrent relay model. Here the protection of the system is an important factor since the protection methods play a vital role in distributed systems. The conventional methods discussed the current in the power system to reduce the fault current tolerance value by using various optimization algorithms like Antlion and Butterfly optimization techniques. The distributed three-phase system uses the IEEE bus network with adaptive overcurrent relay model, which produces the best output as compared to the conventional method. Here the particle swarm optimization (C-SBO) procedure is used to improve the relay setting and it reduces the fault current across the relay.